KR970061779A - 일산화탄소를 제조하는 방법 및 장치 - Google Patents

일산화탄소를 제조하는 방법 및 장치 Download PDF

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KR970061779A
KR970061779A KR1019970004205A KR19970004205A KR970061779A KR 970061779 A KR970061779 A KR 970061779A KR 1019970004205 A KR1019970004205 A KR 1019970004205A KR 19970004205 A KR19970004205 A KR 19970004205A KR 970061779 A KR970061779 A KR 970061779A
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permeate
methane
producing
carbon monoxide
producing carbon
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KR1019970004205A
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빌리 쟝
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띠에리 쉬에르
레르 리뀌드, 소시에떼 아노님 뿌르 레뛰드 에 렉스쁠로와따시옹 데 프로세데 죠르쥬 끌로드
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Publication of KR970061779A publication Critical patent/KR970061779A/ko

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/40—Carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/506—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification at low temperatures
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0223—H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0261—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/046—Purification by cryogenic separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/30—Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/40—Processes or apparatus using other separation and/or other processing means using hybrid system, i.e. combining cryogenic and non-cryogenic separation techniques
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/80—Processes or apparatus using other separation and/or other processing means using membrane, i.e. including a permeation step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/82—Processes or apparatus using other separation and/or other processing means using a reactor with combustion or catalytic reaction
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/04—Mixing or blending of fluids with the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2245/00—Processes or apparatus involving steps for recycling of process streams
    • F25J2245/02—Recycle of a stream in general, e.g. a by-pass stream

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)

Abstract

본 발명은 일산화탄소를 제조하는 방법에 관한 것으로서, 본 발명의 방법에 있어서는 공급 유체로부터 생성된 합성 가스를 저온학적 증류 단계에 의해서 분리시킨다. 잔류하는 메탄이 농후한 분류물은 공급 유체로 재순환시킨다. 또한 본 발명은 일산화탄소를 제조하기 위한 장치에 관한 것이다.

Description

일산화탄소를 제조하는 방법 및 장치
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 의한 장치의 개요도이다.

Claims (11)

  1. 공급 유체로부터 합성 가스를 생성한 후에 그 가스를 분리시키므로써 일산화탄소(CO)를 제조하는 방법에 있어서, 잔류하는 메탄이 농후한 분류물의 적어도 일부분을 공급 유체로 재순환시키는 것을 특징으로 하는 방법.
  2. 제1항에 있어서, 상기 메탄이 농후한 잔류물이 투과 단계에 의해 생성되는 방법.
  3. 제1항에 있어서, 상기 투과 단계는 수소와 메탄을 포함하는 가스 혼합물을 분리시키는 방법.
  4. 제3항에 있어서, 상기 투과 단계의 불투과생성물로 이루어진 분류물의 대부분 또는 전부를 재순환시키는 방법.
  5. 제3항에 있어서, 상기 투과 단계의 투과생성물의 압력을 조정하여 상기 투과생성물의 조성을 조절하는 방법.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 합성 가스를 저온학적 중류에 의해 분리시키는 방법.
  7. CO를 함유하는 합성 가스를 생성하기 위한 수단(1), 상기 가스를 분리시키기 위한 수단(3), 및 상기 분리 수단에 의해 배출된 잔류하는 메탄이 농후한 분류물의 일부분을 상기 합성 가스를 생성하기 위한 수단의 주입구로 복귀시키기 위한 수단을 포함하여, 일산화탄소(CO)를 제조하기 위한 장치.
  8. 제7항에 있어서, 투과 수단이 정제 수단에 의해 배출된 흐름으로부터 잔류 메탄이 농후한 분류물을 생성하는 장치.
  9. 제8항에 있어서, 정제 수단에 의해 배출된 흐름이 수소와 메탄을 함유하는 장치.
  10. 제9항에 있어서, 투과 단계의 투과생성물의 압력을 조정하기 위한 수단(19)를 포함하는 장치.
  11. 제7항 내지 제10항 중 어느 한 항에 있어서, 상기 합성 가스를 분리시키기 위한 수단이 저온학적 분리 수단인 장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970004205A 1996-02-16 1997-02-13 일산화탄소를 제조하는 방법 및 장치 KR970061779A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9601962 1996-02-16
FR9601962A FR2745000A1 (fr) 1996-02-16 1996-02-16 Procede et installation de production de monoxyde de carbone

Publications (1)

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KR970061779A true KR970061779A (ko) 1997-09-12

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EP (1) EP0790212A1 (ko)
KR (1) KR970061779A (ko)
CN (1) CN1172069A (ko)
CA (1) CA2197529A1 (ko)
FR (1) FR2745000A1 (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2838424B1 (fr) * 2002-04-15 2004-05-28 Air Liquide Procede et installation de separation d'un melange d'hydrogene et de monoxyde de carbone
US7066984B2 (en) * 2003-09-25 2006-06-27 The Boc Group, Inc. High recovery carbon monoxide production process
FR2861165B1 (fr) * 2003-10-20 2005-12-16 Air Liquide Procede et appareil pour la production de monoxyde de carbone et/ou d'hydrogene et/ou d'un melange d'hydrogene et de monoxyde de carbone par distillation cryogenique
KR101304652B1 (ko) * 2005-06-06 2013-09-05 레르 리키드 쏘시에떼 아노님 뿌르 레？드 에렉스뿔라따시옹 데 프로세데 조르즈 클로드 수소 및 일산화탄소의 동시적 제조 방법
DE102006006281A1 (de) * 2006-02-10 2007-08-16 Linde Ag Verfahren zur Erzeugung von Kohlenmonoxid aus Synthesegas
WO2014082702A1 (de) 2012-11-29 2014-06-05 Linde Aktiengesellschaft Verfahren zum betrieb einer dampfreformierungsanlage
DE102014003392A1 (de) 2014-03-06 2015-09-10 Linde Aktiengesellschaft Verfahren zum Betrieb einer Dampfreformierungsanlage
EP3599218A1 (de) * 2015-10-01 2020-01-29 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Verfahren und anlage zur erzeugung von synthesegas mit variabler zusammensetzung
FR3052159B1 (fr) 2016-06-06 2018-05-18 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede et installation pour la production combinee d'un melange d'hydrogene et d'azote ainsi que de monoxyde de carbone par distillation et lavage cryogeniques

Family Cites Families (7)

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Publication number Priority date Publication date Assignee Title
US3943236A (en) * 1971-04-02 1976-03-09 E. I. Du Pont De Nemours And Company Reforming process for carbon monoxide
US4836833A (en) * 1988-02-17 1989-06-06 Air Products And Chemicals, Inc. Production and recovery of hydrogen and carbon monoxide
FR2636250B1 (fr) * 1988-09-12 1992-01-17 Air Liquide Procede et installation de recuperation d'hydrogene et de monoxyde de carbone
US5073356A (en) * 1990-09-20 1991-12-17 Air Products And Chemicals, Inc. Integrated processes for the production of carbon monoxide
DE4236263A1 (de) * 1992-10-27 1994-04-28 Linde Ag Verfahren zum Gewinnen eines hochreinen Wasserstoff- und eines hochreinen Kohlenmonoxidstromes
US5435836A (en) * 1993-12-23 1995-07-25 Air Products And Chemicals, Inc. Hydrogen recovery by adsorbent membranes
FR2718428B1 (fr) * 1994-04-11 1997-10-10 Air Liquide Procédé et installation de production de monoxyde de carbone.

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FR2745000A1 (fr) 1997-08-22
CN1172069A (zh) 1998-02-04
CA2197529A1 (en) 1997-08-17
EP0790212A1 (fr) 1997-08-20

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