MD222C2 - Procedeu de obţinere a acizilor ciclopropancarbonici izomerici substituiţi sau a derivaţilor lor funcţionali - Google Patents

Procedeu de obţinere a acizilor ciclopropancarbonici izomerici substituiţi sau a derivaţilor lor funcţionali

Info

Publication number
MD222C2
MD222C2 MD94-0276A MD940276A MD222C2 MD 222 C2 MD222 C2 MD 222C2 MD 940276 A MD940276 A MD 940276A MD 222 C2 MD222 C2 MD 222C2
Authority
MD
Moldova
Prior art keywords
group
atom
chlorine
formula
hydrogen
Prior art date
Application number
MD94-0276A
Other languages
English (en)
Russian (ru)
Other versions
MD222B1 (ro
Inventor
Jacques Martel
Jean Tessier
Jean Pierre Demoute
Original Assignee
Roussel Uclaf, Societe Anonyme
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf, Societe Anonyme filed Critical Roussel Uclaf, Societe Anonyme
Publication of MD222B1 publication Critical patent/MD222B1/ro
Publication of MD222C2 publication Critical patent/MD222C2/ro

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Public Health (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Fodder In General (AREA)
  • Furan Compounds (AREA)
  • Indole Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

Invenţia se referă la procedeul de obţinere a unor noi acizi ciclopropanici izomerici substituiţi sau a derivaţilor lor funcţionali, care pot fi utilizaţi în calitate de remediu ce acţionează asupra buruienilor, insectelor dăunătoare şi paraziţilor în agricultură.Sarcina invenţiei constă în extinderea şirului acestor compuşi.Procedeul prevede obţinerea noilor acizi ciclopropancarbonici izomerici substituiţi sau a derivaţilor lor funcţionali cu formula generală I:în care X1 reprezintă atom de4 H, F, Cl sau Br, X2 reprezintă atom de F, Cl sau Br identic sau diferit de X1; X3 reprezintă atom de Cl, Br sau I, Z reprezintă hidroxil, halogen sau grupa esterică OR, în care R reprezintă sau radical benzilic, care poate fi substituit cu unul sau câţiva radicali, selectaţi din grupa: C1-C4-alchil, C2-C6-alchenil, C2-C6-oxialchenil, C4-C8-alchidienil, dioximetilenă, benzil, halogen, sau grupa cu formula II:în care R1 reprezintă atom de H sau metil, R2 reprezintă fenil sau grupa -CH2-C≡CH, opţional 5-benzil-3-metilfuril, sau grupa cu formula III:în care R3 reprezintă vinil, propen-1-il, buta-1,3-dienil sau buten-1-il, sau grupa cu formula IV:în care R4 reprezintă atom de H, grupa nitrilică sau etinilică (-C≡CH); R5 reprezintă atom de Cl sau metil; n este număr egal cu 0, 1 sau 2, opţional grupa: 3-fenoxibenzilică, α-cian-3-fenoxibenzilică sau α-etinil-3-fenoxibenzilică, sau grupa cu formula V:în care R6, R7, R8, R9 reprezintă H, atom de clor sau metil; S/l reprezintă fenil sau tetra- sau dihidrofenil, şi este caracterizat prin aceea că compusul cu formula generală VI:în care X1, X2 şi Z au valorile menţionate, cu un agent clorurant, bromurant sau iodurant în poziţia legăturii duble. Astfel de agenţi pot fi clorul, bromul sau iodul.
MD94-0276A 1976-09-21 1994-09-08 Procedeu de obţinere a acizilor ciclopropancarbonici izomerici substituiţi sau a derivaţilor lor funcţionali MD222C2 (ro)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7628279A FR2364884A1 (fr) 1976-09-21 1976-09-21 Nouveaux esters d'acides cyclopropane, carboxyliques comportant un substituant polyhalogene, procedes de preparation et compositions insecticides les renfermant
SU772522552A SU858559A3 (ru) 1976-09-21 1977-09-15 Способ получени изомерных замещенных циклопропанкарбоновых кислот или их функциональных производных

Publications (2)

Publication Number Publication Date
MD222B1 MD222B1 (ro) 1995-06-30
MD222C2 true MD222C2 (ro) 1995-12-31

Family

ID=9177883

Family Applications (1)

Application Number Title Priority Date Filing Date
MD94-0276A MD222C2 (ro) 1976-09-21 1994-09-08 Procedeu de obţinere a acizilor ciclopropancarbonici izomerici substituiţi sau a derivaţilor lor funcţionali

Country Status (9)

Country Link
JP (2) JPS59152349A (ro)
AT (2) AT353248B (ro)
BE (2) BE858894A (ro)
FR (1) FR2364884A1 (ro)
MD (1) MD222C2 (ro)
PL (1) PL129488B1 (ro)
SU (1) SU858559A3 (ro)
TR (1) TR20005A (ro)
ZA (2) ZA775669B (ro)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2805193A1 (de) * 1977-02-11 1978-08-17 Ciba Geigy Ag Cyclopropankarbonsaeureester, verfahren zu ihrer herstellung und ihre verwendung in der schaedlingsbekaempfung
FR2380244A1 (fr) * 1977-02-11 1978-09-08 Ciba Geigy Ag Composes cyclopropane-carbonyliques utiles a la preparation de composes appropries a la lutte contre les parasites
TR20113A (tr) * 1977-02-11 1980-08-07 Ciba Geigy Ag Yeni esterler
US4277617A (en) * 1977-10-27 1981-07-07 Roussel Uclaf Process for the preparation of esters
FR2432016A2 (fr) * 1978-07-24 1980-02-22 Roussel Uclaf Procede de preparation d'esters d'alcools a-cyanes
EP0015239A3 (de) * 1979-02-15 1980-09-17 Ciba-Geigy Ag Cyclopropankarbonsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung in der Schädlingsbekämpfung
FR2484256B1 (fr) * 1979-06-29 1986-10-24 Roussel Uclaf Procede de lutte contre les parasites des animaux a sang chaud
OA06730A (fr) * 1980-01-25 1982-06-30 Roussel Uclaf Dérivés 3-(buta-1',3'-diényl) substitué de l'acide cyclopropane-1-carboxylique, leur application contre les parasites des végétaux et des animaux à sang chaud, les compositions correspondantes ainsi que les compositions parfumantes les renfermant, leur pré
DE3004092A1 (de) * 1980-02-05 1981-08-13 Bayer Ag, 5090 Leverkusen Substituierte 3-(1,2-dibrom-alkyl)- 2,2-dimethyl-cyclopropan-1-carbonsaeureester, verfahren sowie zwischenprodukte zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmitteln
EP0074132B1 (en) * 1981-08-31 1986-04-30 Shell Internationale Researchmaatschappij B.V. Protection of crops against soil pests employing an alkylbenzyl cyclopropane carboxylate, novel cyclopropane carboxylates, and compositions containing them
JPH0340181U (ro) * 1989-08-11 1991-04-17
DE102014107739B4 (de) 2014-06-02 2023-12-07 Jacques Tchouangueu Moskitonetz mit Insektenfalle

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1503260A (fr) * 1965-12-09 1967-11-24 Nat Res Dev Nouvelles compositions insecticides

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1503260A (fr) * 1965-12-09 1967-11-24 Nat Res Dev Nouvelles compositions insecticides

Also Published As

Publication number Publication date
TR20005A (tr) 1980-06-11
ZA775669B (en) 1978-10-25
BE858895A (fr) 1978-03-20
ZA775668B (en) 1978-10-25
BE858894A (fr) 1978-03-20
AT350043B (de) 1979-05-10
PL214250A1 (ro) 1980-02-25
JPS6243985B2 (ro) 1987-09-17
SU858559A3 (ru) 1981-08-23
PL129488B1 (en) 1984-05-31
ATA677377A (de) 1978-10-15
MD222B1 (ro) 1995-06-30
ATA677277A (de) 1979-04-15
JPS6011404A (ja) 1985-01-21
AT353248B (de) 1979-11-12
JPS59152349A (ja) 1984-08-31
JPS64363B2 (ro) 1989-01-06
FR2364884A1 (fr) 1978-04-14
FR2364884B1 (ro) 1979-01-12

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