MX171249B - Procedimiento para la desnitrogenacion de los gases residuales con la obtencion de hno3 - Google Patents

Procedimiento para la desnitrogenacion de los gases residuales con la obtencion de hno3

Info

Publication number
MX171249B
MX171249B MX025763A MX2576391A MX171249B MX 171249 B MX171249 B MX 171249B MX 025763 A MX025763 A MX 025763A MX 2576391 A MX2576391 A MX 2576391A MX 171249 B MX171249 B MX 171249B
Authority
MX
Mexico
Prior art keywords
obtaining
hno3
denitrogenation
procedure
residual gases
Prior art date
Application number
MX025763A
Other languages
English (en)
Inventor
Wedigo Von Wedel
Elke Senff
Oswald Llelmling
Original Assignee
Degussa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa filed Critical Degussa
Publication of MX171249B publication Critical patent/MX171249B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/38—Nitric acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

La presente invención se refiere a procedimiento para la eliminación de óxidos de nitrógeno en especial de NO y/o NO2 de los gases residuales especialmente de instalaciones industriales y de combustión, y la obtención de ácido nítrico, caracterizado porque, se determina el contenido en los gases residuales de los óxidos de nitrógeno, se mezcla el gas residual con una solución en estado gaseoso que contiene peróxido de hidrógeno de acuerdo con la cantidad medida de los óxidos de nitrógeno a eliminar, según la estequiometría de las ecuaciones de reacción 2 NO + H2O2 ----2 HNO3 + 2 H2O o bien 2 NO2 + H2O2----2 HNO3 en caso dado en exceso, se transforma la mezcla de gases a su temperatura o de preferencia llevándola a una temperatura de 20 - 120 grados C, en preencia de catalizador sólido que debido a la superficie exterior y/o debido a una superficie interior aumentada presenta por lo menos capacidad de absorción con respecto al H2O2, no descomponiendolo o no descomponiendolo mayormente y la mezcla de gas transformada o la parte contenida en ella de la mezcla gaseosa de HNO3H2O formada es derivada en la elaboración subsiguiente según metodos en sí conocidos para formar ácido nítrico.
MX025763A 1990-05-12 1991-05-13 Procedimiento para la desnitrogenacion de los gases residuales con la obtencion de hno3 MX171249B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4015284A DE4015284C1 (es) 1990-05-12 1990-05-12

Publications (1)

Publication Number Publication Date
MX171249B true MX171249B (es) 1993-10-13

Family

ID=6406263

Family Applications (1)

Application Number Title Priority Date Filing Date
MX025763A MX171249B (es) 1990-05-12 1991-05-13 Procedimiento para la desnitrogenacion de los gases residuales con la obtencion de hno3

Country Status (14)

Country Link
US (1) US5112587A (es)
EP (1) EP0457059B1 (es)
JP (1) JPH04227819A (es)
AT (1) ATE102848T1 (es)
AU (1) AU639100B2 (es)
BR (1) BR9101952A (es)
CA (1) CA2042464A1 (es)
CS (1) CS138091A3 (es)
DE (3) DE4015284C1 (es)
ES (1) ES2054597T1 (es)
HU (1) HUT57631A (es)
MX (1) MX171249B (es)
PT (1) PT97644A (es)
ZA (1) ZA913560B (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4015284C1 (es) * 1990-05-12 1992-01-16 Degussa Ag, 6000 Frankfurt, De
EP0548499B1 (de) * 1991-11-02 1995-09-13 Degussa Aktiengesellschaft Verfahren zur oxidativen Reinigung von Stickoxide enthaltenden Abgasen
DE4216772A1 (de) * 1992-05-21 1993-12-16 Ftu Forschung Und Tech Entwick Verfahren zur Reinigung von Gasen und Abgasen mit Oxidationsmitteln
EP0620037A3 (de) * 1993-04-16 1995-04-05 Alexander Michailow Verfahren und Vorrichtung zum Reinigen von Luft.
JP2700602B2 (ja) * 1993-04-23 1998-01-21 川崎重工業株式会社 煤による燃焼ガスの脱硝方法及び装置
US5980847A (en) * 1995-04-24 1999-11-09 Mitsubishi Materials Corporation Method for removing nitrogen oxide
DE19516253A1 (de) * 1995-04-26 1996-10-31 Grace Gmbh Mattierungsmittel auf Basis von aggregiertem Siliciumdioxid mit verbesserter Effizienz
DE19607389A1 (de) * 1996-02-28 1997-09-04 Krupp Vdm Gmbh Verfahren zur Absorption von Stickoxiden aus Abgasströmen
US5637282A (en) * 1996-04-09 1997-06-10 Seh America, Inc. Nitrogen oxide scrubbing with alkaline peroxide solution
FI104793B (fi) * 1998-05-11 2000-04-14 Ahlstrom Machinery Oy Menetelmä typen oksidien poistamiseksi talteenottokattilan savukaasuista
US6325983B1 (en) 2000-04-19 2001-12-04 Seh America, Inc. Nox scrubbing system and method
US6306197B1 (en) 2000-04-19 2001-10-23 Seh America, Inc. Isopropyl alcohol scrubbing system
NO20005846L (no) * 2000-11-17 2002-05-21 Groenn Kraft As Fremgangsmåte ved forbrenning av organisk materiale
US6793903B1 (en) 2001-03-08 2004-09-21 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration High temperature decomposition of hydrogen peroxide
KR20020081940A (ko) * 2001-04-20 2002-10-30 조규만 과산화수소, 알코올 또는 과산화수소수와 알코올의혼합물을 이용한 질소산화물 저감 및 처리 방법
US7404938B2 (en) * 2004-05-11 2008-07-29 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Emission control system
US7582271B2 (en) * 2004-05-11 2009-09-01 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Emission control system
EP2440756B1 (en) * 2009-05-15 2017-12-13 PeroxyChem LLC COMBUSTION FLUE GAS NOx TREATMENT
CN103877838B (zh) * 2014-01-16 2017-08-15 湖北益泰药业有限公司 一种提高葡醛内酯生产中硝酸回收率的方法
CN106076102B (zh) * 2016-08-16 2018-06-19 金川集团股份有限公司 一种处理冷凝酸中氮氧化物的装置及方法
CN110385024A (zh) * 2019-08-28 2019-10-29 华能国际电力股份有限公司 一种适用于高温区的多效coa系统
CN111545040B (zh) * 2020-04-10 2022-09-23 佛山华清智业环保科技有限公司 一种复合脱硝剂及其制备方法
CN111672311A (zh) * 2020-06-23 2020-09-18 山东蓝帆化工有限公司 一种三废工段烟气提标改造系统

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1509974A (en) * 1974-08-21 1978-05-10 Mitsubishi Heavy Ind Ltd Oxidation of nitric oxide
JPS53119296A (en) * 1977-03-28 1978-10-18 Mizusawa Industrial Chem Method of recovering nitric acid from nitrates
DE2818473C2 (de) * 1978-04-27 1984-01-05 Nukem Gmbh, 6450 Hanau Verfahren und Vorrichtung zur Entfernung von nitrosen Gasen aus Abluft und Abgasen
US4341747A (en) * 1978-08-15 1982-07-27 Fmc Corporation Process of removing nitrogen oxides from gaseous mixtures
US4367204A (en) * 1979-05-04 1983-01-04 Budapesti Muszaki Egyetem Process for the recirculation of nitrogen oxides
DE3642468A1 (de) * 1986-11-26 1988-06-09 Hoelter Heinz Simultane abscheidung von so(pfeil abwaerts)2(pfeil abwaerts) und no(pfeil abwaerts)x(pfeil abwaerts) in einem systemschritt mit getrennter additiv-zugabe
CH673409A5 (es) * 1987-07-09 1990-03-15 Escher Wyss Gmbh
DE4015284C1 (es) * 1990-05-12 1992-01-16 Degussa Ag, 6000 Frankfurt, De

Also Published As

Publication number Publication date
US5112587A (en) 1992-05-12
BR9101952A (pt) 1991-12-24
ES2054597T1 (es) 1994-08-16
EP0457059A1 (de) 1991-11-21
ATE102848T1 (de) 1994-04-15
DE59101183D1 (de) 1994-04-21
PT97644A (pt) 1992-03-31
ZA913560B (en) 1992-02-26
DE4015284C1 (es) 1992-01-16
EP0457059B1 (de) 1994-03-16
CA2042464A1 (en) 1991-11-13
HU911575D0 (en) 1991-11-28
JPH04227819A (ja) 1992-08-17
AU7701291A (en) 1991-11-14
DE4136183C1 (en) 1993-04-08
CS138091A3 (en) 1992-02-19
AU639100B2 (en) 1993-07-15
HUT57631A (en) 1991-12-30

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