MX2012009395A - Proceso para produccion de anhidridos. - Google Patents

Proceso para produccion de anhidridos.

Info

Publication number
MX2012009395A
MX2012009395A MX2012009395A MX2012009395A MX2012009395A MX 2012009395 A MX2012009395 A MX 2012009395A MX 2012009395 A MX2012009395 A MX 2012009395A MX 2012009395 A MX2012009395 A MX 2012009395A MX 2012009395 A MX2012009395 A MX 2012009395A
Authority
MX
Mexico
Prior art keywords
container
wall
catalyst
skirt
perforated
Prior art date
Application number
MX2012009395A
Other languages
English (en)
Inventor
Simon Nicholas Tilley
Original Assignee
Davy Process Techn Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Davy Process Techn Ltd filed Critical Davy Process Techn Ltd
Publication of MX2012009395A publication Critical patent/MX2012009395A/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/54Preparation of carboxylic acid anhydrides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/2485Monolithic reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/60Two oxygen atoms, e.g. succinic anhydride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00805Details of the particulate material
    • B01J2208/00814Details of the particulate material the particulate material being provides in prefilled containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20Vanadium, niobium or tantalum
    • B01J23/22Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198Vanadium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

Un proceso para la producción de anhídridos mediante el contacto de un chorro de alimentación gaseosa con un catalizador en partículas, dicho proceso se lleva a cabo en un reactor tubular que tiene una entrada y una salida, dicha salida está ubicada hacia abajo de la entrada, dicho reactor comprende uno o más tubos que tienen ubicados en éstos uno o más vehículos para dicho catalizador en partículas y medio de enfriamiento en contacto con dichos tubos; en donde dicho vehículo de catalizador comprende: un recipiente anular que contiene catalizador en uso, dicho recipiente contiene una pared interna perforada que define un tubo, una pared externa perforada, una superficie superior que cierra el recipiente anular y una superficie inferior que cierra el recipiente anular; una superficie que cierra la parte inferior de dicho tubo formado por la pared interna del recipiente anular; un bisel que se extiende hacia arriba desde la pared externa perforada del recipiente anular desde una posición que se encuentra en o cerca de la superficie de la parte inferior de dicho recipiente hasta una posición por debajo de la ubicación de un precinto; y un precinto ubicado que se encuentra en o cerca de la superficie superior y que se extiende desde el recipiente por una distancia que se extiende más allá de una superficie externa del bisel; dicho proceso comprende: (a) introducir los reactivos gaseosos a través de la entrada; (b) pasar dichos reactivos en sentido descendente a través de dicho tubo, por lo menos uno, hacia la superficie superior del, o del primer, vehículo catalizador donde pasan hacia el pasaje definido por la pared interna perforada del recipiente antes de pasar en forma radial a través del lecho del catalizador hacia la pared externa perforada; (c) permitir que ocurra la reacción mientras el gas entra en contacto con el catalizador; (d) hacer pasar reactivo sin reaccionar y producto hacia afuera del recipiente a través de la pared externa perforada y a continuación hacia arriba entre la superficie interna del bisel y la pared exterior del recipiente anular hasta que lleguen al precinto donde están orientados sobre el extremo del bisel y producen el flujo hacia abajo entre la superficie externa del bisel y la superficie interna del tubo del reactor donde se desarrolla la transferencia de calor; (e) repetir los pasos (b) hasta (d) en cualquier vehículo catalizador posterior; y (f) eliminar el producto de la salida.
MX2012009395A 2011-04-27 2012-02-03 Proceso para produccion de anhidridos. MX2012009395A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1107073.7A GB201107073D0 (en) 2011-04-27 2011-04-27 Process
PCT/GB2012/050233 WO2012146902A1 (en) 2011-04-27 2012-02-03 Process for the production of anhydrides

Publications (1)

Publication Number Publication Date
MX2012009395A true MX2012009395A (es) 2013-01-15

Family

ID=44168642

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012009395A MX2012009395A (es) 2011-04-27 2012-02-03 Proceso para produccion de anhidridos.

Country Status (17)

Country Link
US (1) US8937190B2 (es)
EP (1) EP2531287B1 (es)
JP (1) JP5946901B2 (es)
KR (1) KR101830277B1 (es)
CN (1) CN102858448B (es)
AR (1) AR086192A1 (es)
AU (1) AU2012206976B2 (es)
BR (1) BR112012019168B1 (es)
CA (1) CA2794681C (es)
EA (1) EA024191B1 (es)
GB (1) GB201107073D0 (es)
MX (1) MX2012009395A (es)
MY (1) MY160037A (es)
SG (1) SG185348A1 (es)
TW (1) TWI516471B (es)
WO (1) WO2012146902A1 (es)
ZA (1) ZA201205844B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201107072D0 (en) * 2011-04-27 2011-06-08 Davy Process Techn Ltd Process
GB201417462D0 (en) 2014-10-02 2014-11-19 Johnson Matthey Davy Technologies Ltd Apparatus and process
EP3501633A1 (en) * 2017-12-19 2019-06-26 Yara International ASA Catalyst support systems for ammonia oxidation burners
DE102018007737A1 (de) 2018-10-01 2020-04-02 Hitachi Zosen Inova Etogas Gmbh Festbettanordnung
CN109589874B (zh) * 2018-11-19 2021-08-24 江苏玖鸿化工技术有限公司 一种银法甲醛装置中的甲醇氧化器
CN110801788B (zh) * 2019-11-27 2023-07-25 北京昆仑永泰科技有限公司 一种高温高压固定床反应器
GB202015186D0 (en) * 2020-09-25 2020-11-11 Johnson Matthey Davy Technologies Ltd Improvements in or relating to catalyst carriers for tubular reactors and associated methods

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1088009A (en) 1964-11-03 1967-10-18 Halcon International Inc Process and apparatus for the vapour phase oxidation of organic compounds
GB1105691A (en) 1963-06-19 1968-03-13 Iris May Cross Improved automatically ignited oil burning heating device
DE3919750A1 (de) * 1989-06-16 1990-12-20 Linde Ag Reaktor
EP1300190A1 (en) * 2001-10-04 2003-04-09 Methanol Casale S.A. Heterogeneous catalytic reactor with modular catalytic cartridge
MX2007001173A (es) * 2004-01-15 2007-09-25 Methanol Casale Sa Reactor catalitico de lecho fijo.
CN2796823Y (zh) * 2005-04-18 2006-07-19 王德瑞 一种换热式转化炉炉管
EP1818094A1 (en) * 2006-02-13 2007-08-15 Ammonia Casale S.A. Wall system for catalytic beds of synthesis reactors
ATE518586T1 (de) * 2008-03-07 2011-08-15 Haldor Topsoe As Katalytischer reaktor
GB0918246D0 (en) * 2009-10-19 2009-12-02 Davy Process Techn Ltd Apparatus
GB201105691D0 (en) * 2011-04-04 2011-05-18 Davy Process Techn Ltd Apparatus
GB201107070D0 (en) * 2011-04-27 2011-06-08 Davy Process Techn Ltd FT process using can reactor

Also Published As

Publication number Publication date
GB201107073D0 (en) 2011-06-08
EA201300199A1 (ru) 2013-05-30
BR112012019168B1 (pt) 2019-11-05
AU2012206976B2 (en) 2014-11-06
AR086192A1 (es) 2013-11-27
WO2012146902A1 (en) 2012-11-01
AU2012206976A1 (en) 2012-11-15
TW201242943A (en) 2012-11-01
ZA201205844B (en) 2014-01-29
EP2531287A1 (en) 2012-12-12
CA2794681A1 (en) 2012-11-01
TWI516471B (zh) 2016-01-11
JP2014518850A (ja) 2014-08-07
CN102858448A (zh) 2013-01-02
MY160037A (en) 2017-02-15
CN102858448B (zh) 2015-08-19
EP2531287B1 (en) 2019-09-18
CA2794681C (en) 2019-07-09
US20140046077A1 (en) 2014-02-13
KR101830277B1 (ko) 2018-02-20
BR112012019168A8 (pt) 2018-07-31
JP5946901B2 (ja) 2016-07-06
SG185348A1 (en) 2012-12-28
EA024191B1 (ru) 2016-08-31
US8937190B2 (en) 2015-01-20
BR112012019168A2 (pt) 2018-03-27
KR20140001081A (ko) 2014-01-06

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