MD222C2 - Method of preparation of the isomeric substituted cyclopropancarbonic acids or their functional derivatives - Google Patents
Method of preparation of the isomeric substituted cyclopropancarbonic acids or their functional derivativesInfo
- Publication number
- MD222C2 MD222C2 MD94-0276A MD940276A MD222C2 MD 222 C2 MD222 C2 MD 222C2 MD 940276 A MD940276 A MD 940276A MD 222 C2 MD222 C2 MD 222C2
- Authority
- MD
- Moldova
- Prior art keywords
- group
- atom
- chlorine
- formula
- hydrogen
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- General Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Public Health (AREA)
- Tropical Medicine & Parasitology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fodder In General (AREA)
- Furan Compounds (AREA)
- Indole Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
The invention relates to the method of preparation of the isomeric substituted cyclopropancarbonic acids or their functional derivatives that can be used as the remedies actioned on the weeds, detriments on insects and parasites in agriculture.The purpose of the invention is widening the class of such compounds.The method forsees the preparation of new substituted isomeric cyclopropancarbonic acids of general formulawherein X1 - atom hydrogen, fluorine, chlorine or bromide, X2 - coincided with X1 or unlike and present itself atom of fluorine, chlorine or bromine, X3 - atom of chlorine. bromine or iodine; Z - hydroxyl, halogen or esteric group IR, wherein R either benzylic radical that can be substituted by one or some radicals selected from group: alcyl C1-C4 alkenyl C2-C6, oxyalkenyl C2-C6, alkidienil C4-C8, dioxymethylen, benzyl, or halogen or group of formula IIwherein R1 - atom hydrogen or methyl; R2 - phenyl or group -C2-CşCH, mainly methylfuryl, or group of formula IIIwherein R3 - vinyl, propen-1-il, buta-1,3-dienil, or buten-1-il or group of formula IVwherein R4 - atom of hydrogen, nitrilic or ethinilic group; R5 - atom of chlorine or methyl; n-number egual 0,1 or 2 mainly 3-phenoxybenzilic, X - ciano-3-phenoxybenzilic or L-ethynil-3-phenoxybenzilic group or group of formula Vwherein R6, R7, R8, R9 - hydrogen, atom of chlorine or methyl; S/1-phenyl or dihydro or tetrahydrophenyl by interaction of compound of general formula VIwherein X1, X2 and X have mentioned values with chlorining, bromining, iodining reagent on the double bond as which can be used chlorine, bromine or iodine.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7628279A FR2364884A1 (en) | 1976-09-21 | 1976-09-21 | Fungicidal bactericidal cyclopropane carboxylic acid derivs. - are intermediates in prepn. of insecticidal, acaricidal, nematocidal and antifungal ester(s) |
| SU772522552A SU858559A3 (en) | 1976-09-21 | 1977-09-15 | Method of producing isomeric sustituted cyclopropanecarboxalic acids or their functional derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD222B1 MD222B1 (en) | 1995-06-30 |
| MD222C2 true MD222C2 (en) | 1995-12-31 |
Family
ID=9177883
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MD94-0276A MD222C2 (en) | 1976-09-21 | 1994-09-08 | Method of preparation of the isomeric substituted cyclopropancarbonic acids or their functional derivatives |
Country Status (9)
| Country | Link |
|---|---|
| JP (2) | JPS59152349A (en) |
| AT (2) | AT353248B (en) |
| BE (2) | BE858894A (en) |
| FR (1) | FR2364884A1 (en) |
| MD (1) | MD222C2 (en) |
| PL (1) | PL129488B1 (en) |
| SU (1) | SU858559A3 (en) |
| TR (1) | TR20005A (en) |
| ZA (2) | ZA775669B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2805193A1 (en) * | 1977-02-11 | 1978-08-17 | Ciba Geigy Ag | CYCLOPROPANIC CARBON ACID ESTERS, THE PROCESS FOR THEIR MANUFACTURING AND THEIR USE IN PEST CONTROL |
| FR2380244A1 (en) * | 1977-02-11 | 1978-09-08 | Ciba Geigy Ag | 3-Ethyl-2-methyl-cyclopropane carboxylic acid derivs. - are intermediates for pesticides, prepd. by halogenation of corresp. 3-vinyl cpd. (BE 16.8.78) |
| TR20113A (en) * | 1977-02-11 | 1980-08-07 | Ciba Geigy Ag | NEW ESTERS |
| US4277617A (en) * | 1977-10-27 | 1981-07-07 | Roussel Uclaf | Process for the preparation of esters |
| FR2432016A2 (en) * | 1978-07-24 | 1980-02-22 | Roussel Uclaf | Insecticidal ester(s) of alpha-halogenated alcohol(s) - useful in prepn. of insecticidal corresp. cyano-ester(s) |
| EP0015239A3 (en) * | 1979-02-15 | 1980-09-17 | Ciba-Geigy Ag | Esters of cyclopropanecarboxylic acid, process for their preparation and their use as pesticides |
| FR2484256B1 (en) * | 1979-06-29 | 1986-10-24 | Roussel Uclaf | METHOD FOR CONTROLLING PEST OF HOT BLOOD ANIMALS |
| OA06730A (en) * | 1980-01-25 | 1982-06-30 | Roussel Uclaf | 3- (buta-1 ', 3'-dienyl) substituted derivatives of cyclopropane-1-carboxylic acid, their application against parasites of plants and warm-blooded animals, the corresponding compositions as well as the perfume compositions containing them, their meadow |
| DE3004092A1 (en) * | 1980-02-05 | 1981-08-13 | Bayer Ag, 5090 Leverkusen | SUBSTITUTED 3- (1,2-DIBROM-ALKYL) - 2,2-DIMETHYL-CYCLOPROPAN-1-CARBONIC ACID ESTERS, METHODS AND INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION AND THEIR USE IN PEST CONTROL |
| EP0074132B1 (en) * | 1981-08-31 | 1986-04-30 | Shell Internationale Researchmaatschappij B.V. | Protection of crops against soil pests employing an alkylbenzyl cyclopropane carboxylate, novel cyclopropane carboxylates, and compositions containing them |
| JPH0340181U (en) * | 1989-08-11 | 1991-04-17 | ||
| DE102014107739B4 (en) | 2014-06-02 | 2023-12-07 | Jacques Tchouangueu | Mosquito net with insect trap |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1503260A (en) * | 1965-12-09 | 1967-11-24 | Nat Res Dev | New insecticidal compositions |
-
1976
- 1976-09-21 FR FR7628279A patent/FR2364884A1/en active Granted
-
1977
- 1977-09-15 SU SU772522552A patent/SU858559A3/en active
- 1977-09-20 PL PL1977214250A patent/PL129488B1/en unknown
- 1977-09-20 BE BE181071A patent/BE858894A/en not_active IP Right Cessation
- 1977-09-20 BE BE181072A patent/BE858895A/en not_active IP Right Cessation
- 1977-09-21 ZA ZA00775669A patent/ZA775669B/en unknown
- 1977-09-21 AT AT677277A patent/AT353248B/en not_active IP Right Cessation
- 1977-09-21 AT AT677377A patent/AT350043B/en not_active IP Right Cessation
- 1977-09-21 ZA ZA00775668A patent/ZA775668B/en unknown
-
1980
- 1980-05-16 TR TR20005A patent/TR20005A/en unknown
-
1983
- 1983-03-02 JP JP58033025A patent/JPS59152349A/en active Granted
-
1984
- 1984-05-07 JP JP59089573A patent/JPS6011404A/en active Granted
-
1994
- 1994-09-08 MD MD94-0276A patent/MD222C2/en not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1503260A (en) * | 1965-12-09 | 1967-11-24 | Nat Res Dev | New insecticidal compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| TR20005A (en) | 1980-06-11 |
| ZA775669B (en) | 1978-10-25 |
| BE858895A (en) | 1978-03-20 |
| ZA775668B (en) | 1978-10-25 |
| BE858894A (en) | 1978-03-20 |
| AT350043B (en) | 1979-05-10 |
| PL214250A1 (en) | 1980-02-25 |
| JPS6243985B2 (en) | 1987-09-17 |
| SU858559A3 (en) | 1981-08-23 |
| PL129488B1 (en) | 1984-05-31 |
| ATA677377A (en) | 1978-10-15 |
| MD222B1 (en) | 1995-06-30 |
| ATA677277A (en) | 1979-04-15 |
| JPS6011404A (en) | 1985-01-21 |
| AT353248B (en) | 1979-11-12 |
| JPS59152349A (en) | 1984-08-31 |
| JPS64363B2 (en) | 1989-01-06 |
| FR2364884A1 (en) | 1978-04-14 |
| FR2364884B1 (en) | 1979-01-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 1M4A | Expiration of terms |