MD222C2 - Способ получения изомерных замещенных циклопропанкарбоновых кислот или их функциональных производных - Google Patents
Способ получения изомерных замещенных циклопропанкарбоновых кислот или их функциональных производныхInfo
- Publication number
- MD222C2 MD222C2 MD94-0276A MD940276A MD222C2 MD 222 C2 MD222 C2 MD 222C2 MD 940276 A MD940276 A MD 940276A MD 222 C2 MD222 C2 MD 222C2
- Authority
- MD
- Moldova
- Prior art keywords
- group
- atom
- chlorine
- formula
- hydrogen
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- General Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Public Health (AREA)
- Tropical Medicine & Parasitology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
- Indole Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Fodder In General (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Изобретение относится к способу получения новых замещенных изомерных циклопропанкарбоновых кислот или их функциональных производных, которые могут быть использованы в качестве средства, воздейсмтвующих на сорные растения, вредных насекомых и паразитов в сельском хозяйстве.Задача изобретения - расширение круга подобных соединений.Способ предусматривает получение новых замещенных изомерных циклопропанкарбоновых кислот или их функциональных производных общей формулы:где Х1 - атом водорода, фтора, хлора или брома, Х2 - совпадающее с Х1 или отличное от него и преставляет собой атом фтора, хлора или брома; Х3 - атом хлора, брома или иода; Z - гидроксил, галоген или сложноэфирная группа OR, где R - либо радикал бензил, который может быть замещен одним или несколькими радикалами, выбранными из группы: алкил - C1-C4, алкенил C2-C6, оксиалкенил C2-C6, алкидиенил C4-C8, диоксиметилен, бензил или галоген, либо группа формулы IIгде R1 - атом водорода или метил; R2 - фенил или группа - CH2-C=CH, преимущественно метилфурил, либо группа формулы IIIгде R3 - винил, пропан-1-ил, бута-1,3-циенил или бутен-1-ил либо группа формулы IVгде R4 - атом водорода, нитрильная или этинильная группа; R5 - атом хлора или метил; n число, равное 0,1 или 2, преимущественно 3-феноксибензиловая, α - циано-3-феноксибензиловая или α -этинил-3-феноксибензиловая группа, либо группа формулы Vгде R6, R7, R8, R9, - водород, атом хлора или метил; S/I - фенил или цихидро- или тетрахидрофенил, путем взаимодействия соединения общей формулы IV,в которой Х1, Х2 и Z имеют указанные значения, с хлорирующим, бромирующим или иодирующим реагентом на двойную связь, в качестве которого может использоваться хлор, бром или иод.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7628279A FR2364884A1 (fr) | 1976-09-21 | 1976-09-21 | Nouveaux esters d'acides cyclopropane, carboxyliques comportant un substituant polyhalogene, procedes de preparation et compositions insecticides les renfermant |
SU772522552A SU858559A3 (ru) | 1976-09-21 | 1977-09-15 | Способ получени изомерных замещенных циклопропанкарбоновых кислот или их функциональных производных |
Publications (2)
Publication Number | Publication Date |
---|---|
MD222B1 MD222B1 (ro) | 1995-06-30 |
MD222C2 true MD222C2 (ru) | 1995-12-31 |
Family
ID=9177883
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MD94-0276A MD222C2 (ru) | 1976-09-21 | 1994-09-08 | Способ получения изомерных замещенных циклопропанкарбоновых кислот или их функциональных производных |
Country Status (9)
Country | Link |
---|---|
JP (2) | JPS59152349A (ru) |
AT (2) | AT353248B (ru) |
BE (2) | BE858895A (ru) |
FR (1) | FR2364884A1 (ru) |
MD (1) | MD222C2 (ru) |
PL (1) | PL129488B1 (ru) |
SU (1) | SU858559A3 (ru) |
TR (1) | TR20005A (ru) |
ZA (2) | ZA775668B (ru) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2380244A1 (fr) * | 1977-02-11 | 1978-09-08 | Ciba Geigy Ag | Composes cyclopropane-carbonyliques utiles a la preparation de composes appropries a la lutte contre les parasites |
TR20011A (tr) * | 1977-02-11 | 1980-06-16 | Ciba Geigy Ag | Yeni esterler |
EG13121A (en) * | 1977-02-11 | 1981-03-31 | Ciba Geigy Ag | Process for preparing of cyclopanecarboxylic acid esters and their use in pest control |
US4277617A (en) * | 1977-10-27 | 1981-07-07 | Roussel Uclaf | Process for the preparation of esters |
FR2432016A2 (fr) * | 1978-07-24 | 1980-02-22 | Roussel Uclaf | Procede de preparation d'esters d'alcools a-cyanes |
EP0015239A3 (de) * | 1979-02-15 | 1980-09-17 | Ciba-Geigy Ag | Cyclopropankarbonsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung in der Schädlingsbekämpfung |
FR2484256B1 (fr) * | 1979-06-29 | 1986-10-24 | Roussel Uclaf | Procede de lutte contre les parasites des animaux a sang chaud |
OA06730A (fr) * | 1980-01-25 | 1982-06-30 | Roussel Uclaf | Dérivés 3-(buta-1',3'-diényl) substitué de l'acide cyclopropane-1-carboxylique, leur application contre les parasites des végétaux et des animaux à sang chaud, les compositions correspondantes ainsi que les compositions parfumantes les renfermant, leur pré |
DE3004092A1 (de) * | 1980-02-05 | 1981-08-13 | Bayer Ag, 5090 Leverkusen | Substituierte 3-(1,2-dibrom-alkyl)- 2,2-dimethyl-cyclopropan-1-carbonsaeureester, verfahren sowie zwischenprodukte zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmitteln |
DE3270859D1 (en) * | 1981-08-31 | 1986-06-05 | Shell Int Research | Protection of crops against soil pests employing an alkylbenzyl cyclopropane carboxylate, novel cyclopropane carboxylates, and compositions containing them |
JPH0340181U (ru) * | 1989-08-11 | 1991-04-17 | ||
DE102014107739B4 (de) | 2014-06-02 | 2023-12-07 | Jacques Tchouangueu | Moskitonetz mit Insektenfalle |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1503260A (fr) * | 1965-12-09 | 1967-11-24 | Nat Res Dev | Nouvelles compositions insecticides |
-
1976
- 1976-09-21 FR FR7628279A patent/FR2364884A1/fr active Granted
-
1977
- 1977-09-15 SU SU772522552A patent/SU858559A3/ru active
- 1977-09-20 BE BE181072A patent/BE858895A/xx not_active IP Right Cessation
- 1977-09-20 PL PL1977214250A patent/PL129488B1/pl unknown
- 1977-09-20 BE BE181071A patent/BE858894A/xx not_active IP Right Cessation
- 1977-09-21 ZA ZA00775668A patent/ZA775668B/xx unknown
- 1977-09-21 AT AT677277A patent/AT353248B/de not_active IP Right Cessation
- 1977-09-21 AT AT677377A patent/AT350043B/de not_active IP Right Cessation
- 1977-09-21 ZA ZA00775669A patent/ZA775669B/xx unknown
-
1980
- 1980-05-16 TR TR20005A patent/TR20005A/xx unknown
-
1983
- 1983-03-02 JP JP58033025A patent/JPS59152349A/ja active Granted
-
1984
- 1984-05-07 JP JP59089573A patent/JPS6011404A/ja active Granted
-
1994
- 1994-09-08 MD MD94-0276A patent/MD222C2/ru not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1503260A (fr) * | 1965-12-09 | 1967-11-24 | Nat Res Dev | Nouvelles compositions insecticides |
Also Published As
Publication number | Publication date |
---|---|
BE858895A (fr) | 1978-03-20 |
ZA775669B (en) | 1978-10-25 |
AT350043B (de) | 1979-05-10 |
FR2364884A1 (fr) | 1978-04-14 |
JPS64363B2 (ru) | 1989-01-06 |
PL129488B1 (en) | 1984-05-31 |
AT353248B (de) | 1979-11-12 |
ZA775668B (en) | 1978-10-25 |
MD222B1 (ro) | 1995-06-30 |
JPS6011404A (ja) | 1985-01-21 |
ATA677377A (de) | 1978-10-15 |
SU858559A3 (ru) | 1981-08-23 |
ATA677277A (de) | 1979-04-15 |
PL214250A1 (ru) | 1980-02-25 |
FR2364884B1 (ru) | 1979-01-12 |
BE858894A (fr) | 1978-03-20 |
JPS59152349A (ja) | 1984-08-31 |
JPS6243985B2 (ru) | 1987-09-17 |
TR20005A (tr) | 1980-06-11 |
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Legal Events
Date | Code | Title | Description |
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1M4A | Expiration of terms |