MX2012009203A - Proceso para producir un alqueno que contiene fluor. - Google Patents
Proceso para producir un alqueno que contiene fluor.Info
- Publication number
- MX2012009203A MX2012009203A MX2012009203A MX2012009203A MX2012009203A MX 2012009203 A MX2012009203 A MX 2012009203A MX 2012009203 A MX2012009203 A MX 2012009203A MX 2012009203 A MX2012009203 A MX 2012009203A MX 2012009203 A MX2012009203 A MX 2012009203A
- Authority
- MX
- Mexico
- Prior art keywords
- sub
- fluorine
- containing alkene
- alkene
- integer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
La presente invención proporciona un proceso para producir un alqueno que contiene flúor representado por la fórmula (2): Rf1C(Rf2)=CH2 en donde Rf1 y Rf2 son iguales o diferentes, y son F, H, F(CF2) en donde n es un entero de 1 a 5, 0 H(CF2)m en donde m es un entero de 1 a 5, con la condición de que Rf1 y Rf2 no sean simultáneamente H, al calentar un alcano que contiene flúor representado por la fórmula (1): Rf1CF(Rf2)CH3 en donde Rf1 y R2 son como se definieron anteriormente, en una fase gaseosa para realizar una reacción de deshidrofluoración, la reacción de deshidrofluoración se lleva a cabo en presencia de 5 moles o más de un fluoruro de hidrógeno anhidro por mol de alcano que contiene flúor; el proceso de la presente invención puede aumentar significativamente la selectividad del alqueno que contiene flúor sin reducir la conversión en la producción del alqueno que contiene flúor del alcano que contiene flúor, tal como propano que contiene flúor.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US28242910P | 2010-02-12 | 2010-02-12 | |
PCT/JP2011/053061 WO2011099604A2 (en) | 2010-02-12 | 2011-02-08 | Process for producing fluorine-containing alkene |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2012009203A true MX2012009203A (es) | 2012-08-31 |
Family
ID=44120715
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012009203A MX2012009203A (es) | 2010-02-12 | 2011-02-08 | Proceso para producir un alqueno que contiene fluor. |
Country Status (7)
Country | Link |
---|---|
US (1) | US8865952B2 (es) |
EP (1) | EP2534120B2 (es) |
JP (1) | JP5500261B2 (es) |
CN (2) | CN106316776A (es) |
ES (1) | ES2567178T5 (es) |
MX (1) | MX2012009203A (es) |
WO (1) | WO2011099604A2 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201207666D0 (en) * | 2012-05-02 | 2012-06-13 | Mexichem Amanco Holding Sa | Process |
JP6328589B2 (ja) | 2015-05-29 | 2018-05-23 | ダイキン工業株式会社 | 含フッ素オレフィンの製造方法 |
GB2540427B (en) | 2015-07-17 | 2017-07-19 | Mexichem Fluor Sa De Cv | Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf) |
JP6624126B2 (ja) * | 2017-03-13 | 2019-12-25 | ダイキン工業株式会社 | 含フッ素オレフィンの製造方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US299655A (en) * | 1884-06-03 | Mining machine | ||
US2996555A (en) | 1959-06-25 | 1961-08-15 | Dow Chemical Co | Preparation of 2, 3, 3, 3-tetrafluoropropene |
EP0223906A3 (en) * | 1982-10-29 | 1989-02-01 | Synthetic Blood Corporation | Gelatin based synthetic whole blood and a process for preparing the same |
CA2019914C (en) * | 1989-07-06 | 1999-06-08 | Maher Yousef Elsheikh | Dehydrofluorination and dehydrogenation of fluorinated alkanes |
JP3412165B2 (ja) | 1991-05-24 | 2003-06-03 | ダイキン工業株式会社 | フッ素化触媒およびハロゲン化炭化水素のフッ素化方法 |
US5396000A (en) | 1993-05-24 | 1995-03-07 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 1,1,1,2,3,-pentafluoropropane |
EP1495801A1 (en) * | 1995-06-08 | 2005-01-12 | E.I. du Pont de Nemours and Company | Catalytic manufacture of vinyl fluoride using chromium oxide |
JP3520900B2 (ja) * | 1997-12-12 | 2004-04-19 | ダイキン工業株式会社 | ペンタフルオロエタンの製造方法、並びにフッ素化用触媒及びその製造方法 |
US7897823B2 (en) | 2004-10-29 | 2011-03-01 | E. I. Du Pont De Nemours And Company | Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes |
US7476771B2 (en) * | 2005-11-01 | 2009-01-13 | E.I. Du Pont De Nemours + Company | Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof |
KR101404981B1 (ko) * | 2005-11-03 | 2014-06-10 | 허니웰 인터내셔널 인코포레이티드 | 플루오르화 유기 화합물 제조방법 |
WO2007079435A2 (en) | 2006-01-03 | 2007-07-12 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
JP5416587B2 (ja) * | 2006-10-03 | 2014-02-12 | メキシケム、アマンコ、ホールディング、ソシエダッド、アノニマ、デ、カピタル、バリアブレ | プロセス |
GB0806422D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
US8398882B2 (en) * | 2006-10-31 | 2013-03-19 | E I Du Pont De Nemours And Company | Processes for the production of fluoropropanes and halopropenes and azeotropic compositions of 2-chloro-3,3,3-trifluoro-1-propene with HF and of 1,1,1,2,2-pentafluoropropane with HF |
BRPI0906014A2 (pt) * | 2008-02-21 | 2015-06-30 | Du Pont | "processo de separação de uma mistura que compreende hf e hfc-1234yf, processo de separação de hfc-1234yf de uma mistura que compreende fluoreto de hidrogênio e o mencionado hfc-1234yf, processo de separação de fluoreto de hidrogênio de uma mistura que compreende fluoreto de hidrogênio e hfc-1234yf, processo de purificação de hfc-1234yf a partir de uma mistura que compreende hfc-1234yf e hf, processo de purificação de hf a partir de uma mistura que compreende um hfc-1234yf e hf, processo de separação de hfc-1234yf de uma mistura de hfc-1234yf, hf e pelo menos um dentre hfc-245cb ou hfc-245eb e processo de separação de hf de uma mistura que compreende hfc-1234yf, hf e pelo menos um dentre hfc-245cb ou hfc-245eb" |
GB0806419D0 (en) * | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
GB0806389D0 (en) * | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
GB0808836D0 (en) * | 2008-05-15 | 2008-06-18 | Ineos Fluor Ltd | Process |
ES2433421T3 (es) * | 2008-07-29 | 2013-12-10 | Daikin Industries, Ltd. | Procedimiento para la preparación de propeno que contiene flúor mediante fluoración en fase gaseosa |
CN102105423B (zh) * | 2008-07-30 | 2013-10-30 | 大金工业株式会社 | 制备2,3,3,3-四氟丙烯的方法 |
JP5413451B2 (ja) * | 2008-07-30 | 2014-02-12 | ダイキン工業株式会社 | 2,3,3,3−テトラフルオロプロペンの製法 |
US8614361B2 (en) | 2009-04-23 | 2013-12-24 | Daikin Industries, Ltd. | Process for preparation of 2,3,3,3-tetrafluoropropene |
-
2011
- 2011-02-08 CN CN201610680755.XA patent/CN106316776A/zh active Pending
- 2011-02-08 MX MX2012009203A patent/MX2012009203A/es active IP Right Grant
- 2011-02-08 WO PCT/JP2011/053061 patent/WO2011099604A2/en active Application Filing
- 2011-02-08 EP EP11705705.9A patent/EP2534120B2/en active Active
- 2011-02-08 CN CN2011800090892A patent/CN102753506A/zh active Pending
- 2011-02-08 ES ES11705705T patent/ES2567178T5/es active Active
- 2011-02-08 JP JP2012536633A patent/JP5500261B2/ja active Active
- 2011-02-08 US US13/575,403 patent/US8865952B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US20120302802A1 (en) | 2012-11-29 |
JP5500261B2 (ja) | 2014-05-21 |
EP2534120B2 (en) | 2023-02-15 |
ES2567178T5 (es) | 2023-04-28 |
WO2011099604A3 (en) | 2011-10-13 |
US8865952B2 (en) | 2014-10-21 |
CN102753506A (zh) | 2012-10-24 |
WO2011099604A2 (en) | 2011-08-18 |
CN106316776A (zh) | 2017-01-11 |
JP2013519628A (ja) | 2013-05-30 |
EP2534120A2 (en) | 2012-12-19 |
ES2567178T3 (es) | 2016-04-20 |
EP2534120B1 (en) | 2016-02-03 |
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