MX166320B - Proceso para la produccion de hidrocarburos pesados a partir de hidrocarburos gaseosos ligeros - Google Patents

Proceso para la produccion de hidrocarburos pesados a partir de hidrocarburos gaseosos ligeros

Info

Publication number
MX166320B
MX166320B MX014749A MX1474989A MX166320B MX 166320 B MX166320 B MX 166320B MX 014749 A MX014749 A MX 014749A MX 1474989 A MX1474989 A MX 1474989A MX 166320 B MX166320 B MX 166320B
Authority
MX
Mexico
Prior art keywords
hydrocarbons
hydrogen
gas stream
light
carbon dioxide
Prior art date
Application number
MX014749A
Other languages
English (en)
Inventor
Kenneth L Agee
Original Assignee
Gtg Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gtg Inc filed Critical Gtg Inc
Publication of MX166320B publication Critical patent/MX166320B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485—Set-up of reactors or accessories; Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para la producción de hidrocarburos pesados a partir de uno o más hidrocarburos gaseosos ligeros, en el cual los hidrocarburos gaseosos se oxidan parcialmente a monóxido de carbono e hidrógeno, los cuales después se hacen reaccionar catalíticamente para formar los hidrocarburos pesados, el proceso para la producción de hidrocarburos pesados a partir de uno o más hidrocarburos gaseosos ligeros está caracterizado porque comprende las etapas de: a) hacer reaccionar los hidrocarburos gaseosos ligeros con aire parcialmente, para oxidar parcialmente una porción de ellos y producir una corriente de gases que consiste de hidrocarburos ligeros que no reaccionaron, hidrógeno, monóxido de carbono y nitrógeno; b) hacer reaccionar la corriente de gases de la etapa (a) con vapor de agua dióxido de carbono en presencia de un catalizador para la reformación con vapor de agua para convertir una porción substancial de los hidrocarburos ligeros que no reaccionaron allí a hidrógeno y monóxido de carbono adicionales y para producir una corriente de gas de síntesis que contiene hidrógeno y monóxido de carbono en la proporción deseada; c) hacer reaccionar la corriente de gas de síntesis de la etapa (b) en presencia de un catalizador para la síntesis de hidrocarburos que contiene cobalto para formar hidrocarburos más pesados y agua a partir de hidrógeno y monóxido de carbono que se encuentran en la corriente; d) separar los hidrocarburos más pesados y el agua de la corriente de productos de la etapa (c) dejando una corriente de gases residuales que consiste de hidrógeno y monóxido de carbono que no reaccionaron, hidrocarburos ligeros, dióxido de carbono y nitrógeno; e) someter a la corriente de gases residuales de la etapa (d) a una combustión catalítica con aire adicional para formar una corriente de producto que consiste de dióxido de carbono, vapor de agua y nitrógeno; f) separar el dióxido de carbono de la corriente de productos de la etapa (e); y g) utilizar por lo menos una porción del dióxido de carbono separado en la etapa (f) para llevar a cabo la etapa (b).
MX014749A 1988-02-05 1989-02-02 Proceso para la produccion de hidrocarburos pesados a partir de hidrocarburos gaseosos ligeros MX166320B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/152,878 US4833170A (en) 1988-02-05 1988-02-05 Process and apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons

Publications (1)

Publication Number Publication Date
MX166320B true MX166320B (es) 1992-12-29

Family

ID=22544838

Family Applications (1)

Application Number Title Priority Date Filing Date
MX014749A MX166320B (es) 1988-02-05 1989-02-02 Proceso para la produccion de hidrocarburos pesados a partir de hidrocarburos gaseosos ligeros

Country Status (9)

Country Link
US (1) US4833170A (es)
CN (1) CN1018916B (es)
AU (1) AU611525B2 (es)
CA (1) CA1294989C (es)
GB (1) GB2215345B (es)
MX (1) MX166320B (es)
MY (1) MY105861A (es)
NL (1) NL193831C (es)
NO (1) NO177346C (es)

Families Citing this family (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9028034D0 (en) * 1990-12-24 1991-02-13 Isis Innovation Improved processes for the conversion of methane to synthesis gas
US5204900A (en) * 1991-03-04 1993-04-20 Pires H George Coding system for descrambling video
NZ242569A (en) † 1991-05-30 1994-07-26 British Petroleum Co Plc Process for the conversion of natural gas into higher hydrocarbons by reforming combined with a fischer-tropsch process
NO934505L (no) * 1992-12-10 1994-06-13 Foster Wheeler Energy Ltd Fremgangsmåte for fremstilling av en organisk væske
US5342702A (en) * 1993-01-05 1994-08-30 Integrated Energy Development Corp. Synergistic process for the production of carbon dioxide using a cogeneration reactor
US5416245A (en) * 1993-11-12 1995-05-16 Integrated Energy Development Corp. Synergistic process for the production of methanol
US5690482A (en) * 1994-11-04 1997-11-25 Integrated Energy Development Corp. Process for the combustion of sulphur containing fuels
US7576296B2 (en) * 1995-03-14 2009-08-18 Battelle Energy Alliance, Llc Thermal synthesis apparatus
US5944104A (en) * 1996-01-31 1999-08-31 Vastar Resources, Inc. Chemically induced stimulation of subterranean carbonaceous formations with gaseous oxidants
US5964290A (en) * 1996-01-31 1999-10-12 Vastar Resources, Inc. Chemically induced stimulation of cleat formation in a subterranean coal formation
US5967233A (en) * 1996-01-31 1999-10-19 Vastar Resources, Inc. Chemically induced stimulation of subterranean carbonaceous formations with aqueous oxidizing solutions
US5769165A (en) * 1996-01-31 1998-06-23 Vastar Resources Inc. Method for increasing methane recovery from a subterranean coal formation by injection of tail gas from a hydrocarbon synthesis process
US5865248A (en) * 1996-01-31 1999-02-02 Vastar Resources, Inc. Chemically induced permeability enhancement of subterranean coal formation
US6313361B1 (en) * 1996-02-13 2001-11-06 Marathon Oil Company Formation of a stable wax slurry from a Fischer-Tropsch reactor effluent
US6201029B1 (en) 1996-02-13 2001-03-13 Marathon Oil Company Staged combustion of a low heating value fuel gas for driving a gas turbine
US5733941A (en) * 1996-02-13 1998-03-31 Marathon Oil Company Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid
US5861441A (en) * 1996-02-13 1999-01-19 Marathon Oil Company Combusting a hydrocarbon gas to produce a reformed gas
US6130259A (en) * 1996-02-13 2000-10-10 Marathon Oil Company Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid
WO1997048639A1 (en) * 1996-06-21 1997-12-24 Syntroleum Corporation Synthesis gas production system and method
MY118075A (en) 1996-07-09 2004-08-30 Syntroleum Corp Process for converting gas to liquids
US5950732A (en) 1997-04-02 1999-09-14 Syntroleum Corporation System and method for hydrate recovery
AU9690298A (en) 1997-10-10 1999-05-03 Syntroleum Corporation System and method for converting light hydrocarbons to heavier hydrocarbons withseparation of water into oxygen and hydrogen
US6056793A (en) * 1997-10-28 2000-05-02 University Of Kansas Center For Research, Inc. Blended compression-ignition fuel containing light synthetic crude and blending stock
US6534552B2 (en) 1998-03-31 2003-03-18 Rentech, Inc. Producing liquid hydrocarbons from natural gas
RU2143417C1 (ru) * 1998-07-27 1999-12-27 Институт катализа им.Г.К.Борескова СО РАН Способ получения моторных топлив из углеродсодержащего сырья
CN1073618C (zh) * 1998-11-18 2001-10-24 中国石油化工集团公司 一种重质烃类加氢裂化催化剂及其制备和应用
US6262131B1 (en) * 1998-12-07 2001-07-17 Syntroleum Corporation Structured fischer-tropsch catalyst system and method
AU762733B2 (en) * 1999-03-30 2003-07-03 Syntroleum Corporation System and method for converting light hydrocarbons into heavier hydrocarbons with a plurality of synthesis gas subsystems
US6156809A (en) * 1999-04-21 2000-12-05 Reema International Corp. Multiple reactor system and method for fischer-tropsch synthesis
US6265453B1 (en) 1999-07-01 2001-07-24 Syntroleum Corporation Hydrocarbon conversion system with enhanced combustor and method
US6451864B1 (en) * 1999-08-17 2002-09-17 Battelle Memorial Institute Catalyst structure and method of Fischer-Tropsch synthesis
ATE311425T1 (de) * 1999-08-17 2005-12-15 Battelle Memorial Institute Katalysatorstruktur und fischer- tropschsyntheseverfahren
WO2001046067A1 (en) * 1999-12-21 2001-06-28 Bechtel Bwxt Idaho, Llc Hydrogen and elemental carbon production from natural gas and other hydrocarbons
US6512018B2 (en) 2000-03-28 2003-01-28 Syntroleum Corporation Hydrocarbon conversion process using a plurality of synthesis gas sources
EP1156026A1 (en) * 2000-05-19 2001-11-21 Shell Internationale Researchmaatschappij B.V. Process for the production of liquid hydrocarbons
US7125540B1 (en) 2000-06-06 2006-10-24 Battelle Memorial Institute Microsystem process networks
GB0027575D0 (en) 2000-11-10 2000-12-27 Sasol Tech Pty Ltd Production of liquid hydrocarbon roducts
MY137714A (en) * 2001-05-29 2009-02-27 Shell Int Research Method to start a process for hydrocarbons
MY139324A (en) * 2001-06-25 2009-09-30 Shell Int Research Integrated process for hydrocarbon synthesis
EA005967B1 (ru) * 2001-08-24 2005-08-25 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения углеводородов
MY128179A (en) * 2001-10-05 2007-01-31 Shell Int Research System for power generation in a process producing hydrocarbons
EP1306632A1 (en) * 2001-10-25 2003-05-02 Shell Internationale Researchmaatschappij B.V. Process for liquefying natural gas and producing liquid hydrocarbons
US20030130510A1 (en) * 2001-12-28 2003-07-10 Nippon Shokubai Co., Ltd. Process for producing N-hydroxyalkyl compound, and tris (2-hydroxyethyl) isocyanurate composition
MY134898A (en) * 2002-01-25 2007-12-31 Sheel Internationale Res Mij B V Method for the preparation of lower olefines by steam cracking
US20030178195A1 (en) * 2002-03-20 2003-09-25 Agee Mark A. Method and system for recovery and conversion of subsurface gas hydrates
US6794417B2 (en) 2002-06-19 2004-09-21 Syntroleum Corporation System and method for treatment of water and disposal of contaminants produced by converting lighter hydrocarbons into heavier hydrocarbon
CA2493912A1 (en) * 2002-07-19 2004-01-29 Shell Internationale Research Maatschappij B.V. Process for combustion of a liquid hydrocarbon
US20050203195A1 (en) * 2003-08-05 2005-09-15 Yong Wang Tailored Fischer-Tropsch synthesis product distribution
US20060189702A1 (en) 2003-08-06 2006-08-24 Tomlinson H L Movable gas-to-liquid system and process
US20050106086A1 (en) * 2003-08-06 2005-05-19 Tomlinson H. L. Movable gas-to-liquid system and process
WO2005019100A1 (en) * 2003-08-22 2005-03-03 Syntroleum Corporation Process for production of synthesis gas using an oxygen-containing gas
EP1658354B1 (en) * 2003-08-22 2008-12-17 Sasol Technology (Proprietary) Limited Process for synthesising hydrocarbons
US6982355B2 (en) * 2003-08-25 2006-01-03 Syntroleum Corporation Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins
WO2005070818A1 (en) * 2004-01-08 2005-08-04 Syntroleum Corporation Processes for starting up an autothermal reformer
WO2006058107A1 (en) 2004-11-22 2006-06-01 Syntroleum Corporation Movable gas-to-liquid system and process
US20070254968A1 (en) * 2006-04-27 2007-11-01 Syntroleum Corporation Method of delivery, replacement, and removal of fischer-tropsch catalyst
US20070259973A1 (en) * 2006-05-03 2007-11-08 Syntroleum Corporation Optimized hydrocarbon synthesis process
US20080021118A1 (en) * 2006-07-21 2008-01-24 Syntroleum Corporation Hydrocarbon recovery in the fischer-tropsch process
CN101657523B (zh) * 2007-07-10 2013-07-17 千代田化工建设株式会社 由天然气制造煤油-瓦斯油的制造工艺中的合成气的制造方法
US20100056648A1 (en) * 2008-07-24 2010-03-04 Schroer Joseph W Processes and systems for production of liquefied petroleum gas (LPG)
US20110104045A1 (en) * 2009-11-05 2011-05-05 Air Liquide Process And Construction, Inc. Hydrogen Production With CO2 Capture
CN104024182A (zh) * 2011-09-08 2014-09-03 强能公司 在gtl环境中用于制备烃类燃料的增强的费-托法
US9096803B2 (en) * 2012-03-30 2015-08-04 General Electric Company Systems and methods for converting gases to liquids
US10005963B2 (en) * 2012-09-20 2018-06-26 University Of South Florida Systems and methods for producing liquid fuels from landfill gases
US10736391B2 (en) * 2016-10-10 2020-08-11 Yeti Coolers, Llc Bag
USD853115S1 (en) 2018-01-22 2019-07-09 Yeti Coolers, Llc Duffel bag
USD851400S1 (en) 2018-03-08 2019-06-18 Yeti Coolers, Llc Duffel bag

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2552308A (en) * 1949-06-16 1951-05-08 Standard Oil Dev Co Low-pressure hydrocarbon synthesis process
US2686195A (en) * 1949-12-10 1954-08-10 Standard Oil Dev Co Hydrocarbon synthesis
US2683121A (en) * 1951-11-28 1954-07-06 Kellogg M W Co Preparation of hydrocarbon synthesis gas
US3549335A (en) * 1965-10-22 1970-12-22 Braun & Co C F Autothermal reactor
US3888043A (en) * 1973-06-25 1975-06-10 Texaco Inc Production of methane
US4074981A (en) * 1976-12-10 1978-02-21 Texaco Inc. Partial oxidation process
JPS55154314A (en) * 1979-05-18 1980-12-01 Toyo Eng Corp Joint production of methanol and ammonia
CA1234158A (en) * 1983-11-15 1988-03-15 Johannes K. Minderhoud Process for the preparation of hydrocarbons
CA1240708A (en) * 1983-11-15 1988-08-16 Johannes K. Minderhoud Process for the preparation of hydrocarbons
US4579986A (en) * 1984-04-18 1986-04-01 Shell Oil Company Process for the preparation of hydrocarbons
CA1241667A (en) * 1984-04-25 1988-09-06 Martin F.M. Post Process for the preparation of hydrocarbons

Also Published As

Publication number Publication date
AU2883789A (en) 1989-08-10
NL193831B (nl) 2000-08-01
US4833170A (en) 1989-05-23
NO177346C (no) 1995-08-30
MY105861A (en) 1995-02-28
CN1018916B (zh) 1992-11-04
NO177346B (no) 1995-05-22
NL193831C (nl) 2000-12-04
CN1036556A (zh) 1989-10-25
CA1294989C (en) 1992-01-28
GB2215345B (en) 1991-07-31
GB2215345A (en) 1989-09-20
NO890459D0 (no) 1989-02-03
NO890459L (no) 1989-08-07
AU611525B2 (en) 1991-06-13
NL8900255A (nl) 1989-09-01
GB8902597D0 (en) 1989-03-22

Similar Documents

Publication Publication Date Title
MX166320B (es) Proceso para la produccion de hidrocarburos pesados a partir de hidrocarburos gaseosos ligeros
KR102596291B1 (ko) 메탄올과 암모니아를 병렬식으로 동시 제조하는 과정
DE69225089D1 (de) Verfahren zur Umsetzung von Erdgas in höhere Kohlenwasserstoffe
RU2008136698A (ru) Способ получения углеводородных продуктов
WO1991012224A3 (en) Circulating bed cofeed conversion reactor and method for converting light hydrocarbons to olefins, gasoline and methanol
DE50305928D1 (de) Verfahren zur Erzeugung von Kohlenmonoxid und Methanol
CA1269819C (en) CONTINUATION OF ABSORPTION STEPS FOR HYDROGEN PURIFICATION
DE69704147D1 (de) Verfahren zur katalytischen Teiloxidation eines Kohlenwasserstoffs
NO821979L (no) Fremgangsmaate ved fremstilling av metanol.
ES547666A0 (es) Un procedimiento para la produccion de gas de sintesis con una relacion h2-co aumentada a partir de hidrocarburos nor- malmente gaseosos
EA202191886A1 (ru) Способ производства метанола с более высокой утилизацией углерода за счет рецикла co2
JP2003212524A (ja) 空気からのクリプトン及びキセノン回収方法
RU2012102457A (ru) Способ получения углеводородов из синтез-газа
ATE312066T1 (de) Verfahren zur herstellung von hydroformylierungsprodukten von olefinen mit 2 bis 8 kohlenstoffatomen
CA2173802A1 (en) Integrated Steam Methane Reforming Process for Producing Carbon Monoxide and Hydrogen
EA200400077A1 (ru) Интегрированный способ получения углеводородов
AR241177A1 (es) Procedimiento de preparacion de amoniaco y anhidrido carbonico.
DE3382207D1 (de) Verfahren zur herstellung von methanol.
RU2004138790A (ru) Способ получения углеводородов из газообразного углеводородного сырья
BR8604040A (pt) Processo para a preparacao de gas de sintese a partir de uma alimentacao contendo hidrocarbonetos e gas de sintese
ES2100478T3 (es) Fabricacion de liquidos organicos.
CA2412057A1 (en) Apparatus and method for production of methanethiol
AU3264901A (en) Spox-enhanced process for production of synthesis gas
WO2002085782A8 (fr) Procede d'oxydation partielle catalytique d'hydrocarbures pour la production de gaz de synthese a faible rapport h2/co
GB1513267A (en) Ammonia synthesis