BR112012009792A2 - catalysts for preparing ethanol from acetic acid - Google Patents

catalysts for preparing ethanol from acetic acid

Info

Publication number
BR112012009792A2
BR112012009792A2 BR112012009792A BR112012009792A BR112012009792A2 BR 112012009792 A2 BR112012009792 A2 BR 112012009792A2 BR 112012009792 A BR112012009792 A BR 112012009792A BR 112012009792 A BR112012009792 A BR 112012009792A BR 112012009792 A2 BR112012009792 A2 BR 112012009792A2
Authority
BR
Brazil
Prior art keywords
catalysts
acetic acid
rhenium
ruthenium
palladium
Prior art date
Application number
BR112012009792A
Other languages
Portuguese (pt)
Inventor
Barbara F Kimmich
Heiko Weiner
James H Zink
John L Potts
Josefina T Chapman
Laiyuan Chen
Radmila Jevtic
Victor J Johnston
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US12/588,727 priority Critical patent/US8309772B2/en
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Priority to PCT/US2010/022950 priority patent/WO2011056247A2/en
Publication of BR112012009792A2 publication Critical patent/BR112012009792A2/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/64Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656Manganese, technetium or rhenium
    • B01J23/6567Rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0207Pretreatment of the support
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of products other than chlorine, adipic acid, caprolactam, or chlorodifluoromethane, e.g. bulk or fine chemicals or pharmaceuticals
    • Y02P20/52Improvements relating to the production of products other than chlorine, adipic acid, caprolactam, or chlorodifluoromethane, e.g. bulk or fine chemicals or pharmaceuticals using catalysts, e.g. selective catalysts

Abstract

catalisadores para preparar etanol a partir de acido acético. catalysts for preparing ethanol from acetic acid. a presente invenção refere-se a catalisadores e processos para formar catalisadores para uso em hidrogenação de ácido acético para formar etanol. The present invention relates to catalysts and processes for forming catalysts for use in hydrogenating acetic acid to form ethanol. em uma modalidade, o catalisador compreende um primeiro metal, um suporte de silicáceo, e pelo menos um modificador de suporte de metassilicato. In one embodiment, the catalyst comprises a first metal, a silicáceo support, and at least one metasilicate support modifier. preferivelmente, o primeiro metal é selecionado do grupo consistindo em cobre, ferro, cobalto, níquel, rutênio, ródio, paládio, ósmio, irídio, platina, titânio, zinco, cromo, rênio, molobdênio, e tungstênio. Preferably, the first metal is selected from the group consisting of copper, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, titanium, zinc, chromium, rhenium, molobdênio, and tungsten. em adição, o catalisador pode compreender um cobre, molibdênio, estanho, cromo, ferro, cobalto, vanáadio, tungstênio, paládio, platina, lantano, cério, manganês, rutênio, rênio, ouro, e níquel. in addition, the catalyst may comprise a copper, molybdenum, tin, chromium, iron, cobalt, vanáadio, tungsten, palladium, platinum, lanthanum, cerium, manganese, ruthenium, rhenium, gold, and nickel.
BR112012009792A 2008-07-31 2010-02-02 catalysts for preparing ethanol from acetic acid BR112012009792A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
PCT/US2010/022950 WO2011056247A2 (en) 2009-10-26 2010-02-02 Catalysts for making ethanol from acetic acid

Publications (1)

Publication Number Publication Date
BR112012009792A2 true BR112012009792A2 (en) 2016-10-18

Family

ID=46506680

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012009792A BR112012009792A2 (en) 2008-07-31 2010-02-02 catalysts for preparing ethanol from acetic acid

Country Status (7)

Country Link
EP (1) EP2493606A2 (en)
CN (1) CN102333588B (en)
AU (1) AU2010315899A1 (en)
BR (1) BR112012009792A2 (en)
CA (1) CA2778767A1 (en)
MX (1) MX337472B (en)
WO (1) WO2011056247A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130197278A1 (en) * 2012-01-27 2013-08-01 Celanese International Corporation Process For Manufacturing Ethanol Using A Metallic Catalyst Supported on Titania
CN102600842A (en) * 2012-03-02 2012-07-25 山西盛驰科技有限公司 Catalyst for preparing ethanol through hydrogenation of acetic acid as well as preparation method and application thereof
US8536383B1 (en) 2012-03-14 2013-09-17 Celanese International Corporation Rhodium/tin catalysts and processes for producing ethanol
CN104043484B (en) * 2013-03-13 2016-10-12 中国石油天然气股份有限公司 Ethanol, acetic acid A catalytic hydrogenation catalyst and its preparation and application
CN103331167A (en) * 2013-07-19 2013-10-02 新地能源工程技术有限公司 Catalyst for directly preparing ethanol from acetic acid, preparation method and application
CN105258185A (en) * 2015-11-14 2016-01-20 无锡清杨机械制造有限公司 Range hood with air purifying function
CN105646143B (en) * 2016-02-23 2018-09-04 上海华谊(集团)公司 Ethyl acetate, ethanol cogeneration system method
CN106345512B (en) * 2016-08-03 2019-03-05 江苏大学 A kind of bianry alloy catalyst and its preparation method and application

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
GB8707595D0 (en) 1987-03-31 1987-05-07 Bp Chem Int Ltd Chemical process
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US5137861A (en) * 1991-01-22 1992-08-11 Mobil Oil Corp. Catalyst comprising a hydrogenation metal and a delaminated layered silicate
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
US5977010A (en) * 1995-06-15 1999-11-02 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
US5945570A (en) 1998-10-29 1999-08-31 Arhancet; Juan Pedro Catalyst and process for preparing 1,3-propanediol
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
EP1277826A1 (en) * 2001-07-18 2003-01-22 ATOFINA Research Hydrogenation and dehydrogenation processes and catalysts therefor
US7608744B1 (en) * 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst

Also Published As

Publication number Publication date
CN102333588B (en) 2014-04-09
CA2778767A1 (en) 2011-05-12
WO2011056247A3 (en) 2011-10-27
CN102333588A (en) 2012-01-25
AU2010315899A2 (en) 2012-06-21
WO2011056247A2 (en) 2011-05-12
AU2010315899A1 (en) 2012-05-17
MX337472B (en) 2016-03-04
EP2493606A2 (en) 2012-09-05
MX2012004839A (en) 2012-05-29

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