KR970701217A - 메소제닉 잔기를 함유하는 에폭시 수지와 경화제와의 경화 조절성 촉매화 혼합물 및 이로부터 B-상태 경화 제품(Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties, B-staged and cured products therefrom) - Google Patents

메소제닉 잔기를 함유하는 에폭시 수지와 경화제와의 경화 조절성 촉매화 혼합물 및 이로부터 B-상태 경화 제품(Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties, B-staged and cured products therefrom)

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Publication number
KR970701217A
KR970701217A KR1019960704422A KR19960704422A KR970701217A KR 970701217 A KR970701217 A KR 970701217A KR 1019960704422 A KR1019960704422 A KR 1019960704422A KR 19960704422 A KR19960704422 A KR 19960704422A KR 970701217 A KR970701217 A KR 970701217A
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curing
curable composition
state
optionally
component
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KR1019960704422A
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English (en)
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지미 디. 얼즈
로버트 이. 2세 헤프너
제임스 엘. 버트람
루이스 엘. 워커
윌리엄 에이. 클레이
Original Assignee
그레이스 스티븐 에스.
더 다우 케미칼 캄파니
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Publication of KR970701217A publication Critical patent/KR970701217A/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C09K19/3804—Polymers with mesogenic groups in the main chain
    • C09K19/3814—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/35—Non-linear optics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
    • C09K2323/055—Epoxy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3472—Woven fabric including an additional woven fabric layer
    • Y10T442/3528—Three or more fabric layers
    • Y10T442/3569—Woven fabric layers impregnated with a thermosetting resin
    • Y10T442/3585—Epoxy resin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/659—Including an additional nonwoven fabric
    • Y10T442/67—Multiple nonwoven fabric layers composed of the same inorganic strand or fiber material

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)

Abstract

하나 이상의 에폭시 수지(A), 하나 이상의 경화제(B) 및 하나 이상의 경화 조절 촉매(C)(여기서, 성분(A) 또는 성분(B) 또는 성분(A)와 성분(B)의 혼합물 중의 하나 이상은 메소제닉 잔기를 함유한다)를 함유하는 경화성 조성물을 제조하였다. 이들 경화성 조성물은 고온에서 가공할 수 있으며, 향상된 특성을 지닌다. 이들은 피복물, 주조물, 전기재, 적충물, 복합재 등의 제조시 유용하다.

Description

메소제닉 잔기를 함유하는 에폭시 수지와 경화제와의 경화 조절성 촉매화 혼합물 및 이로부터의 B-상태 경화 제품 (Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties, B-staged and cured products therefrom)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 분자당 평균 하나 이상의 인접한 에폭사이드 그룹을 포함하는 하나 이상의 에폭시 수지(A), 에폭시 수지에 대한 하나 이상의 경화제(B) 및 하나 이상의 경화제 조절 촉매(C)를 포함하는 경화성 조성물로서, 하나 이상의 성분(A) 또는 (B)가 하나 이상의 메소제닉 잔기를 함유함을 특징으로 하는 경화성 조성물.
  2. 제1항에 있어서, 성분(C)가 오늄 또는 아민 화합물과 약한 친핵성 음이온을 지니는 산과의 혼합으로부터 제조되는 경화 조절 촉매인 경화성 조성물.
  3. 제2항에 있어서, 성분(C)가 에틸(트리톨릴)포스포늄 테트라할로보레이트, 에틸(트리톨릴)암모늄 테트라할로보레이트, 테트라부틸 포스포늄 테트라할로보레이트, 벤질트리메틸암모늄 테트라할로보레이트, 테트라부틸암모늄 테트라할로보레이트, 트리에틸아민 테트라할로보산 착체, 트리부틸아민 테트라할로보산 착체, N,N'-디메틸-1,2-디아미노에탄 테트라할로보산 착체 또는 이들의 임의의 혼합물인 경화성 조성물.
  4. 임의로, 전기장을 적용(a)하거나, 자기장을 적용(b)하거나, 인장력 또는 전단력을 부가(c)하거나, 이들을 임의로 혼합 적용(d)한 제1항 내지 제3항 중 어느 한 항에 따르는 경화성 조성물을 B-상태화(B-staging)하여 수득한 제품.
  5. 경화전 또는 경화 도중의 어느 한 경우 또는 경화전 및 경화 도중 두 경우 모두에 임의로, 전기장을 적용(a)하거나, 자기장을 적용(b)하거나, 인장력 또는 전단력을 부가(c)하거나, 이들을 임의로 혼합 적용(d)한 제1항 내지 제3항 중 어느 한 항에 따르는 경화성 조성물을 경화시켜 수득한 제품.
  6. B-상태 및/또는 경화전 또는 B-상태 및/또는 경화 도중 중의 어느 한 경우 또는 B-상태 및/또는 경화전 및 B-상태 및/또는 경화 도중 두 경우 모두에 임의로, 전기장을 적용(a)하거나, 자기장을 적용(b)하거나, 인장력 또는 전단력을 부가(c)하거나, 이들을 임의로 혼합 적용(d)한 제4항의 B-상태 생성물을 경화시켜 수득한 제품.
  7. 제1항 내지 제3항 중의 어느 한 항에 따르는 경화성 조성물을 함침시킨 기재의 하나 이상의 플라이를 포함하는 적충물.
  8. 제4항의 B-상태 생성물을 함침시킨 기재의 하나 이상의 플라이를 포함하는 적충물.
  9. 제7항 또는 제8항에 있어서, 기재가 유리 재료 또는 흑연 재료인 적충물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960704422A 1994-02-15 1995-02-08 메소제닉 잔기를 함유하는 에폭시 수지와 경화제와의 경화 조절성 촉매화 혼합물 및 이로부터 B-상태 경화 제품(Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties, B-staged and cured products therefrom) KR970701217A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/196,355 1994-02-15
US08/196,355 US5458929A (en) 1994-02-15 1994-02-15 Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties, B-staged and cured products therefrom
PCT/US1995/001791 WO1995022079A1 (en) 1994-02-15 1995-02-08 Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties, b-staged and cured products therefrom

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KR970701217A true KR970701217A (ko) 1997-03-17

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KR1019960704422A KR970701217A (ko) 1994-02-15 1995-02-08 메소제닉 잔기를 함유하는 에폭시 수지와 경화제와의 경화 조절성 촉매화 혼합물 및 이로부터 B-상태 경화 제품(Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties, B-staged and cured products therefrom)

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US (2) US5458929A (ko)
EP (1) EP0745233A1 (ko)
JP (1) JPH09508936A (ko)
KR (1) KR970701217A (ko)
AU (1) AU1842795A (ko)
SG (1) SG47885A1 (ko)
WO (1) WO1995022079A1 (ko)

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EP0473935A3 (en) * 1990-08-03 1992-09-09 The Dow Chemical Company Curable mixture of mesogenic epoxy resins and mesogenic polyamines and cured compositions
US5281675A (en) * 1992-02-06 1994-01-25 The Dow Chemical Company Mesogenic cyclic imino ether-containing compositions and polymerization products thereof

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JPH09508936A (ja) 1997-09-09
SG47885A1 (en) 1998-04-17
AU1842795A (en) 1995-08-29
EP0745233A1 (en) 1996-12-04
US5510431A (en) 1996-04-23
US5458929A (en) 1995-10-17
WO1995022079A1 (en) 1995-08-17

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