MX2007002333A - Catalizadores de alcoxilacion basados en alcalinoterreo. - Google Patents

Catalizadores de alcoxilacion basados en alcalinoterreo.

Info

Publication number
MX2007002333A
MX2007002333A MX2007002333A MX2007002333A MX2007002333A MX 2007002333 A MX2007002333 A MX 2007002333A MX 2007002333 A MX2007002333 A MX 2007002333A MX 2007002333 A MX2007002333 A MX 2007002333A MX 2007002333 A MX2007002333 A MX 2007002333A
Authority
MX
Mexico
Prior art keywords
esters
alkaline earth
fatty acids
alkaline
compounds
Prior art date
Application number
MX2007002333A
Other languages
English (en)
Inventor
George A Smith
Christopher J Whewell
James O'neill
George Sneed
Original Assignee
Huntsman Spec Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Spec Chem Corp filed Critical Huntsman Spec Chem Corp
Publication of MX2007002333A publication Critical patent/MX2007002333A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/27—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a liquid or molten state
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/23—Calcium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Fats And Perfumes (AREA)

Abstract

Se proporcionan en la presente catalizadores utiles al permitir y promover la insercion de oxidos alquileno en laces de ester. Los esteres empleados como un sustrato que se va alcoxilar incluyen esteres de acidos grasos, tal como esteres metilicos de acidos grasos de C14 a C22, y mono-di-, y tri-esteres de glicerina, incluyendo aceites vegetales, grasas animales y aceites de planta. Un catalizador de acuerdo a la invencion incluye al menos dos compuestos alcalinoterreos, que pueden incluir cualquier compuesto estable conocido de los alcalinoterreos, y contiene opcionalmente uno o mas materiales adicionales tal como un acido carboxilico o un polialquilenglicol que tiene un peso molecular entre aproximadamente 100 y 1500 o un polialquilenglicol rematado con C1 - C10 que tiene un peso molecular entre aproximadamente 100 y 1500, que se ha acidificado con un acido mineral fuerte. Los alcalinoterreos preferidos empleados son sales y compuestos de magnesio y calcio.
MX2007002333A 2004-08-26 2005-05-31 Catalizadores de alcoxilacion basados en alcalinoterreo. MX2007002333A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US60465604P 2004-08-26 2004-08-26
PCT/US2005/019050 WO2006025898A1 (en) 2004-08-26 2005-05-31 Alkaline earth-based alkoxylation catalysts

Publications (1)

Publication Number Publication Date
MX2007002333A true MX2007002333A (es) 2007-05-11

Family

ID=36000373

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2007002333A MX2007002333A (es) 2004-08-26 2005-05-31 Catalizadores de alcoxilacion basados en alcalinoterreo.

Country Status (9)

Country Link
US (1) US7629487B2 (es)
EP (1) EP1778397B1 (es)
JP (1) JP4977609B2 (es)
KR (1) KR101208742B1 (es)
CN (1) CN101374599B (es)
AU (1) AU2005280592B2 (es)
CA (1) CA2577935C (es)
MX (1) MX2007002333A (es)
WO (1) WO2006025898A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2349974A1 (en) * 2008-10-29 2011-08-03 Shell Internationale Research Maatschappij B.V. Process for the preparation of acylated secondary alcohol alkoxylates and secondary alcohol alkoxylates
US9056828B2 (en) 2010-09-02 2015-06-16 Kolb Distribution Ltd. Alkoxylation method of fatty acid alkyl esters
CN103124764B (zh) 2010-09-30 2014-12-24 亨斯迈石油化学有限责任公司 衍生自基于生物柴油的烷基化芳族化合物的表面活性剂
BR112013009971A2 (pt) * 2010-10-25 2016-08-02 Stepan Co composição de éster graxo alcoxilado, derivado feito por sulfonação ou sulfitação da composição, emulsificante aniônico e não aniônico para composições agrícolas, solvente agrícola. composição de herbicida solúvel em água, composição antimicrobiana, limpador de superfície áspera aquoso, sabonete e detergente para vestuário sujo
SG11201406438WA (en) * 2012-04-13 2014-12-30 Lion Corp Alkoxylation catalyst, method for producing catalyst, and method for producing fatty acid alkyl ester alkoxylate using catalyst
MY188147A (en) * 2014-04-24 2021-11-24 Lion Corp Method for producing fatty acid alkyl ester alkoxylate
CN105498842B (zh) * 2014-09-25 2018-06-08 中国石油化工股份有限公司 脂肪酸甲酯乙氧基化催化剂及其应用
JP6403325B2 (ja) * 2014-12-26 2018-10-10 ライオン株式会社 脂肪酸アルキルエステルアルコキシレートの製造方法
US10315189B2 (en) 2015-09-04 2019-06-11 Lion Corporation Ethoxylation catalyst and manufacturing method therefor
CN107442173B (zh) * 2016-05-30 2020-10-16 中国石油化工股份有限公司 脂肪酸甲酯乙氧基化催化剂

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302613A (en) * 1980-08-22 1981-11-24 Conoco Inc. Inorganic catalyst for alkoxylation of alcohols
US4375464A (en) * 1981-11-19 1983-03-01 Ayerst, Mckenna & Harrison Inc. Antibiotic AY24,668 and process of preparation
US4375564A (en) * 1981-12-23 1983-03-01 Shell Oil Company Alkoxylation process
EP0085167A1 (en) * 1981-12-24 1983-08-10 Conoco Phillips Company Alkoxylation with calcium and magnesium salts
US4453022A (en) * 1982-04-21 1984-06-05 Union Carbide Corporation Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts
WO1985000365A1 (en) 1983-07-05 1985-01-31 Union Carbide Corporation Alkoxylation using calcium catalysts and products therefrom
US4775653A (en) * 1987-04-28 1988-10-04 Vista Chemical Company Alkoxylation process using calcium based catalysts
DE68904474T2 (de) * 1988-06-09 1993-05-13 Shell Int Research Durch verbindungen der seltenerdmetalle katalysiertes alkoxylationsverfahren.
JPH03229641A (ja) * 1990-02-01 1991-10-11 Union Carbide Chem & Plast Co Inc 改質したカルシウム含有バイメタル又はポリメタル触媒を使用するアルコキシル化方法
US5191104A (en) * 1990-09-20 1993-03-02 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation of carboxylated compounds
US5110991A (en) 1991-04-01 1992-05-05 Texaco Chemical Company Heterogeneous catalyst for alkoxylation of alcohols
US5220046A (en) * 1991-08-22 1993-06-15 Vista Chemical Company Process for alkoxylation of esters and products produced therefrom
PL166429B1 (pl) 1992-01-10 1995-05-31 Inst Ciezkiej Syntezy Orga Katalizator procesu oksyetylenowania
US5627121A (en) * 1995-06-15 1997-05-06 Condea Vista Company Process for preparing alkoxylation catalysts and alkoxylation process
PL343853A1 (en) 2000-11-13 2002-05-20 Inst Ciezkiej Syntezy Orga Oxyalkylenation catalyst and method of obtaining same
US7119236B2 (en) * 2004-04-27 2006-10-10 Harcros Chemicals Inc. Method of preparing alkoxylation catalysts and their use in alkoxylation processes

Also Published As

Publication number Publication date
JP2008510614A (ja) 2008-04-10
KR20070046142A (ko) 2007-05-02
EP1778397B1 (en) 2018-08-29
US7629487B2 (en) 2009-12-08
CN101374599B (zh) 2013-01-09
US20080249330A1 (en) 2008-10-09
JP4977609B2 (ja) 2012-07-18
KR101208742B1 (ko) 2012-12-05
EP1778397A4 (en) 2008-08-27
CN101374599A (zh) 2009-02-25
CA2577935A1 (en) 2006-03-09
AU2005280592A1 (en) 2006-03-09
WO2006025898A1 (en) 2006-03-09
AU2005280592B2 (en) 2011-10-13
EP1778397A1 (en) 2007-05-02
CA2577935C (en) 2013-02-12

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