MX2009010651A - 1,4-hidrogenacion de dienos con complejos de rutenio. - Google Patents

1,4-hidrogenacion de dienos con complejos de rutenio.

Info

Publication number
MX2009010651A
MX2009010651A MX2009010651A MX2009010651A MX2009010651A MX 2009010651 A MX2009010651 A MX 2009010651A MX 2009010651 A MX2009010651 A MX 2009010651A MX 2009010651 A MX2009010651 A MX 2009010651A MX 2009010651 A MX2009010651 A MX 2009010651A
Authority
MX
Mexico
Prior art keywords
hydrogenation
complexes
dienes
diene
alkene
Prior art date
Application number
MX2009010651A
Other languages
English (en)
Inventor
Philippe Dupau
Lucia Bonomo
Original Assignee
Firmenich & Cie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich & Cie filed Critical Firmenich & Cie
Publication of MX2009010651A publication Critical patent/MX2009010651A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se relaciona con el uso de complejos de Ru, que tienen un derivado de ciclopentadienilo y un dieno como ligando, junto con algunos aditivos ácidos para mejorar la selectividad en la 1,4-hidrogenación de dienos conjugados dentro del correspondiente "cis" -alcano como un producto principal, es decir, en donde los dos sustituyentes en la posición 2,3 del dieno está en una configuración cis en el alcano correspondiente.
MX2009010651A 2007-04-03 2008-04-02 1,4-hidrogenacion de dienos con complejos de rutenio. MX2009010651A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07105554 2007-04-03
PCT/IB2008/051227 WO2008120175A1 (en) 2007-04-03 2008-04-02 1,4-hydrogenation of dienes with ru complexes

Publications (1)

Publication Number Publication Date
MX2009010651A true MX2009010651A (es) 2009-10-22

Family

ID=38481915

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009010651A MX2009010651A (es) 2007-04-03 2008-04-02 1,4-hidrogenacion de dienos con complejos de rutenio.

Country Status (11)

Country Link
US (1) US8003838B2 (es)
EP (1) EP2142492B1 (es)
JP (1) JP5404599B2 (es)
CN (1) CN101641310B (es)
AT (1) ATE481373T1 (es)
BR (1) BRPI0811413B1 (es)
DE (1) DE602008002578D1 (es)
ES (1) ES2350465T3 (es)
IL (1) IL201347A (es)
MX (1) MX2009010651A (es)
WO (1) WO2008120175A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7494927B2 (en) * 2000-05-15 2009-02-24 Asm International N.V. Method of growing electrical conductors
US8025922B2 (en) 2005-03-15 2011-09-27 Asm International N.V. Enhanced deposition of noble metals
US7666773B2 (en) 2005-03-15 2010-02-23 Asm International N.V. Selective deposition of noble metal thin films
US20070014919A1 (en) * 2005-07-15 2007-01-18 Jani Hamalainen Atomic layer deposition of noble metal oxides
US7435484B2 (en) * 2006-09-01 2008-10-14 Asm Japan K.K. Ruthenium thin film-formed structure
US20090087339A1 (en) * 2007-09-28 2009-04-02 Asm Japan K.K. METHOD FOR FORMING RUTHENIUM COMPLEX FILM USING Beta-DIKETONE-COORDINATED RUTHENIUM PRECURSOR
CN102036941B (zh) 2008-05-20 2013-07-31 弗门尼舍有限公司 用于制备β-檀香醇及其衍生物的方法
US8084104B2 (en) * 2008-08-29 2011-12-27 Asm Japan K.K. Atomic composition controlled ruthenium alloy film formed by plasma-enhanced atomic layer deposition
US9379011B2 (en) 2008-12-19 2016-06-28 Asm International N.V. Methods for depositing nickel films and for making nickel silicide and nickel germanide
US20110020546A1 (en) * 2009-05-15 2011-01-27 Asm International N.V. Low Temperature ALD of Noble Metals
ES2541419T3 (es) 2011-02-16 2015-07-20 Firmenich Sa Intermedios para la preparación del beta-santalol
US8871617B2 (en) 2011-04-22 2014-10-28 Asm Ip Holding B.V. Deposition and reduction of mixed metal oxide thin films
BR112013029840A2 (pt) 2011-06-30 2016-12-06 Firmenich & Cie processo para a preparação de beta-santalol
ES2613091T3 (es) 2011-06-30 2017-05-22 Firmenich Sa Procedimiento de preparación de beta-santalol
BR112017011065A2 (pt) 2014-12-02 2018-02-27 Firmenich & Cie intermediários e processo para o preparo de componentes essenciais de óleo de sândalo
US9607842B1 (en) 2015-10-02 2017-03-28 Asm Ip Holding B.V. Methods of forming metal silicides
BR112019022269A2 (pt) 2017-04-27 2020-05-19 Deuteria Beverages Llc processo para a preparação de etanol deuterado a partir de d2
BR112019022276A2 (pt) 2017-04-27 2020-05-19 Deuteria Beverages Llc processo para a preparação de etanol deuterado a partir de d2o

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51125205A (en) * 1975-03-25 1976-11-01 T Hasegawa Co Ltd Precess for preparation of cis-3-hexenol and its derivatives
DE3337294A1 (de) * 1983-10-13 1985-04-25 Bayer Ag, 5090 Leverkusen Verfahren zur selektiven hydrierung von c-c-doppelbindungen in gegenwart von reduzierbaren, stickstoffhaltigen gruppen und neue ruthenium-komplexverbindungen
JPH0617326B2 (ja) * 1985-01-29 1994-03-09 三菱化成株式会社 共役ジエン類の部分水素化方法
JP2000136152A (ja) * 1998-08-26 2000-05-16 Takasago Internatl Corp ジエン化合物及びその製造方法
DE10240255A1 (de) * 2002-08-31 2004-03-11 Degussa Ag Verfahren zur Herstellung von cis-Alkenen und neue Katalysatoren hierfür
ES2309810T3 (es) 2004-11-11 2008-12-16 Firmenich Sa Sintesis de ciclopentonas.
ES2351059T3 (es) * 2007-04-03 2011-01-31 Acrostak Corp. Bvi Aleaciones basadas en magnesio.

Also Published As

Publication number Publication date
US20100099904A1 (en) 2010-04-22
ES2350465T3 (es) 2011-01-24
CN101641310A (zh) 2010-02-03
BRPI0811413A2 (pt) 2014-11-04
ATE481373T1 (de) 2010-10-15
BRPI0811413B1 (pt) 2017-02-14
IL201347A0 (en) 2010-05-31
IL201347A (en) 2013-03-24
JP2010523543A (ja) 2010-07-15
US8003838B2 (en) 2011-08-23
WO2008120175A1 (en) 2008-10-09
JP5404599B2 (ja) 2014-02-05
DE602008002578D1 (de) 2010-10-28
EP2142492B1 (en) 2010-09-15
CN101641310B (zh) 2013-07-24
EP2142492A1 (en) 2010-01-13

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