MX2017011347A - Metodo para hidrolisis cataliticamente inducida y reciclado de soluciones de borohidruro metalico. - Google Patents

Metodo para hidrolisis cataliticamente inducida y reciclado de soluciones de borohidruro metalico.

Info

Publication number
MX2017011347A
MX2017011347A MX2017011347A MX2017011347A MX2017011347A MX 2017011347 A MX2017011347 A MX 2017011347A MX 2017011347 A MX2017011347 A MX 2017011347A MX 2017011347 A MX2017011347 A MX 2017011347A MX 2017011347 A MX2017011347 A MX 2017011347A
Authority
MX
Mexico
Prior art keywords
recycling
metal borohydride
induced hydrolysis
metal
borohydride solutions
Prior art date
Application number
MX2017011347A
Other languages
English (en)
Inventor
Silberman Alex
Cohen Dvir
Duchovny Yaniv
Original Assignee
Terragenic Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IL237950A external-priority patent/IL237950A0/en
Application filed by Terragenic Ltd filed Critical Terragenic Ltd
Publication of MX2017011347A publication Critical patent/MX2017011347A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
    • C01B6/10—Monoborane; Diborane; Addition complexes thereof
    • C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
    • C01B6/15—Metal borohydrides; Addition complexes thereof
    • C01B6/19—Preparation from other compounds of boron
    • C01B6/21—Preparation of borohydrides of alkali metals, alkaline earth metals, magnesium or beryllium; Addition complexes thereof, e.g. LiBH4.2N2H4, NaB2H7
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/344—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using non-catalytic solid particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
    • C01B6/10—Monoborane; Diborane; Addition complexes thereof
    • C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
    • C01B6/15—Metal borohydrides; Addition complexes thereof
    • C01B6/17—Preparation from boron or inorganic compounds containing boron and oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Se describe el proceso para obtener M1BH4, el proceso comprende poner en contacto M1-BO2 con un metal M2 en la presencia de hidrógeno molecular (H2) bajo condiciones que permiten la formación de M1-BH4 y óxido M2, en donde el M1 es un metal seleccionado de la columna I de la tabla periódica de los elementos o aleaciones de metales seleccionados de la columna I de la tabla periódica de los elementos y M2 es un metal o una aleación de metales seleccionados de la columna II de la tabla periódica de los elementos, siempre y cuando M2 no sea Mg y M1 sea diferente de M2.
MX2017011347A 2015-03-05 2016-03-03 Metodo para hidrolisis cataliticamente inducida y reciclado de soluciones de borohidruro metalico. MX2017011347A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IL23758015 2015-03-05
IL237950A IL237950A0 (en) 2015-03-26 2015-03-26 Deposition process of a cobalt-phosphorus alloy using a constant electric potential
PCT/IL2016/050245 WO2016139669A2 (en) 2015-03-05 2016-03-03 A method for catalytically induced hydrolysis and recycling of metal borohydride solutions

Publications (1)

Publication Number Publication Date
MX2017011347A true MX2017011347A (es) 2018-04-30

Family

ID=56849355

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017011347A MX2017011347A (es) 2015-03-05 2016-03-03 Metodo para hidrolisis cataliticamente inducida y reciclado de soluciones de borohidruro metalico.

Country Status (14)

Country Link
US (2) US10351425B2 (es)
EP (2) EP3265422B1 (es)
JP (1) JP2018510833A (es)
KR (1) KR20180008404A (es)
CN (2) CN108722419A (es)
AU (1) AU2016227323B2 (es)
BR (1) BR112017019016A2 (es)
DK (1) DK3265422T3 (es)
ES (1) ES2922419T3 (es)
IL (2) IL254217B (es)
MX (1) MX2017011347A (es)
PL (1) PL3265422T3 (es)
RU (1) RU2017132484A (es)
WO (1) WO2016139669A2 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2017011347A (es) 2015-03-05 2018-04-30 Terragenic Ltd Metodo para hidrolisis cataliticamente inducida y reciclado de soluciones de borohidruro metalico.
NL2016374B1 (en) * 2015-11-06 2017-05-29 H2Fuel Cascade B V Method for Producing Metal borohydride and Molecular Hydrogen.
CN109518217B (zh) * 2018-11-23 2023-08-15 济南大学 一种硼化钴基析氧催化剂的制备方法
WO2022229949A2 (en) 2021-04-27 2022-11-03 Electriq-Global Energy Solutions Ltd. Devices and modules for use in hydrogen release systems
CN114394603B (zh) * 2021-12-31 2023-04-07 山东大学 一种非晶态镍铁基硼化物纳米材料及其制备方法与应用
IL292647B2 (en) 2022-05-01 2024-03-01 Electriq Global Energy Solutions Ltd A catalyst for generating hydrogen and a method for its preparation

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140150A (en) 1956-12-24 1964-07-07 Bayer Ag Process for the production of boranates
DE1467018A1 (de) 1962-09-25 1969-01-23 Degussa Verfahren zur Herstellung von Alkaliboranaten oder dieses enthaltenden Reaktionsgemischen
JP3225348B2 (ja) * 1996-06-15 2001-11-05 有限会社野上商事 草取り鎌
US5782952A (en) * 1996-08-30 1998-07-21 Massachusetts Institute Of Technology Method for production of magnesium
JP2004224684A (ja) * 2002-11-27 2004-08-12 Materials & Energy Research Institute Tokyo Ltd テトラヒドロホウ酸塩の製造方法
US20040249215A1 (en) * 2000-04-26 2004-12-09 Seijirau Suda Method for producing tetrahydroborates
US7429368B2 (en) * 2001-02-08 2008-09-30 Yu Zhou Process for synthesizing metal borohydrides
JP2002241109A (ja) * 2001-02-09 2002-08-28 Toyota Central Res & Dev Lab Inc ホウ水素化金属の製造方法
EP1302441B1 (en) * 2001-10-10 2007-01-03 Rohm And Haas Company An improved method for making lithium borohydride
DE10302262A1 (de) * 2003-01-22 2004-08-05 Chemetall Gmbh Verfahren zur Herstellung von Lithiumborhydrid
TWI314918B (en) * 2004-04-12 2009-09-21 Rohm And Haas Compan Process for production of a borohydride compound
TWI265146B (en) * 2004-10-08 2006-11-01 Rohm & Haas Direct elemental synthesis of sodium borohydride
US7420027B2 (en) * 2004-11-17 2008-09-02 Battelle Energy Alliance, Llc Method for producing a borohydride
US20060293173A1 (en) 2005-06-28 2006-12-28 Qinglin Zhang Hydrogen generation catalysts and systems for hydrogen generation
US20070172417A1 (en) * 2005-06-28 2007-07-26 Qinglin Zhang Hydrogen generation catalysts and systems for hydrogen generation
US20100012499A1 (en) 2006-06-01 2010-01-21 Yu Zhou Fuel cell charger
RU2344071C1 (ru) 2007-06-25 2009-01-20 Институт химии Дальневосточного отделения Российской академии наук (статус государственного учреждения) (Институт химии ДВО РАН) Способ получения тетрагидробората калия
US20090214417A1 (en) * 2007-12-26 2009-08-27 University Of Delaware Preparation of cobalt-boron alloy catalysts useful for generating hydrogen from borohydrides
US20090196821A1 (en) * 2008-02-06 2009-08-06 University Of Delaware Plated cobalt-boron catalyst on high surface area templates for hydrogen generation from sodium borohydride
JP4965589B2 (ja) 2008-02-26 2012-07-04 ローム アンド ハース カンパニー 水素化ホウ素化合物の製造方法
WO2010010560A1 (en) * 2008-07-23 2010-01-28 M.I.H.G Ltd. Catalyst for the chemical decomposition of metalhydride
JP5495010B2 (ja) * 2009-07-31 2014-05-21 バイオコーク技研株式会社 酸化マグネシウム還元方法及び反応装置
CN103103562B (zh) * 2011-11-14 2016-05-18 新奥科技发展有限公司 一种Ni-Co-W-Cu-B多组分阴极材料及其制备方法和用途
CN102806093B (zh) * 2012-08-31 2014-07-09 重庆大学 一种高效低铂直接甲醇燃料电池催化剂的制备方法
KR101500463B1 (ko) * 2012-12-07 2015-04-02 한국과학기술연구원 연료전지용 코발트계 음극 촉매 및 그 제조방법
CN104046967B (zh) * 2014-05-28 2016-03-16 沈阳师范大学 一种Co-P纳米催化材料的制备方法
CN104091958B (zh) * 2014-07-09 2016-03-09 哈尔滨工程大学 石墨烯贴附塑料负载AuCo硼氢化钠电氧化催化剂的制备方法
MX2017011347A (es) 2015-03-05 2018-04-30 Terragenic Ltd Metodo para hidrolisis cataliticamente inducida y reciclado de soluciones de borohidruro metalico.

Also Published As

Publication number Publication date
IL280943A (en) 2021-04-29
JP2018510833A (ja) 2018-04-19
WO2016139669A3 (en) 2017-01-05
EP3265422B1 (en) 2022-04-27
BR112017019016A2 (pt) 2018-04-17
CN107406253A (zh) 2017-11-28
IL280943B (en) 2021-08-31
EP3265422A4 (en) 2018-12-05
RU2017132484A3 (es) 2019-07-24
RU2017132484A (ru) 2019-04-05
AU2016227323A1 (en) 2017-09-28
AU2016227323B2 (en) 2020-04-09
US10351425B2 (en) 2019-07-16
US10919763B2 (en) 2021-02-16
EP3265422A2 (en) 2018-01-10
IL254217B (en) 2021-08-31
IL254217A0 (en) 2017-10-31
CN107406253B (zh) 2021-02-05
US20180265357A1 (en) 2018-09-20
PL3265422T3 (pl) 2022-09-05
US20180370797A1 (en) 2018-12-27
CN108722419A (zh) 2018-11-02
DK3265422T3 (da) 2022-07-18
ES2922419T3 (es) 2022-09-14
KR20180008404A (ko) 2018-01-24
WO2016139669A2 (en) 2016-09-09
EP3437735A1 (en) 2019-02-06

Similar Documents

Publication Publication Date Title
MX2017011347A (es) Metodo para hidrolisis cataliticamente inducida y reciclado de soluciones de borohidruro metalico.
MY190789A (en) Method for manufacturing ammonia synthesis catalyst, and method for manufacturing ammonia
MX2019010190A (es) Metodo para producir una tira de acero con una capa de recubrimiento de aleacion de aluminio.
WO2018084723A3 (en) PROCESS FOR RECOVERING METAL
GB0920226D0 (en) Fischer-tropsch synthesis
PL2012947T3 (pl) Sposób i urządzenie do wytwarzania półskorup o małym sprężynowaniu
IN2014KN00779A (es)
MX2011007160A (es) Transferencia de fondos de persona a persona.
BR112016031020A2 (pt) sistema e método aperfeiçoado para cobranças automatizadas de dívidas para empresas
GEP20217257B (en) Duplex stainless steel and use thereof
MX2017011979A (es) Aleaciones magneticas de cobre.
PH12016500325A1 (en) A process for cooper and/or precious metal recovery
MX2015007431A (es) Expulsor para uso cuando se rebaja un recipiente de metal, sistema de matriz para rebajar recipiente de metal y metodo de rebajamiento de recipiente de metal.
MY177691A (en) Chemical treatment steel sheet for acidic content storage container and method for producing chemical treatment steel sheet for acidic content storage container
MX2013002063A (es) Metodo para conformar en caliente una parte de metal revestida y parte conformada.
SA516371201B1 (ar) طريقة لتحسين نوع نفط ثقيل بشكل معزز عن طريق إضافة خطوة معالجة بالهيدروجين إلى عملية تحسين النوع
IN2015DN02518A (es)
EP3396028A3 (en) Direct electrochemical synthesis of doped conductive polymers on metal alloys
MY179338A (en) Production method of aliphatic alcohol
CL2015003410A1 (es) Método para pre-tratamiento de menas de óxido que contienen oro.
MX2015015292A (es) Boquilla de entrada refractaria sumergida.
MX2019002840A (es) Metodo para la recuperacion de metales preciosos.
PT3371098T (pt) Método para a produção de hidretoborato de metal e hidrogénio molecular
Hultquist et al. Response to comment by A. Hedin et al. on" Corrosion of copper in distilled water without oxygen and the detection of produced hydrogen"
MY178396A (en) Method for producing magnesium hydride, power generation system using magnesium hydride, and apparatus for producing magnesium hydride