MX2016008061A - Sistesis directa de diol-éteres, acetatos, éter-acetatos y carbonatos de alquilo y furanicos de base biológica. - Google Patents

Sistesis directa de diol-éteres, acetatos, éter-acetatos y carbonatos de alquilo y furanicos de base biológica.

Info

Publication number
MX2016008061A
MX2016008061A MX2016008061A MX2016008061A MX2016008061A MX 2016008061 A MX2016008061 A MX 2016008061A MX 2016008061 A MX2016008061 A MX 2016008061A MX 2016008061 A MX2016008061 A MX 2016008061A MX 2016008061 A MX2016008061 A MX 2016008061A
Authority
MX
Mexico
Prior art keywords
acetates
ether
furanic
carbonates
bio
Prior art date
Application number
MX2016008061A
Other languages
English (en)
Inventor
Stensrud Kenneth
Venkitasubramaniam Padmesh
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2014/068809 external-priority patent/WO2015094716A1/en
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2016008061A publication Critical patent/MX2016008061A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/15—Unsaturated ethers containing only non-aromatic carbon-to-carbon double bonds
    • C07C43/16—Vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/16—Acetic acid esters of dihydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/96—Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)

Abstract

Se describe un método de preparar un mono-acetato, o carbonato de aglicol que implica una cualquiera de dos vías a partir de alquilen-glicoles, HMF o sus productos derivados de la reducción (es decir, FDM, bHMTHFs). En particular, de acuerdo con una vía, el alquilen-glicol, HMF O fdm, BhmthfS se hacen reaccionar con un dicarbonato de dialquilo en presencia de un agemte desprotonante, en ausencia sustancial de un catalizador extrínseco, para producir un éter, y subsiguientemente se hace reaccionar el éter con una base acida. De acuerdo con la otra via, se hacen reaccionar alquilen-glicoles con un donante de acetato en presencia de una base ácida para generar un mono-acetato de alquileno, y se eterifican con un carbonato en presencia de un agente desprotonante.
MX2016008061A 2013-12-20 2014-12-19 Sistesis directa de diol-éteres, acetatos, éter-acetatos y carbonatos de alquilo y furanicos de base biológica. MX2016008061A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201361918795P 2013-12-20 2013-12-20
PCT/US2014/068809 WO2015094716A1 (en) 2013-12-20 2014-12-05 Synthesis of isohexide ethers and carbonates
US201462093683P 2014-12-18 2014-12-18
PCT/US2014/071512 WO2015095710A1 (en) 2013-12-20 2014-12-19 Direct synthesis of bio-based alkyl & furanic diol ethers, acetates, ether-acetates, and carbonates

Publications (1)

Publication Number Publication Date
MX2016008061A true MX2016008061A (es) 2017-02-27

Family

ID=53403742

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016008061A MX2016008061A (es) 2013-12-20 2014-12-19 Sistesis directa de diol-éteres, acetatos, éter-acetatos y carbonatos de alquilo y furanicos de base biológica.

Country Status (9)

Country Link
EP (1) EP3083548A4 (es)
JP (1) JP2017507899A (es)
KR (1) KR20160099646A (es)
CN (1) CN105849080A (es)
AU (1) AU2014369062A1 (es)
BR (1) BR112016014267A2 (es)
CA (1) CA2934512A1 (es)
MX (1) MX2016008061A (es)
WO (1) WO2015095710A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2019001840A (es) 2016-08-16 2019-05-09 Ppg Ind Ohio Inc Composicion polimerizable para articulos opticos.
US10865172B1 (en) * 2019-09-04 2020-12-15 Eastman Chemical Company Aromatic enol ethers
US10858304B1 (en) * 2019-09-04 2020-12-08 Eastman Chemical Company Aromatic enol ethers
CN111349492B (zh) * 2020-02-28 2021-05-25 浙江糖能科技有限公司 2,5-四氢呋喃二甲醇脂肪酸二酯在柴油添加剂的应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2963489A (en) * 1953-07-30 1960-12-06 American Cyanamid Co 3, 4-furandimethanol and derivatives
US4012424A (en) * 1975-08-07 1977-03-15 Chem Systems Inc. Cracking of mixtures containing hydroxyesters
US4170596A (en) * 1976-10-05 1979-10-09 Kowa Company, Ltd. Novel monoesters of cis-cyclopentenediol, process for preparation thereof, and process for preparation of lactones from the monoesters
US4192949A (en) * 1977-06-28 1980-03-11 Basf Aktiengesellschaft Preparation of aralkyl phenyl ethers and alkyl phenyl ethers
JPH07100702B2 (ja) * 1987-07-22 1995-11-01 三井石油化学工業株式会社 環状カ−ボネ−トの製造方法
JPH09227435A (ja) * 1996-02-26 1997-09-02 Mitsui Toatsu Chem Inc （ポリ）エチレングリコールジエーテルの製造法
KR100593529B1 (ko) * 2004-03-31 2006-06-28 주식회사 엘지생활건강 에스테르계 표백활성화제 화합물의 제조방법
FR2950892B1 (fr) * 2009-10-01 2011-11-18 Roquette Freres Procede de preparation de di(alkylcarbonate) de dianhydrohexitol
WO2012003501A2 (en) * 2010-07-02 2012-01-05 Reviva Pharmaceuticals, Inc. Compositions, synthesis, and methods of using cycloalkylmethylamine derivatives

Also Published As

Publication number Publication date
JP2017507899A (ja) 2017-03-23
CA2934512A1 (en) 2015-06-25
CN105849080A (zh) 2016-08-10
AU2014369062A1 (en) 2016-06-30
WO2015095710A1 (en) 2015-06-25
EP3083548A4 (en) 2017-08-30
BR112016014267A2 (pt) 2017-08-08
KR20160099646A (ko) 2016-08-22
EP3083548A1 (en) 2016-10-26

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