MX2018008853A - Una composición de resina fotocurable para la fabricación estereolitográfica de artículos tridimensionales producidos con dicha composición y un método relativo de fabricación. - Google Patents
Una composición de resina fotocurable para la fabricación estereolitográfica de artículos tridimensionales producidos con dicha composición y un método relativo de fabricación.Info
- Publication number
- MX2018008853A MX2018008853A MX2018008853A MX2018008853A MX2018008853A MX 2018008853 A MX2018008853 A MX 2018008853A MX 2018008853 A MX2018008853 A MX 2018008853A MX 2018008853 A MX2018008853 A MX 2018008853A MX 2018008853 A MX2018008853 A MX 2018008853A
- Authority
- MX
- Mexico
- Prior art keywords
- acro
- manufacturing
- compound
- composition
- photocurable resin
- Prior art date
Links
- 239000011342 resin composition Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 2
- 239000000203 mixture Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- -1 polytetramethylene Polymers 0.000 abstract 3
- 125000003827 glycol group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical group C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 239000007870 radical polymerization initiator Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y80/00—Products made by additive manufacturing
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
- B29K2033/08—Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
- B29K2033/12—Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
- C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
- C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
- C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Mechanical Engineering (AREA)
- Optics & Photonics (AREA)
- Inorganic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
Abstract
La invencion se refiere a una composicion de resina liquida fotocurable para estereolitografia, que comprende (i) al menos un compuesto polimerizable por radicales (A) representado por la siguiente formula general (I): R4O-CO-NH-R2-NH-CO-O-R1-O-CO-NH-R3- NHCO- OR4 (I), en donde R1 es un residuo de politetrametilenglicol lineal o ramificado que tiene un peso molecular promedio de 200 a 3,000 g/mol; R2 es un residuo compuesto de diisocianato; R3 es un residuo de compuesto de diisocianato que es el mismo o diferente de R2; y R4 se seleccionan de AcrO-CH2-CH2-, (AcrO-CH2)2CH-, (AcrO-CH2)3C-CH2-, AcrO CH2-CHCH3-, AcrO-CH2-CHC2H5- y (AcrO-CH2)2C(C2H5)CH2-, preferiblemente de AcrO-CH2-CH2- y (AcrO-CH2)2CH-, mas preferiblemente es AcrO-CH2-CH2-; en donde Acr es CH2=C(R)-CO- y R es un atomo de hidrogeno o un grupo de metilo; (ii) al menos un compuesto organico radicalmente polimerizable (B) diferente del compuesto (A); y (iii) un iniciador de polimerizacion de radicales fotosensibles (C), en donde el contenido de dicho compuesto polimerizable por radicales (A) varia de 5% a 70% en peso basado en la cantidad total de compuestos (A) y (B). La invencion describe ademas un uso y metodo estereolitografico correspondiente y articulos tridimensionales producidos con el mismo.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITUB2016A000408A ITUB20160408A1 (it) | 2016-01-28 | 2016-01-28 | Composizione di resina fotoindurente per produzioni stereolitografiche, articoli tridimensionali prodotti con detta composizione e relativo metodo di produzione |
PCT/IB2017/050449 WO2017130153A1 (en) | 2016-01-28 | 2017-01-27 | A photocurable resin composition for stereolithographic manufacturing, three-dimensional articles produced with said composition and a relative manufacturing method |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2018008853A true MX2018008853A (es) | 2019-01-14 |
Family
ID=55806678
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2018008853A MX2018008853A (es) | 2016-01-28 | 2017-01-27 | Una composición de resina fotocurable para la fabricación estereolitográfica de artículos tridimensionales producidos con dicha composición y un método relativo de fabricación. |
Country Status (15)
Country | Link |
---|---|
US (1) | US11042088B2 (es) |
EP (1) | EP3408708B1 (es) |
JP (1) | JP6970673B2 (es) |
KR (1) | KR20180098382A (es) |
CN (1) | CN108475011A (es) |
BR (1) | BR112018014407A2 (es) |
CA (1) | CA3009615A1 (es) |
HK (1) | HK1258601A1 (es) |
IL (1) | IL260355A (es) |
IT (1) | ITUB20160408A1 (es) |
MX (1) | MX2018008853A (es) |
RU (1) | RU2689578C1 (es) |
SG (1) | SG11201805416RA (es) |
TW (1) | TWI648331B (es) |
WO (1) | WO2017130153A1 (es) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR112020010358A2 (pt) * | 2017-12-01 | 2020-11-10 | Lego A/S | cubo de construção de brinquedo fabricado de maneira aditiva |
CN115284609B (zh) * | 2022-08-01 | 2024-06-18 | 深圳市金石三维打印科技有限公司 | 光固化3d打印机的构件表面平滑打印方法、装置及设备 |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1352063A (en) | 1971-01-08 | 1974-05-15 | Ici Ltd | Polymerisable compositions and resins derived thererom |
GB1465897A (en) | 1973-04-24 | 1977-03-02 | Ici Ltd | Dental compositions |
GB1498421A (en) | 1974-05-21 | 1978-01-18 | Ici Ltd | Dental compositions |
IT1190382B (it) | 1985-07-26 | 1988-02-16 | Montedison Spa | Diesteri acrilici per bisfenolo alchil etere,relativi polimeri e compositi per uso dentale |
DE3820498A1 (de) | 1988-06-16 | 1989-12-21 | Bayer Ag | Dentalwerkstoffe |
GB8815065D0 (en) | 1988-06-24 | 1988-08-03 | Ici Plc | Prosthetic devices |
JPH0452042Y2 (es) | 1988-07-13 | 1992-12-08 | ||
JP3276388B2 (ja) | 1992-01-13 | 2002-04-22 | 株式会社ジーシー | 歯科用修復材組成物 |
JP3419488B2 (ja) | 1993-03-09 | 2003-06-23 | 株式会社クラレ | 光重合性歯科用組成物 |
DE4443702A1 (de) | 1994-12-08 | 1996-06-13 | Ivoclar Ag | Feinkörnige unter Druck oder Scherbeanspruchung fließfähige polymerisierbare Zusammensetzungen |
JPH0970897A (ja) * | 1995-07-06 | 1997-03-18 | Japan Synthetic Rubber Co Ltd | 光造形法 |
JPH09217004A (ja) * | 1996-02-09 | 1997-08-19 | Takemoto Oil & Fat Co Ltd | 光学的立体造形用光硬化性組成物 |
EP0802455B1 (en) * | 1996-04-15 | 2002-10-16 | Teijin Seiki Co., Ltd. | Use of a photocurable resin composition for the production of a stereolithographed object |
JP2000171969A (ja) * | 1998-12-03 | 2000-06-23 | Mitsubishi Chemicals Corp | 感光性樹脂積層体 |
JP4315507B2 (ja) * | 1999-01-08 | 2009-08-19 | ナブテスコ株式会社 | 耐熱性に優れる光硬化性樹脂組成物 |
JP4067718B2 (ja) * | 1999-09-20 | 2008-03-26 | Jsr株式会社 | 樹脂製型の処理法および樹脂製型 |
DE19961342B4 (de) | 1999-12-17 | 2004-02-19 | 3M Espe Ag | Radikalisch härtbare Urethanpräpolymere und deren Verwendung |
DE10114290B4 (de) | 2001-03-23 | 2004-08-12 | Ivoclar Vivadent Ag | Desktop-Verfahren zur Herstellung von Dentalprodukten unter Verwendung des 3D-Plottings |
FR2857668B1 (fr) | 2003-07-16 | 2006-01-13 | Commissariat Energie Atomique | Composition photopolymerisable a base d'une resine expoxyvinylester et d'une resine urethane acrylate et utilisation de ladite composition pour realiser des preformes et/ou des maquettes de protheses dentaires. |
US7262228B2 (en) | 2003-11-21 | 2007-08-28 | Curators Of The University Of Missouri | Photoinitiator systems with anthracene-based electron donors for curing cationically polymerizable resins |
JP4564834B2 (ja) * | 2004-09-24 | 2010-10-20 | Jsr株式会社 | 光ファイバアップジャケット用液状硬化性樹脂組成物 |
RU2408627C2 (ru) * | 2005-10-27 | 2011-01-10 | Хантсман Эдвантс Матириалз (Свитзерланд) Гмбх | Свободная от сурьмы фотоотверждаемая полимерная композиция и трехмерное изделие |
DE602006044294C5 (de) | 2005-11-30 | 2019-10-31 | 3Shape A/S | Herstellung eines Dentalmodells |
DE102007010624B4 (de) | 2007-03-02 | 2009-04-30 | Deltamed Gmbh | Vorrichtung zur schichtweisen generativen Herstellung dreidimensionaler Formteile, Verfahren zur Herstellung dieser Formteile sowie diese Formteile |
EP2151214B1 (de) | 2008-07-30 | 2013-01-23 | Ivoclar Vivadent AG | Lichthärtende Schlicker für die stereolithographische Herstellung von Dentalkeramiken |
WO2010045950A1 (de) | 2008-10-20 | 2010-04-29 | Ivoclar Vivadent Ag | Vorrichtung und verfahren zur verarbeitung von lichtpolymerisierbarem material zum schichtweisen aufbau von formkörpern |
CN101776844A (zh) * | 2009-01-14 | 2010-07-14 | 北京光创物成材料科技有限公司 | 一种用于立体成像的光固化组份 |
KR20110127137A (ko) * | 2009-02-04 | 2011-11-24 | 니폰 가야꾸 가부시끼가이샤 | 활성 에너지선 경화형 하드코트용 수지 조성물과 그의 용도 |
JP2011085614A (ja) | 2009-10-13 | 2011-04-28 | Jsr Corp | 歯牙模型およびその製造方法 |
RU2557961C2 (ru) | 2009-12-22 | 2015-07-27 | 3М Инновейтив Пропертиз Компани | Стоматологические композиции, заготовки для стоматологического протезирования и способы |
US8292625B2 (en) * | 2010-07-23 | 2012-10-23 | Pulpdent Corporation | Radically curable urethane dimethacrylates and compositions thereof for tougher dental prosthetics |
US9120270B2 (en) | 2012-04-27 | 2015-09-01 | University Of Southern California | Digital mask-image-projection-based additive manufacturing that applies shearing force to detach each added layer |
JP2013242941A (ja) * | 2012-05-22 | 2013-12-05 | Nippon Kayaku Co Ltd | 紫外線硬化型樹脂組成物 |
JP6197043B2 (ja) * | 2012-11-14 | 2017-09-13 | デンツプライ シロナ インコーポレーテッド | 歯科製品を製造するための三次元加工材料系 |
JP2015043793A (ja) * | 2013-08-27 | 2015-03-12 | ディーダブルエス エス・アール・エル | 人工歯の製造方法 |
CN103642382B (zh) * | 2013-11-25 | 2015-07-22 | 中国科学院长春应用化学研究所 | 紫外光固化抗污涂料及其制备方法 |
JP6158742B2 (ja) * | 2014-04-17 | 2017-07-05 | 株式会社オートネットワーク技術研究所 | 光硬化性防水剤およびワイヤーハーネス |
-
2016
- 2016-01-28 IT ITUB2016A000408A patent/ITUB20160408A1/it unknown
-
2017
- 2017-01-13 TW TW106101101A patent/TWI648331B/zh not_active IP Right Cessation
- 2017-01-27 BR BR112018014407A patent/BR112018014407A2/pt not_active IP Right Cessation
- 2017-01-27 CA CA3009615A patent/CA3009615A1/en not_active Abandoned
- 2017-01-27 MX MX2018008853A patent/MX2018008853A/es unknown
- 2017-01-27 KR KR1020187021693A patent/KR20180098382A/ko not_active Application Discontinuation
- 2017-01-27 US US16/069,825 patent/US11042088B2/en active Active
- 2017-01-27 CN CN201780007592.1A patent/CN108475011A/zh active Pending
- 2017-01-27 WO PCT/IB2017/050449 patent/WO2017130153A1/en active Application Filing
- 2017-01-27 JP JP2018533152A patent/JP6970673B2/ja active Active
- 2017-01-27 RU RU2018129215A patent/RU2689578C1/ru not_active IP Right Cessation
- 2017-01-27 EP EP17714271.8A patent/EP3408708B1/en active Active
- 2017-01-27 SG SG11201805416RA patent/SG11201805416RA/en unknown
-
2018
- 2018-07-01 IL IL260355A patent/IL260355A/en unknown
-
2019
- 2019-01-18 HK HK19100960.5A patent/HK1258601A1/zh unknown
Also Published As
Publication number | Publication date |
---|---|
BR112018014407A2 (pt) | 2018-12-11 |
KR20180098382A (ko) | 2018-09-03 |
CA3009615A1 (en) | 2017-08-03 |
EP3408708A1 (en) | 2018-12-05 |
IL260355A (en) | 2018-08-30 |
WO2017130153A1 (en) | 2017-08-03 |
US20190011832A1 (en) | 2019-01-10 |
ITUB20160408A1 (it) | 2017-07-28 |
HK1258601A1 (zh) | 2019-11-15 |
RU2689578C1 (ru) | 2019-05-28 |
SG11201805416RA (en) | 2018-07-30 |
TWI648331B (zh) | 2019-01-21 |
JP6970673B2 (ja) | 2021-11-24 |
TW201726797A (zh) | 2017-08-01 |
CN108475011A (zh) | 2018-08-31 |
EP3408708B1 (en) | 2020-03-18 |
JP2019505628A (ja) | 2019-02-28 |
US11042088B2 (en) | 2021-06-22 |
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