LU81055A1 - Compositions fongicides a base de phosphites d'isothiouronium - Google Patents
Compositions fongicides a base de phosphites d'isothiouronium Download PDFInfo
- Publication number
- LU81055A1 LU81055A1 LU81055A LU81055A LU81055A1 LU 81055 A1 LU81055 A1 LU 81055A1 LU 81055 A LU81055 A LU 81055A LU 81055 A LU81055 A LU 81055A LU 81055 A1 LU81055 A1 LU 81055A1
- Authority
- LU
- Luxembourg
- Prior art keywords
- carbon atoms
- radical containing
- alkyl radical
- isothiouronium
- fungicidal compositions
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 24
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 title claims description 16
- 230000000855 fungicidal effect Effects 0.000 title claims description 15
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical compound [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 title description 4
- 150000001875 compounds Chemical class 0.000 claims description 40
- 125000004432 carbon atom Chemical group C* 0.000 claims description 27
- -1 alkyl radical Chemical class 0.000 claims description 23
- 239000011149 active material Substances 0.000 claims description 21
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 208000031888 Mycoses Diseases 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 208000035143 Bacterial infection Diseases 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 230000002538 fungal effect Effects 0.000 claims description 2
- PSYDSRLQABJJAD-UHFFFAOYSA-N dodecylthiourea Chemical compound CCCCCCCCCCCCNC(N)=S PSYDSRLQABJJAD-UHFFFAOYSA-N 0.000 claims 4
- SLRMQYXOBQWXCR-UHFFFAOYSA-N 2154-56-5 Chemical compound [CH2]C1=CC=CC=C1 SLRMQYXOBQWXCR-UHFFFAOYSA-N 0.000 claims 2
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
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- 150000003254 radicals Chemical class 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- LMYQWQCDUHNQLF-UHFFFAOYSA-N hexylthiourea Chemical compound CCCCCCNC(N)=S LMYQWQCDUHNQLF-UHFFFAOYSA-N 0.000 claims 1
- 239000000047 product Substances 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
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- 241000196324 Embryophyta Species 0.000 description 10
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- 239000002244 precipitate Substances 0.000 description 6
- 241000233866 Fungi Species 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- SDDKIZNHOCEXTF-UHFFFAOYSA-N methyl carbamimidothioate Chemical compound CSC(N)=N SDDKIZNHOCEXTF-UHFFFAOYSA-N 0.000 description 5
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- 150000003839 salts Chemical class 0.000 description 4
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- 229920001817 Agar Polymers 0.000 description 3
- 241000589613 Pseudomonas savastanoi pv. phaseolicola Species 0.000 description 3
- 240000003768 Solanum lycopersicum Species 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
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- 150000004694 iodide salts Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 230000009885 systemic effect Effects 0.000 description 3
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical class C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 206010061217 Infestation Diseases 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 241000233679 Peronosporaceae Species 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 241000233622 Phytophthora infestans Species 0.000 description 2
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- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
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- CZHYKKAKFWLGJO-UHFFFAOYSA-N dimethyl phosphite Chemical group COP([O-])OC CZHYKKAKFWLGJO-UHFFFAOYSA-N 0.000 description 2
- HWSUUGHIDOOOOJ-UHFFFAOYSA-N dioxaphosphinane Chemical compound C1COOPC1 HWSUUGHIDOOOOJ-UHFFFAOYSA-N 0.000 description 2
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- 230000001681 protective effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000013008 thixotropic agent Substances 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- SZUVGFMDDVSKSI-WIFOCOSTSA-N (1s,2s,3s,5r)-1-(carboxymethyl)-3,5-bis[(4-phenoxyphenyl)methyl-propylcarbamoyl]cyclopentane-1,2-dicarboxylic acid Chemical compound O=C([C@@H]1[C@@H]([C@](CC(O)=O)([C@H](C(=O)N(CCC)CC=2C=CC(OC=3C=CC=CC=3)=CC=2)C1)C(O)=O)C(O)=O)N(CCC)CC(C=C1)=CC=C1OC1=CC=CC=C1 SZUVGFMDDVSKSI-WIFOCOSTSA-N 0.000 description 1
- GHYOCDFICYLMRF-UTIIJYGPSA-N (2S,3R)-N-[(2S)-3-(cyclopenten-1-yl)-1-[(2R)-2-methyloxiran-2-yl]-1-oxopropan-2-yl]-3-hydroxy-3-(4-methoxyphenyl)-2-[[(2S)-2-[(2-morpholin-4-ylacetyl)amino]propanoyl]amino]propanamide Chemical compound C1(=CCCC1)C[C@@H](C(=O)[C@@]1(OC1)C)NC([C@H]([C@@H](C1=CC=C(C=C1)OC)O)NC([C@H](C)NC(CN1CCOCC1)=O)=O)=O GHYOCDFICYLMRF-UTIIJYGPSA-N 0.000 description 1
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
- BZZXQZOBAUXLHZ-UHFFFAOYSA-N (c-methylsulfanylcarbonimidoyl)azanium;sulfate Chemical compound CSC(N)=N.CSC(N)=N.OS(O)(=O)=O BZZXQZOBAUXLHZ-UHFFFAOYSA-N 0.000 description 1
- FZRJLBJACDITKM-UHFFFAOYSA-N 1,3,2-dioxaphospholane Chemical compound C1COPO1 FZRJLBJACDITKM-UHFFFAOYSA-N 0.000 description 1
- UNILWMWFPHPYOR-KXEYIPSPSA-M 1-[6-[2-[3-[3-[3-[2-[2-[3-[[2-[2-[[(2r)-1-[[2-[[(2r)-1-[3-[2-[2-[3-[[2-(2-amino-2-oxoethoxy)acetyl]amino]propoxy]ethoxy]ethoxy]propylamino]-3-hydroxy-1-oxopropan-2-yl]amino]-2-oxoethyl]amino]-3-[(2r)-2,3-di(hexadecanoyloxy)propyl]sulfanyl-1-oxopropan-2-yl Chemical compound O=C1C(SCCC(=O)NCCCOCCOCCOCCCNC(=O)COCC(=O)N[C@@H](CSC[C@@H](COC(=O)CCCCCCCCCCCCCCC)OC(=O)CCCCCCCCCCCCCCC)C(=O)NCC(=O)N[C@H](CO)C(=O)NCCCOCCOCCOCCCNC(=O)COCC(N)=O)CC(=O)N1CCNC(=O)CCCCCN\1C2=CC=C(S([O-])(=O)=O)C=C2CC/1=C/C=C/C=C/C1=[N+](CC)C2=CC=C(S([O-])(=O)=O)C=C2C1 UNILWMWFPHPYOR-KXEYIPSPSA-M 0.000 description 1
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 101100294115 Caenorhabditis elegans nhr-4 gene Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000010523 Cicer arietinum Nutrition 0.000 description 1
- 244000045195 Cicer arietinum Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000001692 EU approved anti-caking agent Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 101000713585 Homo sapiens Tubulin beta-4A chain Proteins 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- YTAUXQXYUZTHAT-UHFFFAOYSA-N NC(S)=N.NC(S)=N.NC(S)=N.OP(O)O Chemical class NC(S)=N.NC(S)=N.NC(S)=N.OP(O)O YTAUXQXYUZTHAT-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
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- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 102100036788 Tubulin beta-4A chain Human genes 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
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- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- GDOIQLNSIAMNMA-UHFFFAOYSA-N [I-].C(C)SC(NCCCCCCCCCCCC)=[NH2+] Chemical compound [I-].C(C)SC(NCCCCCCCCCCCC)=[NH2+] GDOIQLNSIAMNMA-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000001351 alkyl iodides Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
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- 229910052799 carbon Inorganic materials 0.000 description 1
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- 238000000151 deposition Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- DLQDGVZAEYZNTG-UHFFFAOYSA-N dimethyl hydrogen phosphite Chemical compound COP(O)OC DLQDGVZAEYZNTG-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
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- 230000001804 emulsifying effect Effects 0.000 description 1
- QDHCHVWSKUMZDZ-UHFFFAOYSA-N ethyl dihydrogen phosphite Chemical class CCOP(O)O QDHCHVWSKUMZDZ-UHFFFAOYSA-N 0.000 description 1
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- 150000004820 halides Chemical class 0.000 description 1
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- KRZGKJJPEOUIBI-UHFFFAOYSA-N hydron;thiourea;iodide Chemical class I.NC(S)=N KRZGKJJPEOUIBI-UHFFFAOYSA-N 0.000 description 1
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- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
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- 239000008268 mayonnaise Substances 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- VXTFGYMINLXJPW-UHFFFAOYSA-N phosphinane Chemical compound C1CCPCC1 VXTFGYMINLXJPW-UHFFFAOYSA-N 0.000 description 1
- 231100000208 phytotoxic Toxicity 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7808237 | 1978-03-16 | ||
| FR7808237A FR2419675A1 (fr) | 1978-03-16 | 1978-03-16 | Compositions fongicides a base de phosphites d'isothiouronium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU81055A1 true LU81055A1 (fr) | 1980-09-24 |
Family
ID=9206121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU81055A LU81055A1 (fr) | 1978-03-16 | 1979-03-16 | Compositions fongicides a base de phosphites d'isothiouronium |
Country Status (36)
| Country | Link |
|---|---|
| US (1) | US4382928A (de) |
| JP (2) | JPS54130521A (de) |
| AR (1) | AR220747A1 (de) |
| AT (1) | AT374483B (de) |
| AU (1) | AU530215B2 (de) |
| BE (1) | BE874907A (de) |
| BG (1) | BG32264A3 (de) |
| BR (1) | BR7901620A (de) |
| CA (1) | CA1118785A (de) |
| CH (1) | CH640700A5 (de) |
| CS (1) | CS208492B2 (de) |
| CU (1) | CU35057A (de) |
| DD (1) | DD142282A5 (de) |
| DE (1) | DE2910237C2 (de) |
| DK (1) | DK106679A (de) |
| EG (1) | EG14428A (de) |
| ES (2) | ES478641A1 (de) |
| FR (1) | FR2419675A1 (de) |
| GB (1) | GB2016926B (de) |
| GR (1) | GR68033B (de) |
| HU (1) | HU182985B (de) |
| IE (1) | IE48734B1 (de) |
| IL (1) | IL56884A (de) |
| IT (1) | IT1162483B (de) |
| LU (1) | LU81055A1 (de) |
| NL (1) | NL188831C (de) |
| NZ (1) | NZ189907A (de) |
| OA (1) | OA06216A (de) |
| PH (1) | PH16323A (de) |
| PL (1) | PL214137A1 (de) |
| PT (1) | PT69356A (de) |
| RO (1) | RO79037A (de) |
| SE (1) | SE446929B (de) |
| SU (1) | SU952107A3 (de) |
| TR (1) | TR19935A (de) |
| ZA (1) | ZA791224B (de) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2457873A1 (fr) * | 1978-03-16 | 1980-12-26 | Rhone Poulenc Agrochimie | Compositions fongicides a base de phosphites d'isothiouronium |
| FR2451164A2 (fr) * | 1978-03-16 | 1980-10-10 | Rhone Poulenc Agrochimie | Compositions fongicides a base de phosphites d'isothiouronium |
| FR2655816B1 (fr) * | 1989-12-14 | 1994-04-29 | Rhone Poulenc Agrochimie | Granules dispersables de produits fongicides. |
| US5133891A (en) * | 1990-04-27 | 1992-07-28 | Rhone Poulenc Ag Co. | Treatment of plants for frost protection |
| JPH0478737U (de) * | 1990-11-19 | 1992-07-09 | ||
| PT928191E (pt) * | 1996-09-26 | 2003-01-31 | Meditor Pharmaceuticals Ltd | Formulacoes farmaceuticas compreendendo derivados de s-alquilisotiouronio |
| IL144632A0 (en) * | 2001-07-30 | 2002-05-23 | Meditor Pharmaceuticals Ltd | Method and pharmaceutical compositions for treating headache, nausea and migraine |
| EP1315505B1 (de) * | 2000-09-05 | 2007-10-17 | Meditor Pharmaceuticals Ltd. | Pharmazeutische zubereitungen gegen kopfschmerz, migräne, nausea und erbrechen |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4119724A (en) * | 1973-11-26 | 1978-10-10 | Pepro | Fungicidal compositions containing phosphorous acid and derivatives thereof |
| FR2254276B1 (de) * | 1973-12-14 | 1977-03-04 | Philagro Sa | |
| DE2463046C2 (de) | 1973-12-14 | 1984-05-03 | PEPRO - Société pour le Développement et la Vente de Spécialités Chimiques, Lyon | Fungizide Mittel auf Ammoniumphosphonatbasis |
| FR2380286A1 (fr) * | 1977-02-14 | 1978-09-08 | Philagro Sa | Nouveaux derives de phosphites d'hydrazinium |
-
1978
- 1978-03-16 FR FR7808237A patent/FR2419675A1/fr active Granted
-
1979
- 1979-03-07 GR GR58536A patent/GR68033B/el unknown
- 1979-03-13 PH PH22281A patent/PH16323A/en unknown
- 1979-03-14 NZ NZ189907A patent/NZ189907A/xx unknown
- 1979-03-15 ES ES478641A patent/ES478641A1/es not_active Expired
- 1979-03-15 NL NLAANVRAGE7902056,A patent/NL188831C/xx not_active IP Right Cessation
- 1979-03-15 IT IT48373/79A patent/IT1162483B/it active
- 1979-03-15 ZA ZA791224A patent/ZA791224B/xx unknown
- 1979-03-15 JP JP3052079A patent/JPS54130521A/ja active Granted
- 1979-03-15 PL PL21413779A patent/PL214137A1/xx unknown
- 1979-03-15 DE DE2910237A patent/DE2910237C2/de not_active Expired
- 1979-03-15 BR BR7901620A patent/BR7901620A/pt unknown
- 1979-03-15 CH CH245679A patent/CH640700A5/fr not_active IP Right Cessation
- 1979-03-15 GB GB7909200A patent/GB2016926B/en not_active Expired
- 1979-03-15 SE SE7902354A patent/SE446929B/sv not_active IP Right Cessation
- 1979-03-15 DK DK106679A patent/DK106679A/da unknown
- 1979-03-15 CA CA000323456A patent/CA1118785A/en not_active Expired
- 1979-03-15 AU AU45162/79A patent/AU530215B2/en not_active Ceased
- 1979-03-15 TR TR19935A patent/TR19935A/xx unknown
- 1979-03-15 IL IL56884A patent/IL56884A/xx unknown
- 1979-03-15 PT PT69356A patent/PT69356A/pt unknown
- 1979-03-15 RO RO7996910A patent/RO79037A/ro unknown
- 1979-03-15 OA OA56767A patent/OA06216A/xx unknown
- 1979-03-15 AT AT0197179A patent/AT374483B/de not_active IP Right Cessation
- 1979-03-15 AR AR275811A patent/AR220747A1/es active
- 1979-03-16 CS CS791772A patent/CS208492B2/cs unknown
- 1979-03-16 DD DD79211633A patent/DD142282A5/de unknown
- 1979-03-16 LU LU81055A patent/LU81055A1/fr unknown
- 1979-03-16 CU CU7935057A patent/CU35057A/es unknown
- 1979-03-16 BE BE0/194072A patent/BE874907A/xx not_active IP Right Cessation
- 1979-03-16 HU HU79PI669A patent/HU182985B/hu unknown
- 1979-03-16 BG BG042905A patent/BG32264A3/xx unknown
- 1979-03-17 EG EG178/79A patent/EG14428A/xx active
- 1979-05-04 ES ES480224A patent/ES480224A1/es not_active Expired
- 1979-08-08 IE IE614/79A patent/IE48734B1/en not_active IP Right Cessation
-
1980
- 1980-03-11 SU SU802891756A patent/SU952107A3/ru active
- 1980-03-18 US US06/131,400 patent/US4382928A/en not_active Expired - Lifetime
-
1987
- 1987-05-12 JP JP62115686A patent/JPS62281886A/ja active Pending
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