KR970065547A - 1-하이드록시디하이드로포스폴 옥사이드의 염과 1-하이드록시포스폴란 옥사이드의 염, 이의 제조방법 및 난연제로서의 이의 용도 - Google Patents
1-하이드록시디하이드로포스폴 옥사이드의 염과 1-하이드록시포스폴란 옥사이드의 염, 이의 제조방법 및 난연제로서의 이의 용도 Download PDFInfo
- Publication number
- KR970065547A KR970065547A KR1019970006966A KR19970006966A KR970065547A KR 970065547 A KR970065547 A KR 970065547A KR 1019970006966 A KR1019970006966 A KR 1019970006966A KR 19970006966 A KR19970006966 A KR 19970006966A KR 970065547 A KR970065547 A KR 970065547A
- Authority
- KR
- South Korea
- Prior art keywords
- oxide
- salt
- salts
- metal
- hydroxydihydrophosphol
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title claims abstract 12
- 239000003063 flame retardant Substances 0.000 title claims abstract 3
- CDDGCGLADRPTQZ-UHFFFAOYSA-N 1-hydroxy-2,3-dihydro-1$l^{5}-phosphole 1-oxide Chemical class OP1(=O)CCC=C1 CDDGCGLADRPTQZ-UHFFFAOYSA-N 0.000 title claims 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title 1
- 239000004952 Polyamide Substances 0.000 claims abstract 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000004033 plastic Substances 0.000 claims abstract 2
- 229920003023 plastic Polymers 0.000 claims abstract 2
- 229920002647 polyamide Polymers 0.000 claims abstract 2
- 229920000728 polyester Polymers 0.000 claims abstract 2
- 229910052751 metal Inorganic materials 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- 239000012778 molding material Substances 0.000 claims 3
- CSSLZLQDGHKFLE-UHFFFAOYSA-N 1-hydroxy-1$l^{5}-phospholane 1-oxide Chemical class OP1(=O)CCCC1 CSSLZLQDGHKFLE-UHFFFAOYSA-N 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 159000000007 calcium salts Chemical group 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910000000 metal hydroxide Inorganic materials 0.000 claims 1
- 150000004692 metal hydroxides Chemical class 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000011253 protective coating Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 claims 1
- 239000004416 thermosoftening plastic Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65681—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a (thio)phosphinic acid or ester thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/66—Substances characterised by their function in the composition
- C08L2666/84—Flame-proofing or flame-retarding additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
1-하이드록시디하이드로포드폴 옥사이드의 염과 1-하이그록시포스롤란 옥사이드의 염은 특히 포리에스테르나 폴리아미드와 같은 플라스틱용 난연제로서 유용하다. 알루미늄염이 바람직하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 화학식 (Ia) 또는 화학식 (Ib)의 1-하이드록시디하이드로포스폴 옥사이드의 염 및 화학식(2)의 1-하이드록시포스폴란 옥사이드의 염.상기 화학식 (Ia), (Ib), (2)에서, R1,R2,R3및 R4는 각각 수소 또는 직쇄 또는 측쇄 알킬 라디칼, 바람직하게는 직쇄 또는 측쇄 C1-C12-알킬 라디칼, 특히 바람직하게는 C1-C4-알킬 라디칼, 특히 메틸 또는 에틸이고, M은 주기율표의 제Ⅱ족 또는 제Ⅲa족 또는 제Ⅲb족의 금속, 특히 마그네슘, 칼슘, 아연 또는 알류미늄이며, n은 1,2 또는 3이다.
- 1-하이드록시디하이드로포스폴 옥사이드 및/또는 1-하이드록시포스폴란 옥사이드를 수용액 속에서 금속 탄산염, 금속 수산화물 또는 금속 산화물(여기서, 금속은 주기율표의 제Ⅱ족 또는 제Ⅲa족 또는 제Ⅲb족 금속이다)과 반응시킴을 포함하여, 제1항의 염을 제조하는 방법.
- 제2항에 있어서, 반응을 교반하면서 30 내지 150℃에서 수행하는 방법.
- 역사소성 플라스틱과 제1항의 염 하나 이상을 포함하는 성형 재료.
- 제4항에 있어서, 염을, 중합체의 중량을 기준으로 하여, 5 내지 30중량%의 양으로 포함하는 성형 재료.
- 열가소성 플라스틱, 특히 폴리에스테르 또는 폴리아미드용 난연제로서의 제1항에서 청구한 염의 용도.
- 제6항에 있어서, 염이 칼슘 염 또는 알루미늄 염인 용도.
- 성형품, 특히 전기 제품, 기게부품, 플러그, 마운트, 케이싱, 커버, 외장 또는 오버코트를 제조하기 위한, 제4항에서 청구한 성형 재료의 용도.
- 피막, 특히 화염 보호 피막에 있어서의 제1항에서 청구한 염의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19608011A DE19608011A1 (de) | 1996-03-04 | 1996-03-04 | Salze von 1-Hydroxy-dihydrophospholoxiden und 1-Hydroxy-phospholanoxiden und ihre Verwendung als Flammschutzmittel |
| DE19608011,8 | 1996-03-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR970065547A true KR970065547A (ko) | 1997-10-13 |
Family
ID=7786994
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019970006966A KR970065547A (ko) | 1996-03-04 | 1997-03-04 | 1-하이드록시디하이드로포스폴 옥사이드의 염과 1-하이드록시포스폴란 옥사이드의 염, 이의 제조방법 및 난연제로서의 이의 용도 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6087423A (ko) |
| EP (1) | EP0794191B1 (ko) |
| JP (1) | JPH09278784A (ko) |
| KR (1) | KR970065547A (ko) |
| CN (1) | CN1168381A (ko) |
| BR (1) | BR9701157A (ko) |
| DE (2) | DE19608011A1 (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9276290B2 (en) | 2011-03-24 | 2016-03-01 | Samsung Sdi Co., Ltd. | Electrolyte for rechargeable lithium battery and rechargeable lithium battery comprising same |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19708726A1 (de) | 1997-03-04 | 1998-09-10 | Hoechst Ag | Flammgeschützte Polymerformmassen |
| DE19708725A1 (de) | 1997-03-04 | 1998-09-10 | Hoechst Ag | Aluminiumsalze von Alkyl-hydroxymethylphosphinsäuren |
| DE19708724A1 (de) | 1997-03-04 | 1998-09-10 | Hoechst Ag | Aluminiumsalze von Alkyl-1-alkoxyethylphosphinsäuren |
| DE19720977A1 (de) | 1997-05-20 | 1998-11-26 | Hoechst Ag | Verfahren zur Herstellung von Aluminiumsalzen cyclischer Phosphinsäuren |
| MY117653A (en) | 1997-06-13 | 2004-07-31 | Polyplastics Co | Flame-retardant thermoplastic polyester resin composition |
| DE19734246A1 (de) * | 1997-08-07 | 1999-02-11 | Hoechst Ag | Verfahren zur Herstellung von Aluminiumsalzen cyclischer Phosphinsäuren |
| DE19737727A1 (de) * | 1997-08-29 | 1999-07-08 | Clariant Gmbh | Synergistische Flammschutzmittel-Kombination für Kunststoffe |
| DE19903709A1 (de) * | 1999-01-30 | 2000-08-10 | Clariant Gmbh | Flammschutzmittel-Kombination für thermoplastische Polymere II |
| TR200201863T2 (tr) * | 2000-01-21 | 2002-11-21 | Ticona Gmbh | Motorlu araçların motor bölmesinde termoplastik malzemeleri yapı elemanlarının üretimi. |
| DE10305548A1 (de) * | 2003-02-10 | 2004-08-26 | Basf Ag | Flammgeschützte Kunststoffformteile |
| KR100803193B1 (ko) * | 2005-08-24 | 2008-02-14 | 삼성에스디아이 주식회사 | 유기전해액 및 이를 채용한 리튬 전지 |
| JP5243006B2 (ja) * | 2006-12-04 | 2013-07-24 | 三菱エンジニアリングプラスチックス株式会社 | 難燃性ポリアミド樹脂組成物および成形品 |
| JP5468944B2 (ja) | 2010-03-12 | 2014-04-09 | 矢崎総業株式会社 | 押出しフレキシブルフラットケーブル |
| US10093801B2 (en) | 2013-12-12 | 2018-10-09 | Italmatch Chemicals S.P.A. | Halogen-free flame retardant polyamide moulding compositions with increased glow wire and fire resistance |
| KR20180081736A (ko) | 2015-11-13 | 2018-07-17 | 아이씨엘-아이피 아메리카 아이엔씨. | 폴리우레탄 및 폴리이소시아누레이트 포움용 반응성 난연제 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE700042A (ko) * | 1966-06-18 | 1967-12-01 | ||
| DE2252258A1 (de) * | 1972-10-25 | 1974-05-09 | Hoechst Ag | Schwerentflammbare thermoplastische polyester |
| DE2447727A1 (de) * | 1974-10-07 | 1976-04-08 | Hoechst Ag | Schwerentflammbare polyamidformmassen |
| GB1585085A (en) * | 1976-06-21 | 1981-02-25 | Ici Ltd | Polyamide compositions |
| US4208322A (en) * | 1978-04-13 | 1980-06-17 | Pennwalt Corporation | Polyester-polyamide resins flame retarded by poly(metal phosphinate)s |
| US4180495A (en) * | 1978-04-13 | 1979-12-25 | Pennwalt Corporation | Polyester resins flame retarded by poly(metal phosphinate)s |
| US4221874A (en) * | 1978-06-07 | 1980-09-09 | Monsanto Company | Phospholane oxide containing polymers |
| IT1157253B (it) * | 1982-02-09 | 1987-02-11 | Saffa Spa | Procedimento per rendere autoestinguenti, mediante fosforo rosso, materiali termoplastici sintetici e prodotti cosi' ottenuti |
| DE4012489A1 (de) | 1990-04-19 | 1991-10-24 | Bayer Ag | Verfahren zur herstellung von 1-halogen-1-oxophospholenen |
| DE4430932A1 (de) * | 1994-08-31 | 1996-03-07 | Hoechst Ag | Flammgeschützte Polyesterformmasse |
| DE19608006A1 (de) * | 1996-03-04 | 1997-09-11 | Hoechst Ag | Salze von phosphonigen Säuren und deren Verwendung als Flammschutzmittel in Kunststoffen |
| DE19645125A1 (de) * | 1996-11-04 | 1998-05-14 | Hoechst Ag | Verfahren zur Herstellung von Aluminiumsalzen organischer Phosphorsäuren |
-
1996
- 1996-03-04 DE DE19608011A patent/DE19608011A1/de not_active Withdrawn
-
1997
- 1997-02-20 DE DE59710003T patent/DE59710003D1/de not_active Expired - Fee Related
- 1997-02-20 EP EP97102722A patent/EP0794191B1/de not_active Expired - Lifetime
- 1997-02-28 CN CN97110012A patent/CN1168381A/zh active Pending
- 1997-03-03 BR BR9701157A patent/BR9701157A/pt not_active Application Discontinuation
- 1997-03-03 US US08/810,656 patent/US6087423A/en not_active Expired - Fee Related
- 1997-03-04 JP JP9048865A patent/JPH09278784A/ja active Pending
- 1997-03-04 KR KR1019970006966A patent/KR970065547A/ko not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9276290B2 (en) | 2011-03-24 | 2016-03-01 | Samsung Sdi Co., Ltd. | Electrolyte for rechargeable lithium battery and rechargeable lithium battery comprising same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1168381A (zh) | 1997-12-24 |
| JPH09278784A (ja) | 1997-10-28 |
| DE59710003D1 (de) | 2003-06-12 |
| US6087423A (en) | 2000-07-11 |
| DE19608011A1 (de) | 1997-09-11 |
| EP0794191A1 (de) | 1997-09-10 |
| EP0794191B1 (de) | 2003-05-07 |
| BR9701157A (pt) | 1998-12-15 |
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| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |