MX2016013202A - Sintesis de alcoholes de azúcares reducidos, derivados de furano. - Google Patents

Sintesis de alcoholes de azúcares reducidos, derivados de furano.

Info

Publication number
MX2016013202A
MX2016013202A MX2016013202A MX2016013202A MX2016013202A MX 2016013202 A MX2016013202 A MX 2016013202A MX 2016013202 A MX2016013202 A MX 2016013202A MX 2016013202 A MX2016013202 A MX 2016013202A MX 2016013202 A MX2016013202 A MX 2016013202A
Authority
MX
Mexico
Prior art keywords
hto
sugar alcohols
synthesis
sugar
reduced sugar
Prior art date
Application number
MX2016013202A
Other languages
English (en)
Inventor
Ma Chi-Cheng
Stensrud Kenneth
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2016013202A publication Critical patent/MX2016013202A/es

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30—Artificial sweetening agents
    • A23L27/33—Artificial sweetening agents containing sugars or derivatives
    • A23L27/34—Sugar alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/22—Trihydroxylic alcohols, e.g. glycerol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/24—Tetrahydroxylic alcohols, e.g. pentaerythritol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/26—Hexahydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/20—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G3/00—Glycosides
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Saccharide Compounds (AREA)
  • Furan Compounds (AREA)
  • Catalysts (AREA)

Abstract

En la presente se describen métodos para sintetizar 1, 2, 5, 6-hexanotetrol (HTO), 1,6-hexanodiol (HDO) y otros polioles reducidos a partir de glucósidos R o alcoholes de azúcares C5 y C6. Los métodos incluyen poner en contacto el glucósido R o alcohol de azúcar con un catalizador de cobre, de la forma más deseable un catalizador de cobre Raney, con hidrógeno durante un tiempo y a una temperatura y presión que sean suficientes para formar polioles reducidos que tengan de 2 a 3 grupos hidroxi menos que el material de partida. Cuando el compuesto de partida es un alcohol de azúcar C6 tal como el sorbitol o un glucósido R de un azúcar C6 tal como un glucósido metílico, el producto dominante es HTO. Se puede utilizar el mismo catalizador para reducir adicionalmente el HTO a HDO.
MX2016013202A 2014-04-10 2014-04-10 Sintesis de alcoholes de azúcares reducidos, derivados de furano. MX2016013202A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2014/033580 WO2015156802A1 (en) 2014-04-10 2014-04-10 Synthesis of reduced sugar alcohols, furan derivatives

Publications (1)

Publication Number Publication Date
MX2016013202A true MX2016013202A (es) 2017-05-01

Family

ID=54288222

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2016013202A MX2016013202A (es) 2014-04-10 2014-04-10 Sintesis de alcoholes de azúcares reducidos, derivados de furano.
MX2016013207A MX2016013207A (es) 2014-04-10 2014-11-19 Catalizador de acido fosfonico en ciclación deshidratante de polioles de 5 y 6 átomos de carbono con color y recuento del producto mejorado.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2016013207A MX2016013207A (es) 2014-04-10 2014-11-19 Catalizador de acido fosfonico en ciclación deshidratante de polioles de 5 y 6 átomos de carbono con color y recuento del producto mejorado.

Country Status (10)

Country Link
US (2) US20170044123A1 (es)
EP (2) EP3131413A4 (es)
JP (2) JP2017513841A (es)
KR (2) KR20160143760A (es)
CN (2) CN106413427A (es)
AU (2) AU2014390019A1 (es)
CA (2) CA2945297A1 (es)
MX (2) MX2016013202A (es)
SG (1) SG11201608426PA (es)
WO (2) WO2015156802A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160146787A (ko) * 2014-04-10 2016-12-21 아처 다니엘 미드랜드 캄파니 R-글루코시드, 당 알코올, 환원 당 알코올 및 환원 당 알코올의 퓨란 유도체의 합성
WO2017100402A1 (en) * 2015-12-11 2017-06-15 Archer Daniels Midland Company One-pot synthesis of anhydropentitol esters from pentitols, catalyzed by water-tolerant lewis acids
US11598125B2 (en) 2017-09-03 2023-03-07 Dan Raz Ltd. Latch arrangement
JP2018115332A (ja) * 2018-03-20 2018-07-26 リンテック株式会社 粘着テープおよび半導体装置の製造方法
JP2018115333A (ja) * 2018-03-20 2018-07-26 リンテック株式会社 粘着テープおよび半導体装置の製造方法
WO2019204753A1 (en) 2018-04-20 2019-10-24 Wisconsin Alumni Research Foundation Catalytic production of 1,2,5,6-hexanetetrol from levoglucosenone
CN110935435B (zh) * 2018-09-21 2022-09-20 中国石油化工股份有限公司 一种用于制备环状多元醇的催化剂及其应用

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CA1088525A (en) * 1977-03-30 1980-10-28 Kuno Wagner Process for the preparation of low molecular weight polyhydroxyl compounds
DE2738512A1 (de) * 1977-08-26 1979-03-08 Bayer Ag Verfahren zur herstellung von niedermolekularen polyhydroxylverbindungen
US4820880A (en) * 1987-05-18 1989-04-11 Michigan Biotechnology Institute Process for the production of 3,4-dideoxyhexitol
DE3928285A1 (de) * 1989-08-26 1991-02-28 Basf Ag Verfahren zur herstellung niederer, mehrwertiger alkohole
DE19758788B4 (de) * 1997-01-17 2007-12-13 Südzucker Aktiengesellschaft Mannheim/Ochsenfurt Verfahren zur Hydrierung von Glucose oder Glucosegemischen mittels eines Schalenkatalysators
EP1127613A1 (de) * 2000-02-18 2001-08-29 Degussa AG Geformter Festbettraney-Kupferkatalysator zur Verwendung bei der Dehydrierung von Alkoholen
AU2001264848A1 (en) * 2000-05-26 2001-12-11 E.I. Du Pont De Nemours And Company Continuous process for the manufacture of anhydro sugar alcohols and reactor useful therefor
US7772412B2 (en) * 2006-01-26 2010-08-10 Battelle Memorial Institute Methods for dehydration of sugars and sugar alcohols
MX2009006724A (es) * 2006-12-22 2009-06-30 Cargill Inc Procedimiento para la hidrogenacion de un azucar o mezcla de azucar.
JP5612806B2 (ja) * 2008-01-30 2014-10-22 花王株式会社 多価アルコールの水素化分解物の製造方法
US9120806B2 (en) * 2008-04-10 2015-09-01 Iowa Corn Promotion Board Dianhydrosugar production process
CN101492457B (zh) * 2009-02-27 2011-05-11 南京工业大学 一种异山梨醇的制备方法
CN101701065B (zh) * 2009-10-14 2011-08-10 南京威尔化工有限公司 高纯度聚山梨酯-80的合成方法
KR20120124427A (ko) * 2009-12-30 2012-11-13 바이렌트, 아이엔씨. 폴리올의 산소환원 수소처리를 위한 개선된 촉매
EP2390247A1 (en) * 2010-05-26 2011-11-30 Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) Preparation of caprolactone, caprolactam, 2,5-tetrahydrofuran dimethanol, 1,6-hexanediol or 1,2,6-hexanetriol from 5-hydroxymethyl-2-furfuraldehyde
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Also Published As

Publication number Publication date
CA2944731A1 (en) 2015-10-15
JP2017512823A (ja) 2017-05-25
EP3129384A1 (en) 2017-02-15
CN106413427A (zh) 2017-02-15
MX2016013207A (es) 2017-05-19
KR20160146772A (ko) 2016-12-21
CA2945297A1 (en) 2015-10-15
KR20160143760A (ko) 2016-12-14
US9969704B2 (en) 2018-05-15
US20170044123A1 (en) 2017-02-16
WO2015156802A1 (en) 2015-10-15
EP3131413A1 (en) 2017-02-22
EP3129384A4 (en) 2017-10-25
EP3131413A4 (en) 2017-08-30
JP2017513841A (ja) 2017-06-01
WO2015156839A1 (en) 2015-10-15
US20170015676A1 (en) 2017-01-19
SG11201608426PA (en) 2016-11-29
CN106414453A (zh) 2017-02-15
AU2014390019A1 (en) 2016-11-03
AU2014389993A1 (en) 2016-11-03

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