WO2011056247A3 - Catalysts for making ethanol from acetic acid - Google Patents

Catalysts for making ethanol from acetic acid Download PDF

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Publication number
WO2011056247A3
WO2011056247A3 PCT/US2010/022950 US2010022950W WO2011056247A3 WO 2011056247 A3 WO2011056247 A3 WO 2011056247A3 US 2010022950 W US2010022950 W US 2010022950W WO 2011056247 A3 WO2011056247 A3 WO 2011056247A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalysts
acetic acid
metal
rhenium
ruthenium
Prior art date
Application number
PCT/US2010/022950
Other languages
French (fr)
Other versions
WO2011056247A2 (en
Inventor
Victor J. Johnston
Laiyuan Chen
Barbara F. Kimmich
Josefina T. Chapman
James H. Zink
Heiko Weiner
John L. Potts
Radmila Jevtic
Original Assignee
Celanese International Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese International Corporation filed Critical Celanese International Corporation
Priority to EP10702393A priority Critical patent/EP2493606A2/en
Priority to PCT/US2010/022950 priority patent/WO2011056247A2/en
Priority to AU2010315899A priority patent/AU2010315899A1/en
Priority to CN201080003926.6A priority patent/CN102333588B/en
Priority to MX2012004839A priority patent/MX337472B/en
Priority to CA2778767A priority patent/CA2778767A1/en
Priority to BR112012009792A priority patent/BR112012009792A2/en
Publication of WO2011056247A2 publication Critical patent/WO2011056247A2/en
Publication of WO2011056247A3 publication Critical patent/WO2011056247A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Catalysts and processes for forming catalysts for use in hydrogenating acetic acid to form ethanol. In one embodiment, the catalyst comprises a first metal, a silicaceous support, and at least one metasilicate support modifier. Preferably, the first metal is selected from the group consisting of copper, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, titanium, zinc, chromium, rhenium, molybdenum, and tungsten. In addition the catalyst may comprise a second metal preferably selected from the group consisting of copper, molybdenum, tin, chromium, iron, cobalt, vanadium, tungsten, palladium, platinum, lanthanum, cerium, manganese, ruthenium, rhenium, gold, and nickel.
PCT/US2010/022950 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid WO2011056247A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP10702393A EP2493606A2 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid
PCT/US2010/022950 WO2011056247A2 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid
AU2010315899A AU2010315899A1 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid
CN201080003926.6A CN102333588B (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid
MX2012004839A MX337472B (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid.
CA2778767A CA2778767A1 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid
BR112012009792A BR112012009792A2 (en) 2009-10-26 2010-02-02 catalysts for preparing ethanol from acetic acid

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
US12/588,727 2009-10-26
PCT/US2010/022950 WO2011056247A2 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid

Publications (2)

Publication Number Publication Date
WO2011056247A2 WO2011056247A2 (en) 2011-05-12
WO2011056247A3 true WO2011056247A3 (en) 2011-10-27

Family

ID=46506680

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/022950 WO2011056247A2 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid

Country Status (7)

Country Link
EP (1) EP2493606A2 (en)
CN (1) CN102333588B (en)
AU (1) AU2010315899A1 (en)
BR (1) BR112012009792A2 (en)
CA (1) CA2778767A1 (en)
MX (1) MX337472B (en)
WO (1) WO2011056247A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130197278A1 (en) * 2012-01-27 2013-08-01 Celanese International Corporation Process For Manufacturing Ethanol Using A Metallic Catalyst Supported on Titania
CN102600842A (en) * 2012-03-02 2012-07-25 山西盛驰科技有限公司 Catalyst for preparing ethanol through hydrogenation of acetic acid as well as preparation method and application thereof
US8536383B1 (en) 2012-03-14 2013-09-17 Celanese International Corporation Rhodium/tin catalysts and processes for producing ethanol
CN104043484B (en) * 2013-03-13 2016-10-12 中国石油天然气股份有限公司 A kind of acetic acid catalytic hydrogenation prepares the catalyst of ethanol and preparation thereof and application
CN103331167A (en) * 2013-07-19 2013-10-02 新地能源工程技术有限公司 Catalyst for directly preparing ethanol from acetic acid, preparation method and application
CN105258185A (en) * 2015-11-14 2016-01-20 无锡清杨机械制造有限公司 Range hood with air purifying function
CN105646143B (en) * 2016-02-23 2018-09-04 上海华谊（集团）公司 The method of acetic acid co-productiono f ethanol ethyl acetate
CN106345512B (en) * 2016-08-03 2019-03-05 江苏大学 A kind of bianry alloy catalyst and its preparation method and application
CN108358752A (en) * 2018-04-18 2018-08-03 肖锦 A kind of method of acetic acid hydrogenation ethyl alcohol
US20210300848A1 (en) * 2018-09-17 2021-09-30 Sabic Global Technologies B.V. Catalysts for producing alcohols and ethers from synthesis gas
DE112019004677T5 (en) * 2018-09-19 2021-12-30 Sabic Global Technologies B.V. BIMETALLIC CATALYSTS ON ZEOLITHES FOR THE SELECTIVE CONVERSION OF n-BUTANE INTO ETHANE

Citations (5)

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Publication number Priority date Publication date Assignee Title
US5137861A (en) * 1991-01-22 1992-08-11 Mobil Oil Corp. Catalyst comprising a hydrogenation metal and a delaminated layered silicate
US5945570A (en) * 1998-10-29 1999-08-31 Arhancet; Juan Pedro Catalyst and process for preparing 1,3-propanediol
US6049008A (en) * 1995-06-15 2000-04-11 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
EP1277826A1 (en) * 2001-07-18 2003-01-22 ATOFINA Research Hydrogenation and dehydrogenation processes and catalysts therefor
WO2010014153A2 (en) * 2008-07-31 2010-02-04 Celanese International Corporation Ethanol production from acetic acid utillizing a cobalt catalyst

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US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
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Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
US5137861A (en) * 1991-01-22 1992-08-11 Mobil Oil Corp. Catalyst comprising a hydrogenation metal and a delaminated layered silicate
US6049008A (en) * 1995-06-15 2000-04-11 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
US5945570A (en) * 1998-10-29 1999-08-31 Arhancet; Juan Pedro Catalyst and process for preparing 1,3-propanediol
EP1277826A1 (en) * 2001-07-18 2003-01-22 ATOFINA Research Hydrogenation and dehydrogenation processes and catalysts therefor
WO2010014153A2 (en) * 2008-07-31 2010-02-04 Celanese International Corporation Ethanol production from acetic acid utillizing a cobalt catalyst

Also Published As

Publication number Publication date
CN102333588B (en) 2014-04-09
MX337472B (en) 2016-03-04
CA2778767A1 (en) 2011-05-12
EP2493606A2 (en) 2012-09-05
CN102333588A (en) 2012-01-25
AU2010315899A1 (en) 2012-05-17
WO2011056247A2 (en) 2011-05-12
BR112012009792A2 (en) 2016-10-18
AU2010315899A2 (en) 2012-06-21
MX2012004839A (en) 2012-05-29

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