MX2013002126A - Composiciones curables con agregados de funcionalidad curables por humedad cerca de los extremos de la cadena. - Google Patents

Composiciones curables con agregados de funcionalidad curables por humedad cerca de los extremos de la cadena.

Info

Publication number
MX2013002126A
MX2013002126A MX2013002126A MX2013002126A MX2013002126A MX 2013002126 A MX2013002126 A MX 2013002126A MX 2013002126 A MX2013002126 A MX 2013002126A MX 2013002126 A MX2013002126 A MX 2013002126A MX 2013002126 A MX2013002126 A MX 2013002126A
Authority
MX
Mexico
Prior art keywords
curable
moisture
controlled radical
radical polymerization
chain ends
Prior art date
Application number
MX2013002126A
Other languages
English (en)
Inventor
Anthony F Jacobine
Roderick Coffey
Joel Schall
John G Woods
Original Assignee
Henkel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Corp filed Critical Henkel Corp
Publication of MX2013002126A publication Critical patent/MX2013002126A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/02Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/01Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/20Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/30Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Se describe un proceso de polimerización por radicales controlada, y productos hechos a partir del mismo. El proceso incluye realizar polimerización por radicales controlada sobre una composición que comprende un compuesto polimerizable, un iniciador, un ligando y un catalizador; permitir que la reacción de polimerización por radicales controlada proceda hasta que se obtenga un nivel de conversión deseado, pero antes de que la conversión completa obtenga un producto de polimerización intermedio; y hacer reaccionar además el producto de polimerización intermedio con un reactivo que tiene un agregado de múltiples sitios reactivos para proveer un producto de reacción de polímero que tenga un agregado de sitios reactivos múltiples colgantes adyacentes a dichos extremos terminales del producto de reacción de polímero.
MX2013002126A 2010-08-25 2011-08-22 Composiciones curables con agregados de funcionalidad curables por humedad cerca de los extremos de la cadena. MX2013002126A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/868,159 US8436094B2 (en) 2010-08-25 2010-08-25 Curable compositions with moisture-curable functionality clusters near the chain ends
PCT/US2011/048562 WO2012027246A2 (en) 2010-08-25 2011-08-22 Curable compositions with moisture-curable functionality clusters near the chain ends

Publications (1)

Publication Number Publication Date
MX2013002126A true MX2013002126A (es) 2013-04-03

Family

ID=45698079

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013002126A MX2013002126A (es) 2010-08-25 2011-08-22 Composiciones curables con agregados de funcionalidad curables por humedad cerca de los extremos de la cadena.

Country Status (8)

Country Link
US (1) US8436094B2 (es)
EP (1) EP2609122A4 (es)
JP (1) JP6000249B2 (es)
KR (1) KR101512390B1 (es)
CN (1) CN103261236B (es)
CA (1) CA2807963A1 (es)
MX (1) MX2013002126A (es)
WO (1) WO2012027246A2 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8729179B1 (en) * 2012-08-20 2014-05-20 Henkel US IP LLC Moisture curable polyacrylates
CN104870485A (zh) * 2012-12-18 2015-08-26 汉高知识产权控股有限责任公司 支化聚丙烯酸酯的受控自由基聚合的方法
US9676933B2 (en) * 2013-07-31 2017-06-13 Three Bond Fine Chemical Co., Ltd. Moisture-curing composition
US9587062B2 (en) * 2014-12-15 2017-03-07 Henkel IP & Holding GmbH and Henkel AG & Co. KGaA Photocrosslinkable block copolymers for hot-melt adhesives
EP3275909A1 (en) * 2016-07-27 2018-01-31 Clariant Plastics & Coatings Ltd Novel polyacrylate-polysilane block copolymers
JP6787824B2 (ja) * 2017-03-27 2020-11-18 株式会社カネカ 加水分解性シリル基を含有するポリ(メタ)アクリレートの製造方法
CN107976487A (zh) * 2017-12-21 2018-05-01 上海微谱化工技术服务有限公司 一种利用制备型gpc分析uv预聚物的方法
WO2019208386A1 (ja) * 2018-04-27 2019-10-31 東亞合成株式会社 硬化性樹脂組成物、並びに、ブロック共重合体及びその製造方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3806475B2 (ja) * 1996-02-08 2006-08-09 株式会社カネカ 末端に官能基を有する(メタ)アクリル系重合体の 製造方法
DE69829063T2 (de) * 1997-09-22 2006-03-23 Kaneka Corp. Polymer, verfahren zu dessen herstellung und härtbare zusammensetzung, die dieses polymer enthält
US6911515B2 (en) * 2001-03-23 2005-06-28 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
US7279527B2 (en) * 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
DE102005041528A1 (de) * 2005-08-31 2007-03-01 Rohmax Additives Gmbh Öllösliche Polymere
US8716409B2 (en) * 2006-12-29 2014-05-06 Firestone Polymers, Llc Carboxylate terminated polymers and their use in impact-modified plastics
WO2009033974A1 (de) * 2007-09-12 2009-03-19 Construction Research & Technology Gmbh Verfahren zur herstellung von silanmodifizierten copolymeren
DE102008002016A1 (de) 2008-05-28 2009-12-03 Evonik Röhm Gmbh Verfahren zur Herstellung von silyl-funktionalisierten ABA-Triblockcopolymeren auf (Meth)acrylatbasis
BRPI0914145A2 (pt) 2008-06-18 2015-10-20 Henkel Corp métodos para produzir polimerização por radical controlada, e para obter distribuição por radical atva controlada.
US20100204361A1 (en) * 2009-02-09 2010-08-12 Kurian Pious V Novel multifunctional azo initiators for free radical polymerizations: methods of preparation

Also Published As

Publication number Publication date
WO2012027246A2 (en) 2012-03-01
CN103261236A (zh) 2013-08-21
JP6000249B2 (ja) 2016-09-28
CA2807963A1 (en) 2012-03-01
US20120053296A1 (en) 2012-03-01
JP2013536303A (ja) 2013-09-19
KR101512390B1 (ko) 2015-04-16
KR20130139233A (ko) 2013-12-20
EP2609122A2 (en) 2013-07-03
WO2012027246A3 (en) 2012-07-12
US8436094B2 (en) 2013-05-07
EP2609122A4 (en) 2015-03-25
CN103261236B (zh) 2017-05-24

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