MX2017000340A - Una composicion para reducir la cantidad de aldehidos emitidos de espumas de poliuretano. - Google Patents

Una composicion para reducir la cantidad de aldehidos emitidos de espumas de poliuretano.

Info

Publication number
MX2017000340A
MX2017000340A MX2017000340A MX2017000340A MX2017000340A MX 2017000340 A MX2017000340 A MX 2017000340A MX 2017000340 A MX2017000340 A MX 2017000340A MX 2017000340 A MX2017000340 A MX 2017000340A MX 2017000340 A MX2017000340 A MX 2017000340A
Authority
MX
Mexico
Prior art keywords
composition
aldehydes
issued
reduce
amount
Prior art date
Application number
MX2017000340A
Other languages
English (en)
Other versions
MX389249B (es
Inventor
P Wiltz Eugene Jr
Lodewijk Dries Geert
Allison Grigsby Robert Jr
Original Assignee
Huntsman Petrochemical Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Petrochemical Llc filed Critical Huntsman Petrochemical Llc
Publication of MX2017000340A publication Critical patent/MX2017000340A/es
Publication of MX389249B publication Critical patent/MX389249B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/325—Polyamines containing secondary or tertiary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3275—Hydroxyamines containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3293—Hydroxyamines containing heterocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3848—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
    • C08G18/3882—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
    • C08G18/3887—Phosphite compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/105—Esters; Ether-esters of monocarboxylic acids with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Se describe una composición reactiva al isocianato que comprende al menos un componente seleccionado del grupo que consiste de un componente reactivo al isocianato; un agente para tratamiento seleccionado del grupo que consiste de urea cíclica sustituida con al menos un grupo reactivo al isocianato, un depurador de radicales libres, o un ácido polimérico, o una mezcla de los mismos; uno o más componentes de amina, cada uno de los componentes de amina tienen una estructura determinada.
MX2017000340A 2014-07-10 2015-07-09 Una composicion para reducir la cantidad de aldehidos emitidos de espumas de poliuretano. MX389249B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462022928P 2014-07-10 2014-07-10
EP14178274 2014-07-24
PCT/EP2015/065657 WO2016005479A1 (en) 2014-07-10 2015-07-09 A composition to reduce the amount of aldehydes emitted from polyurethane foams

Publications (2)

Publication Number Publication Date
MX2017000340A true MX2017000340A (es) 2017-04-27
MX389249B MX389249B (es) 2025-03-20

Family

ID=51220465

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017000340A MX389249B (es) 2014-07-10 2015-07-09 Una composicion para reducir la cantidad de aldehidos emitidos de espumas de poliuretano.

Country Status (11)

Country Link
US (1) US10472456B2 (es)
EP (1) EP3166986B1 (es)
JP (1) JP6722168B2 (es)
KR (1) KR102390574B1 (es)
CN (2) CN107075062A (es)
BR (1) BR112016030534B1 (es)
CA (1) CA2954558C (es)
MX (1) MX389249B (es)
PL (1) PL3166986T3 (es)
RU (1) RU2712184C2 (es)
WO (1) WO2016005479A1 (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2703421A1 (en) * 2012-08-28 2014-03-05 Huntsman Petrochemical LLC A composition for making foams with reduced aldehyde emission
MX2018009401A (es) * 2016-02-05 2018-12-19 Huntsman Int Llc Metodo para la reduccion de emision de aldehidos en espuma de poliuretano.
EP3293218A1 (de) * 2016-09-13 2018-03-14 Covestro Deutschland AG Verfahren zur erniedrigung der aldehydemissionen von polyurethanschaumstoffen
WO2018145283A1 (en) * 2017-02-09 2018-08-16 Dow Global Technologies Llc Polyurethane foams having low levels of aldehyde emissions
WO2018234348A1 (en) 2017-06-21 2018-12-27 Huntsman International Llc Formulation for reduction of formaldehyde emission in pu foam
JP7079329B2 (ja) * 2017-12-18 2022-06-01 ハンツマン・インターナショナル・エルエルシー ポリウレタン含有材料におけるアルデヒド放出を低減させる方法
PT110585B (pt) * 2018-02-22 2021-04-22 Hovione Farmaciencia Sa Processo de produção contínua de partículas compreendendo secagem por atomização com preparação contínua da solução de atomização
FR3081469B1 (fr) * 2018-05-28 2021-09-03 Groupe Fp Bois Utilisation de derives cycliques d'uree pour diminuer la teneur en composes organiques volatils dans l'air ambiant
EP3830166A4 (en) * 2018-08-02 2022-03-23 Dow Global Technologies LLC PROCESS FOR REDUCING ALDEHYDE EMISSIONS IN POLYURETHANE FOAM MATERIALS
KR102649155B1 (ko) * 2018-08-02 2024-03-20 다우 글로벌 테크놀로지스 엘엘씨 폴리우레탄 폼에서 알데히드 방출을 감소시키는 방법
GB2579405B (en) 2018-11-30 2022-09-14 Si Group Switzerland Chaa Gmbh Antioxidant compositions
US20230141792A1 (en) * 2020-03-12 2023-05-11 Dow Global Technologies Llc Process for reducing aldehyde emissions in polyether polyols and polyurethane foams
JP7757954B2 (ja) * 2020-03-16 2025-10-22 東ソー株式会社 軟質ポリウレタンフォーム形成用二液型組成物、並びに、軟質ポリウレタンフォーム及びその製造方法
JP2022022758A (ja) * 2020-07-06 2022-02-07 東ソー株式会社 ポリウレタンフォーム製造用のアミン触媒組成物及びその用途
EP4267642A1 (de) * 2020-12-23 2023-11-01 Basf Se Neuer katalysator zur herstellung von polyurethanen
KR20240058891A (ko) 2021-08-31 2024-05-03 모멘티브 퍼포먼스 머티리얼즈 인크. 폴리우레탄 폼용 조성물, 이로부터 제조된 폼 및 이의 방법
KR20250004807A (ko) * 2022-04-14 2025-01-08 헌츠만 페트로케미칼 엘엘씨 폴리우레탄 발포체로부터의 알데하이드 방출을 연장된 시간 기간 동안 억제하기 위한 혼합물

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ES2136438T3 (es) * 1995-12-11 1999-11-16 Huntsman Ici Europ Llc The Cor Dispositivo de aislamiento termico.
JP3703262B2 (ja) 1997-08-19 2005-10-05 三井化学株式会社 ポリオキシアルキレンポリオール、軟質ポリウレタンフォーム及び非発泡ポリウレタンの製造方法
JPH11197501A (ja) 1998-01-07 1999-07-27 Nippon Synthetic Chem Ind Co Ltd:The アルデヒド吸着剤及びその用途、その使用方法
DE10003157B4 (de) 2000-01-26 2006-10-26 Basf Ag Verfahren zur Herstellung von funktionalisierten Polyurethanschaumstoffen
US6818675B2 (en) * 2002-08-06 2004-11-16 General Electric Company Process for preparing polyurethane foam
JP3959092B2 (ja) * 2004-12-27 2007-08-15 住化バイエルウレタン株式会社 ポリウレタン成形品およびその製造方法
ES2322776T5 (es) * 2005-04-19 2012-11-20 Basf Se Poliéter-polioles, poliéster-polioles y poliuretanos de bajo contenido residual de aldehídos
JP4971677B2 (ja) 2006-05-01 2012-07-11 協同油脂株式会社 グリース組成物
EP2106415B1 (en) 2007-01-19 2016-04-20 Huntsman Petrochemical LLC Tertiary amines blocked with polymer acids
US20100113634A1 (en) * 2007-02-27 2010-05-06 Katsumi Tokumoto Catalyst composition for production of flexible polyurethane foam
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EP2521746B1 (en) * 2010-01-08 2019-03-13 Huntsman Petrochemical LLC Inhibition of amine oxidation
US10066047B2 (en) 2012-02-02 2018-09-04 Covestro Llc Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams
EP2703421A1 (en) 2012-08-28 2014-03-05 Huntsman Petrochemical LLC A composition for making foams with reduced aldehyde emission

Also Published As

Publication number Publication date
JP2017521527A (ja) 2017-08-03
KR20170032346A (ko) 2017-03-22
BR112016030534B1 (pt) 2021-08-17
CN107075062A (zh) 2017-08-18
BR112016030534A2 (pt) 2017-08-22
CA2954558A1 (en) 2016-01-14
MX389249B (es) 2025-03-20
BR112016030534A8 (pt) 2021-05-04
US20170129988A1 (en) 2017-05-11
WO2016005479A1 (en) 2016-01-14
JP6722168B2 (ja) 2020-07-15
KR102390574B1 (ko) 2022-04-26
RU2017104242A3 (es) 2019-01-23
EP3166986A1 (en) 2017-05-17
EP3166986B1 (en) 2023-04-19
PL3166986T3 (pl) 2023-07-31
CA2954558C (en) 2023-09-26
US10472456B2 (en) 2019-11-12
RU2017104242A (ru) 2018-08-15
CN117106151A (zh) 2023-11-24
RU2712184C2 (ru) 2020-01-24

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