MX154813A - Procedimiento mejorado para separar triorganofosfina de una composicion liquida que contiene rodio - Google Patents

Procedimiento mejorado para separar triorganofosfina de una composicion liquida que contiene rodio

Info

Publication number
MX154813A
MX154813A MX182411A MX18241180A MX154813A MX 154813 A MX154813 A MX 154813A MX 182411 A MX182411 A MX 182411A MX 18241180 A MX18241180 A MX 18241180A MX 154813 A MX154813 A MX 154813A
Authority
MX
Mexico
Prior art keywords
triorganophosphine
rhodium
separating
liquid composition
containing liquid
Prior art date
Application number
MX182411A
Other languages
English (en)
Inventor
David Robert Bryant
Richard Allen Galley
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of MX154813A publication Critical patent/MX154813A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4053Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4023Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/025Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • C07F9/505Preparation; Separation; Purification; Stabilisation
    • C07F9/5095Separation; Purification; Stabilisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255Phosphorus containing compounds
    • B01J31/0267Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
MX182411A 1979-05-21 1980-05-20 Procedimiento mejorado para separar triorganofosfina de una composicion liquida que contiene rodio MX154813A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US4091379A 1979-05-21 1979-05-21
US06/108,279 US4283304A (en) 1979-05-21 1979-12-28 Process for removing triorganophosphine from a liquid composition

Publications (1)

Publication Number Publication Date
MX154813A true MX154813A (es) 1987-12-15

Family

ID=26717593

Family Applications (1)

Application Number Title Priority Date Filing Date
MX182411A MX154813A (es) 1979-05-21 1980-05-20 Procedimiento mejorado para separar triorganofosfina de una composicion liquida que contiene rodio

Country Status (13)

Country Link
US (1) US4283304A (es)
EP (1) EP0019296B1 (es)
JP (1) JPS6026397B2 (es)
KR (1) KR840001926B1 (es)
AT (1) ATE3210T1 (es)
AU (1) AU5851780A (es)
BR (1) BR8003134A (es)
CA (1) CA1139312A (es)
DE (1) DE3062948D1 (es)
ES (1) ES8104313A1 (es)
MX (1) MX154813A (es)
PL (1) PL128785B1 (es)
ZA (1) ZA802603B (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4374278A (en) * 1980-02-28 1983-02-15 Union Carbide Corporation Hydroformylation catalyst reactivation
US4710587A (en) * 1980-04-16 1987-12-01 Union Carbide Corp. Process for removing triorganophosphine from an organic liquid
US4605780A (en) * 1980-09-24 1986-08-12 Union Carbide Corporation Reactivation of rhodium complex hydroformylation catalysts
GB2097795B (en) * 1981-05-01 1984-08-01 Johnson Matthey Plc Recovering triaryl phosphine from poisoned thodium catalyst systems
US4390473A (en) * 1981-06-22 1983-06-28 Eastman Kodak Company Recovery of rhodium and cobalt low pressure oxo catalyst
DE3235029A1 (de) * 1982-09-22 1984-03-22 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von wasserloeslichen, rhodium enthaltenden hydroformylierungskatalysatoren
US4599456A (en) * 1984-12-20 1986-07-08 Phillips Petroleum Company Novel aldehyde-phosphine compositions and uses therefor
DE3715344A1 (de) * 1987-05-08 1988-11-24 Basf Ag Alkoxysubstituierte maleinsaeureimide und maleinsaeureanhydride, verfahren zu ihrer herstellung und ihre verwendung
US4861918A (en) * 1988-08-12 1989-08-29 Union Carbide Corporation Reactivation of hydroformylation catalysts
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
US4929767A (en) * 1988-08-12 1990-05-29 Union Carbide Chemicals And Plastics Company Inc. Treatment of rhodium catalysts
US4975180A (en) * 1989-06-05 1990-12-04 Exxon Research And Engineering Company Cracking process
US5114970A (en) * 1991-07-25 1992-05-19 The Dow Chemical Company Use of 3-iodo-2-chloro-2-propenenitrile as an antimicrobial
DE4135050A1 (de) * 1991-10-24 1993-04-29 Hoechst Ag Verfahren zur reaktivierung wasserloeslicher hydroformylierungskatalysatoren
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5520722A (en) * 1995-01-18 1996-05-28 Exxon Research And Engineering Company Multiunsaturates removal process
US5516965A (en) * 1995-01-18 1996-05-14 Exxon Research And Engineering Company Unsaturates recovery and recycle process
EP2231682B1 (en) * 2008-01-15 2016-01-06 Dow Global Technologies LLC Sulfonated organophosphine compounds and use thereof in hydroformylation processes
WO2009091670A1 (en) * 2008-01-15 2009-07-23 Dow Global Technologies Inc. Sulfonated organophosphine compounds and use thereof in hydroformylation processes
WO2009091669A1 (en) * 2008-01-15 2009-07-23 Dow Global Technologies Inc. Sulfonated organophosphine compounds and use in hydroformylation processes
WO2013184350A1 (en) 2012-06-04 2013-12-12 Dow Technology Investments Llc Hydroformylation process
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
DE102014002103B4 (de) * 2014-02-15 2020-10-22 Oxea Gmbh Verfahren zur Regenerierung gebrauchter Hydroformylierungskatalysatoren

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2822376A (en) * 1957-02-27 1958-02-04 American Cyanamid Co Reaction of phosphine with alpha, beta-unsatu-rated compounds
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US3555098A (en) * 1967-12-13 1971-01-12 Union Oil Co Hydroformylation
IT1007026B (it) * 1974-01-23 1976-10-30 Montedison Spa Procedimento per il ricupero di sistemi catalitici da grezzi di idroformilazione
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4009003A (en) * 1976-02-09 1977-02-22 Celanese Corporation Method for determining suitability of triorganophosphorus ligands for use in hydroformylation processes
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium

Also Published As

Publication number Publication date
ES491648A0 (es) 1981-04-16
PL128785B1 (en) 1984-02-29
PL224367A1 (es) 1981-06-05
KR830002795A (ko) 1983-05-30
EP0019296A1 (en) 1980-11-26
US4283304A (en) 1981-08-11
BR8003134A (pt) 1980-12-23
DE3062948D1 (en) 1983-06-09
ZA802603B (en) 1981-04-29
KR840001926B1 (ko) 1984-10-25
EP0019296B1 (en) 1983-05-04
ATE3210T1 (de) 1983-05-15
CA1139312A (en) 1983-01-11
AU5851780A (en) 1980-11-27
ES8104313A1 (es) 1981-04-16
JPS55154985A (en) 1980-12-02
JPS6026397B2 (ja) 1985-06-24

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