MX2019000517A - Acero martensitico de alto contenido de cromo resistente al calor con alta resistencia a la ruptura por fluencia y resistencia a la oxidacion combinadas. - Google Patents

Acero martensitico de alto contenido de cromo resistente al calor con alta resistencia a la ruptura por fluencia y resistencia a la oxidacion combinadas.

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Publication number
MX2019000517A
MX2019000517A MX2019000517A MX2019000517A MX2019000517A MX 2019000517 A MX2019000517 A MX 2019000517A MX 2019000517 A MX2019000517 A MX 2019000517A MX 2019000517 A MX2019000517 A MX 2019000517A MX 2019000517 A MX2019000517 A MX 2019000517A
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MX
Mexico
Prior art keywords
oxidation resistance
resistant steel
rupture strength
creep rupture
martensitic heat
Prior art date
Application number
MX2019000517A
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English (en)
Inventor
Fuchsmann Arno
Koschlig Bernhard
Subanovic Marko
Bendick Walter
Original Assignee
Vallourec Tubes France
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Filing date
Publication date
Application filed by Vallourec Tubes France filed Critical Vallourec Tubes France
Publication of MX2019000517A publication Critical patent/MX2019000517A/es

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/08Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
    • C21D9/085Cooling or quenching
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/004Heat treatment of ferrous alloys containing Cr and Ni
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/007Heat treatment of ferrous alloys containing Co
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/10Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
    • C21D8/105Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/08Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/10Ferrous alloys, e.g. steel alloys containing cobalt
    • C22C38/105Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

Acero martensitico resistente al calor para aplicaciones de caldera con una combinación unica de resistencia a la fluencia mejorada y excelente resistencia a la oxidacion al exponerse a altas temperaturas en ambientes que contienen vapor, que tiene el siguiente analisis de fusion (en % en peso): C: 0.10 a 0.16 %, Si: 0.20 a 0.60 %, Mn: 0.30 a 0.80 %, P =0.020 %, S =0.010 %, Al =0.020 %, Cr: 10.5 a 12.00 %, Mo: 0.10 a 0.60 %, V: 0.15 a 0.30 %, Ni: 0.10 a 0.40 %, B: 0.008 a 0.015 %, N: 0.002 a 0.020 %, Co: 1.50 a 3.00 %, W: 1.50 a 2.50 %, Nb: 0.02 a 0.07 %, Ti: 0.001-0.020 %. El resto del acero consiste en hierro e impurezas inevitables. El acero se normaliza durante un periodo de aproximadamente 10 a aproximadamente 120 minutos en el intervalo de temperatura entre 1050 °C y 1170 °C y se enfria en aire o agua hasta la temperatura ambiente, y, despues, se reviene durante al menos una hora en el intervalo de temperatura entre 750 °C y 820 °C. Presenta una microestructura martensitica con un contenido promedio de ferrita d menor que 5 % en volumen.
MX2019000517A 2016-07-12 2017-07-12 Acero martensitico de alto contenido de cromo resistente al calor con alta resistencia a la ruptura por fluencia y resistencia a la oxidacion combinadas. MX2019000517A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16179114.0A EP3269831B1 (en) 2016-07-12 2016-07-12 High chromium martensitic heat-resistant seamless steel tube or pipe with combined high creep rupture strength and oxidation resistance
PCT/EP2017/067613 WO2018011301A1 (en) 2016-07-12 2017-07-12 High chromium martensitic heat-resistant steel with combined high creep rupture strength and oxidation resistance

Publications (1)

Publication Number Publication Date
MX2019000517A true MX2019000517A (es) 2019-09-23

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MX2019000517A MX2019000517A (es) 2016-07-12 2017-07-12 Acero martensitico de alto contenido de cromo resistente al calor con alta resistencia a la ruptura por fluencia y resistencia a la oxidacion combinadas.

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US (1) US20190203313A1 (es)
EP (2) EP3269831B1 (es)
JP (1) JP7016343B2 (es)
KR (1) KR102475025B1 (es)
CN (1) CN109689901A (es)
AU (1) AU2017297766B2 (es)
BR (1) BR112019000376B1 (es)
CA (1) CA3025133A1 (es)
EA (1) EA036004B1 (es)
ES (1) ES2846875T3 (es)
MX (1) MX2019000517A (es)
PL (1) PL3269831T3 (es)
UA (1) UA124766C2 (es)
WO (1) WO2018011301A1 (es)

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US10772147B2 (en) 2016-12-22 2020-09-08 Intel Corporation Methods and apparatus for connection attempt failure avoidance with a wireless network
CN109594019A (zh) * 2018-12-27 2019-04-09 天津理工大学 一种9Cr马氏体耐热铸钢及消除该铸钢中δ-铁素体的方法
US11772206B2 (en) 2019-09-20 2023-10-03 Lincoln Global, Inc. High chromium creep resistant weld metal for arc welding of thin walled steel members
US11772207B2 (en) 2019-09-20 2023-10-03 Lincoln Global, Inc. High chromium creep resistant weld metal for arc welding of thick walled steel members
CN111057827B (zh) * 2019-11-27 2022-04-05 中国科学院金属研究所 调控超超临界机组用9Cr3W3CoB耐热钢中硼元素分布状态的方法
CN111041179B (zh) * 2019-12-03 2021-12-14 马鞍山钢铁股份有限公司 一种消除高Cr当量P92耐热钢高温铁素体的方法及高Cr当量P92耐热钢的制备方法
CN116949260B (zh) * 2023-09-20 2023-12-19 成都先进金属材料产业技术研究院股份有限公司 一种p91无缝钢管用钢锭及其热变形方法

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JP4212132B2 (ja) * 1997-09-22 2009-01-21 独立行政法人物質・材料研究機構 マルテンサイト組織を有するフェライト系耐熱鋼とその製造方法
JPH11350031A (ja) * 1998-06-11 1999-12-21 Nippon Steel Corp 低温靭性とクリープ強度に優れた高Cr耐熱鋼の製造方法
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EA201990013A1 (ru) 2019-05-31
JP7016343B2 (ja) 2022-02-04
CA3025133A1 (en) 2018-01-18
AU2017297766A1 (en) 2018-12-13
CN109689901A (zh) 2019-04-26
AU2017297766B2 (en) 2023-02-16
BR112019000376B1 (pt) 2022-06-28
ES2846875T3 (es) 2021-07-30
UA124766C2 (uk) 2021-11-17
KR102475025B1 (ko) 2022-12-07
PL3269831T3 (pl) 2021-05-04
EP3269831B1 (en) 2020-11-04
EA036004B1 (ru) 2020-09-11
JP2019524996A (ja) 2019-09-05
EP3485046A1 (en) 2019-05-22
BR112019000376A2 (pt) 2019-04-24
EP3269831A1 (en) 2018-01-17
WO2018011301A1 (en) 2018-01-18
KR20190029654A (ko) 2019-03-20
EP3485046B1 (en) 2020-11-18
US20190203313A1 (en) 2019-07-04

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