MX2012004839A - Catalizadores para hacer etanol a partir de acido acetico. - Google Patents

Catalizadores para hacer etanol a partir de acido acetico.

Info

Publication number
MX2012004839A
MX2012004839A MX2012004839A MX2012004839A MX2012004839A MX 2012004839 A MX2012004839 A MX 2012004839A MX 2012004839 A MX2012004839 A MX 2012004839A MX 2012004839 A MX2012004839 A MX 2012004839A MX 2012004839 A MX2012004839 A MX 2012004839A
Authority
MX
Mexico
Prior art keywords
catalysts
acetic acid
metal
rhenium
ruthenium
Prior art date
Application number
MX2012004839A
Other languages
English (en)
Other versions
MX337472B (es
Inventor
James H Zink
Victor J Johnston
Laiyuan Chen
Barbara F Kimmich
Josefina T Chapman
Heiko Weiner
John L Potts
Radmila Jevtic
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of MX2012004839A publication Critical patent/MX2012004839A/es
Publication of MX337472B publication Critical patent/MX337472B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Catalizadores y procedimientos para formar catalizadores para usarse en la hidrogenación de ácido acético para formar etanol; en una modalidad, el catalizador comprende un primer metal, un soporte silicáceo y por lo menos un modificador de soporte de metasilicato; preferiblemente, se selecciona el primer metal del grupo que consta de cobre, hierro, cobalto, níquel, rutenio, rodio, paladio, osmio, iridio, platino, titanio, zinc, cromo, renio, molibdeno y tungsteno; además, el catalizador puede comprender un segundo metal, seleccionado preferiblemente del grupo que consta de cobre, molibdeno, estaño, cromo, hierro, cobalto, vanadio, tungsteno, paladio, platino, lantano, cerio, manganeso, rutenio, renio, oro y níquel.
MX2012004839A 2009-10-26 2010-02-02 Catalizadores para hacer etanol a partir de acido acetico. MX337472B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
PCT/US2010/022950 WO2011056247A2 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid

Publications (2)

Publication Number Publication Date
MX2012004839A true MX2012004839A (es) 2012-05-29
MX337472B MX337472B (es) 2016-03-04

Family

ID=46506680

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012004839A MX337472B (es) 2009-10-26 2010-02-02 Catalizadores para hacer etanol a partir de acido acetico.

Country Status (7)

Country Link
EP (1) EP2493606A2 (es)
CN (1) CN102333588B (es)
AU (1) AU2010315899A1 (es)
BR (1) BR112012009792A2 (es)
CA (1) CA2778767A1 (es)
MX (1) MX337472B (es)
WO (1) WO2011056247A2 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130197278A1 (en) * 2012-01-27 2013-08-01 Celanese International Corporation Process For Manufacturing Ethanol Using A Metallic Catalyst Supported on Titania
CN102600842A (zh) * 2012-03-02 2012-07-25 山西盛驰科技有限公司 乙酸加氢制乙醇催化剂及其制备方法和应用
US8536383B1 (en) * 2012-03-14 2013-09-17 Celanese International Corporation Rhodium/tin catalysts and processes for producing ethanol
CN104043484B (zh) * 2013-03-13 2016-10-12 中国石油天然气股份有限公司 一种醋酸催化加氢制备乙醇的催化剂及其制备和应用
CN103331167A (zh) * 2013-07-19 2013-10-02 新地能源工程技术有限公司 一种乙酸直接制备乙醇的催化剂及制备方法和应用
CN105258185A (zh) * 2015-11-14 2016-01-20 无锡清杨机械制造有限公司 一种带空气净化功能的抽油烟机
CN105646143B (zh) * 2016-02-23 2018-09-04 上海华谊（集团）公司 醋酸制乙醇联产乙酸乙酯的方法
CN106345512B (zh) * 2016-08-03 2019-03-05 江苏大学 一种二元合金催化剂及其制备方法和用途
CN108358752A (zh) * 2018-04-18 2018-08-03 肖锦 一种乙酸加氢制乙醇的方法
WO2020058822A1 (en) * 2018-09-17 2020-03-26 Sabic Global Technologies B.V. Catalysts for producing alcohols and ethers from synthesis gas
US11559795B2 (en) * 2018-09-19 2023-01-24 Sabic Global Technologies, B.V. Bimetallic catalysts supported on zeolites for selective conversion of n-butane to ethane

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US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US5137861A (en) * 1991-01-22 1992-08-11 Mobil Oil Corp. Catalyst comprising a hydrogenation metal and a delaminated layered silicate
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US5977010A (en) * 1995-06-15 1999-11-02 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
US5945570A (en) * 1998-10-29 1999-08-31 Arhancet; Juan Pedro Catalyst and process for preparing 1,3-propanediol
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
EP1277826A1 (en) * 2001-07-18 2003-01-22 ATOFINA Research Hydrogenation and dehydrogenation processes and catalysts therefor
US7608744B1 (en) * 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst

Also Published As

Publication number Publication date
MX337472B (es) 2016-03-04
AU2010315899A1 (en) 2012-05-17
AU2010315899A2 (en) 2012-06-21
CN102333588A (zh) 2012-01-25
CA2778767A1 (en) 2011-05-12
WO2011056247A2 (en) 2011-05-12
BR112012009792A2 (pt) 2016-10-18
CN102333588B (zh) 2014-04-09
EP2493606A2 (en) 2012-09-05
WO2011056247A3 (en) 2011-10-27

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