MX2012004840A - Catalizadores para hacer acetato de etilo a partir de acido acetico. - Google Patents

Catalizadores para hacer acetato de etilo a partir de acido acetico.

Info

Publication number
MX2012004840A
MX2012004840A MX2012004840A MX2012004840A MX2012004840A MX 2012004840 A MX2012004840 A MX 2012004840A MX 2012004840 A MX2012004840 A MX 2012004840A MX 2012004840 A MX2012004840 A MX 2012004840A MX 2012004840 A MX2012004840 A MX 2012004840A
Authority
MX
Mexico
Prior art keywords
ethyl acetate
catalysts
acetic acid
making ethyl
palladium
Prior art date
Application number
MX2012004840A
Other languages
English (en)
Inventor
James H Zink
Victor J Johnston
Laiyuan Chen
Barbara F Kimmich
Josefina T Chapman
Heiko Weiner
John L Potts
Radmila Jevtic
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of MX2012004840A publication Critical patent/MX2012004840A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Catalizadores y procesos para hacer catalizadores adecuados para usarse en procesos para hidrogenar ácido acético para formar acetato de etilo y mezclas de acetato de etilo y etanol; en una primera modalidad, el catalizador incluye una alta carga de níquel, paladio o platino; en una segunda modalidad, el catalizador comprende un primer metal seleccionado de níquel y paladio y un segundo metal seleccionado de estaño y zinc; en una tercera modalidad, el catalizador comprende uno o más metales en un soporte que se ha modificado con un modificador de soporte ácido o un modificador de soporte de redox.
MX2012004840A 2009-10-26 2010-02-02 Catalizadores para hacer acetato de etilo a partir de acido acetico. MX2012004840A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
PCT/US2010/022953 WO2011053367A1 (en) 2009-10-26 2010-02-02 Catalysts for making ethyl acetate from acetic acid

Publications (1)

Publication Number Publication Date
MX2012004840A true MX2012004840A (es) 2012-05-29

Family

ID=46506681

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012004840A MX2012004840A (es) 2009-10-26 2010-02-02 Catalizadores para hacer acetato de etilo a partir de acido acetico.

Country Status (7)

Country Link
EP (1) EP2493612A1 (es)
CN (1) CN102300638A (es)
AU (1) AU2010313700A1 (es)
BR (1) BR112012009856A2 (es)
CA (1) CA2778771A1 (es)
MX (1) MX2012004840A (es)
WO (1) WO2011053367A1 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
WO2013056268A2 (en) * 2011-10-06 2013-04-18 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol
US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
US8575406B2 (en) * 2011-12-22 2013-11-05 Celanese International Corporation Catalysts having promoter metals and process for producing ethanol
US9024086B2 (en) 2012-01-06 2015-05-05 Celanese International Corporation Hydrogenation catalysts with acidic sites
MX2014008270A (es) * 2012-01-06 2014-10-06 Celanese Int Corp Catalizadores de hidrogenacion que contienen cobalto y procesos para la preparacion de los mismos.
US8815768B2 (en) 2012-01-06 2014-08-26 Celanese International Corporation Processes for making catalysts with acidic precursors
US8841230B2 (en) 2012-01-06 2014-09-23 Celanese International Corporation Processes for making catalysts with metal halide precursors
WO2013103392A1 (en) * 2012-01-06 2013-07-11 Celanese International Corporation Hydrogenation catalyst and process for producing ethanol using the catalyst
US8981164B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Cobalt and tin hydrogenation catalysts
WO2013103850A1 (en) * 2012-01-06 2013-07-11 Celanese International Corporation Hydrogenation catalysts with acidic sites comprising modified silica support
CN104039448B (zh) * 2012-01-06 2016-11-16 国际人造丝公司 具有钴改性载体的加氢催化剂
WO2013103393A1 (en) * 2012-01-06 2013-07-11 Celanese International Corporation Processes for making catalysts comprising precious metal and active metal modified support
US8980789B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Modified catalyst supports
US9126194B2 (en) 2012-02-29 2015-09-08 Celanese International Corporation Catalyst having support containing tin and process for manufacturing ethanol
US20130225876A1 (en) * 2012-02-29 2013-08-29 Celanese International Corporation Hydrogenation Catalyst Using Multiple Impregnations of an Active Metal Solution
US20130261349A1 (en) * 2012-03-28 2013-10-03 Celanese International Corporation Hydrogenation Catalysts and Processes for Making Same
CN102671682B (zh) * 2012-06-05 2014-04-16 中国科学院山西煤炭化学研究所 一种用于合成乙酸乙酯的催化剂及制法和应用
CN104232173A (zh) * 2014-10-08 2014-12-24 匡明星 一种高效节能绿色环保有机燃料
US9670120B2 (en) 2015-01-27 2017-06-06 Celanese International Corporation Process for producing ethanol using a solid catalyst
CN112739458B (zh) * 2018-09-19 2023-12-22 Sabic环球技术有限责任公司 正丁烷选择性转化为乙烷用负载于沸石的双金属催化剂

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2607807A (en) 1950-02-24 1952-08-19 Du Pont Preparation of alcohols from carboxylic acids
US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
DE3221077A1 (de) 1982-06-04 1983-12-08 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von ethanol
US4399305A (en) 1982-10-18 1983-08-16 Union Carbide Corporation Production of ethylene by the pyrolysis of ethyl acetate
US4550185A (en) * 1983-12-22 1985-10-29 E. I. Du Pont De Nemours And Company Process for making tetrahydrofuran and 1,4-butanediol using Pd/Re hydrogenation catalyst
FR2570370B1 (fr) 1984-09-17 1987-03-20 Atochem Procede de fabrication d'ethylene a partir d'esters ethyliques
GB8509530D0 (en) * 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
GB8707595D0 (en) * 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
GB8828616D0 (en) 1988-12-07 1989-01-11 Bp Chem Int Ltd Chemical process
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
US5350504A (en) * 1992-12-18 1994-09-27 Mobil Oil Corporation Shape selective hydrogenation of aromatics over modified non-acidic platinum/ZSM-5 catalysts
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
JP3786007B2 (ja) * 2001-05-29 2006-06-14 住友金属鉱山株式会社 炭化水素油中に含む芳香族化合物の水素化処理用触媒
US20070238605A1 (en) * 2004-04-26 2007-10-11 Wolfgang Strehlau Catalysts for the Simultaneous Removal of Carbon Monoxide and Hydrocarbons from Oxygen-Rich Exhaust Gases and Processes for the Manufacture Thereof
DE102004020259A1 (de) * 2004-04-26 2005-11-10 Hte Ag The High Throughput Experimentation Company Oxidationskatalysator für die simultane Entfernung von Kohlenmonoxid und Kohlenwasserstoffen aus sauerstoffreichen Abgasen und Verfahren zu seiner Herstellung
US20110060174A1 (en) * 2008-01-07 2011-03-10 Danmarks Tekniske Universitet - Dtu catalyst, a process for selective hydrogenation of acetylene to ethylene and a method for the manufacture of the catalyst
US7820852B2 (en) * 2008-07-31 2010-10-26 Celanese International Corporation Direct and selective production of ethyl acetate from acetic acid utilizing a bimetal supported catalyst

Also Published As

Publication number Publication date
AU2010313700A1 (en) 2012-05-17
CN102300638A (zh) 2011-12-28
EP2493612A1 (en) 2012-09-05
BR112012009856A2 (pt) 2016-08-30
CA2778771A1 (en) 2011-05-05
WO2011053367A1 (en) 2011-05-05

Similar Documents

Publication Publication Date Title
MX2012004840A (es) Catalizadores para hacer acetato de etilo a partir de acido acetico.
MX2014008253A (es) Catalizadores de hidrogenacion con soportes modificados con cobalto.
MX346356B (es) Procedimiento de obtencion de alcoholes superiores.
MX2012004837A (es) Procesos para hacer etanol a partir de acido acetico.
UA100743C2 (ru) Способ разложения n2o, катализатор для этого и способ получения такого катализатора
CL2012001053A1 (es) Proceso para producir etanol mediante la reducción del ácido acético que comprende el paso de ácido acético e hidrógeno sobre un catalizador que comprende platino y estaño sobre un soporte modificado con un modificador de soporte seleccionado de óxidos y metasilicatos de metal alcalino, alcalinotérreo, sus precursores y sus mezclas.
BR112014018998A8 (pt) Catalisador de hidrogenação para a conversão de uma mistura; e processo
MX2012004838A (es) Procesamientos para hacer acetato de etilo a partir de acido acetico.
MY161990A (en) Monolith catalyst and use thereof
EP2392557A3 (en) Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
MX337472B (es) Catalizadores para hacer etanol a partir de acido acetico.
NZ598773A (en) Ethanol production from acetic acid utilizing a cobalt catalyst
IN2014CN04844A (es)
ATE520636T1 (de) Verfahren zur isomerisierung von olefinisch ungesättigten alkoholen
NZ599463A (en) Process for making ethanol from acetic acid using acidic catalysts
EP2276701A4 (en) Base metal and base metal modified diesel oxidation catalysts
WO2011113881A3 (en) Hydrogenation catalyst
EP3144064A3 (en) Selective hydrogenation catalyst and methods of making and using same
WO2011113611A3 (en) Reforming catalyst
EA201170581A1 (ru) Способ получения катализатора окисления и катализаторы, полученные данным способом
IN2014KN02708A (es)
EP3733286A4 (en) PRECIOUS METAL-TRANSITION METAL COMPLEX CATALYST SUPPORTED ON CARBON-COATED SILICON DIOXIDE-ALUMINUM OXIDE SUPPORT AND MANUFACTURING METHOD FOR IT
WO2008107109A8 (en) Process for the preparation of hydroxytyrosol
WO2010038209A8 (en) Hydrogenation of esters or carbonyl groups with phosphino-oxide based ruthenium complexes
UA88151C2 (uk) Спосіб одержання меркаптоорганіл(алкоксисиланів)

Legal Events

Date Code Title Description
FA Abandonment or withdrawal