MY125560A - Method for the preparation of methanol from natural gas - Google Patents

Method for the preparation of methanol from natural gas

Info

Publication number
MY125560A
MY125560A MYPI97001311A MYPI9701311A MY125560A MY 125560 A MY125560 A MY 125560A MY PI97001311 A MYPI97001311 A MY PI97001311A MY PI9701311 A MYPI9701311 A MY PI9701311A MY 125560 A MY125560 A MY 125560A
Authority
MY
Malaysia
Prior art keywords
gas
synthesis
methanol
reactor
purge
Prior art date
Application number
MYPI97001311A
Inventor
Walter Dr Boll
Hermann Gohna
Original Assignee
Metallgesellschaft Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft Ag filed Critical Metallgesellschaft Ag
Publication of MY125560A publication Critical patent/MY125560A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516Multisteps
    • C07C29/1518Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

NATURAL GAS IS CONVERTED WITH STEAM AND OXYGEN IN AN AUTOTHERMALLY OPERATED REACTOR, AND FROM THE REACTOR A RAW SYNTHESIS GAS WITH A TEMPERATURE IN THE RANGE FROM 800 TO 1200°C IS WITHDRAWN. TO THE COOLED, RAW SYNTHESIS GAS A GAS RICH IN H₂ IS ADMIXED. THE SYNTHESIS GAS WITH AN INCREASED H2 CONTENT IS CONVERTED IN A METHANOL SYNTHESIS REACTOR ON A COPPER CATALYST AT A PRESSURE IN THE RANGE FROM 10 TO 150 BAR AND TEMPERATURE FROM 180 TO 350°C. FROM THE SYNTHESIS REACTOR A GAS MIXTURE CONTAINING METHANOL VAPOR IS WITHDRAWN, METHANOL IS CONDENSED OUT, AND A COOLED RESIDUAL GAS IS SEPARATED. THE RESIDUAL GAS IS DIVIDED INTO A FIRST PARTIAL STREAM (RECYCLE GAS) AND A SECOND PARTIAL STREAM (PURGE GAS). THE RECYCLE GAS IS ADMIXED TO THE SYNTHESIS GAS BEFORE THE METHANOL SYNTHESIS REACTOR. THE PURGE GAS CONSISTS OF 30 TO 80 VOL- % H₂, 7 TO 35 VOL -% O2 AND 3 TO 25 VOL -% O. THE HOURLY QUANTITY OF PURGE GAS IS 8 TO 25% (CALCULATED DRY) OF THE HOURLY QUANTITY OF RAW SYNTHESIS GAS. THE PURGE GAS IS CHARGED INTO A SEPARATING MEANS, WHERE THE GAS RICH IN H₂ IS RECOVERED, WHICH IS ADMIXED TO THE RAW SYNTHESIS GAS. THE HOURLY QUANTITY OF CARBON DIOXIDE SUPPLIED TO THE SEPARATING MEANS IN THE PURGE GAS IS 10 TO 50% OF THE HOURLY QUANTITY OF CO₂ IN THE RAW SYNTHESIS GAS.
MYPI97001311A 1996-10-24 1997-03-27 Method for the preparation of methanol from natural gas MY125560A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19644216A DE19644216A1 (en) 1996-10-24 1996-10-24 Process for producing methanol from natural gas

Publications (1)

Publication Number Publication Date
MY125560A true MY125560A (en) 2006-08-30

Family

ID=7809871

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI97001311A MY125560A (en) 1996-10-24 1997-03-27 Method for the preparation of methanol from natural gas

Country Status (7)

Country Link
EP (1) EP0839786B1 (en)
CA (1) CA2213025C (en)
DE (2) DE19644216A1 (en)
DK (1) DK0839786T3 (en)
MY (1) MY125560A (en)
NO (1) NO315938B1 (en)
SA (1) SA98180958B1 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO314989B1 (en) 1999-12-28 2003-06-23 Statoil Asa Process for increasing production in an existing processing plant for conversion of natural gas to a product, as well as processing plants
CA2357527C (en) 2001-10-01 2009-12-01 Technology Convergence Inc. Methanol recycle stream
US7205376B2 (en) 2004-05-04 2007-04-17 General Electric Company Processes for the production of cumene, polyetherimides, and polycarbonates
DE102004028200B3 (en) * 2004-05-28 2005-12-15 Hippweb E.K. Method for carrying out heterogeneous catalytic exothermic gas phase reactions for the synthesis of methanol
US7019039B1 (en) * 2005-07-14 2006-03-28 Starchem Technologies, Inc. High efficiency process for producing methanol from a synthesis gas
AU2007257434B2 (en) 2006-05-30 2010-08-26 Starchem Technologies, Inc. Methanol production process and system
EP3016924A1 (en) * 2013-04-26 2016-05-11 Silicon Fire AG Process and reactor system for synthesis of methanol with cycle gas and purge gas recycling
JP6663211B2 (en) * 2015-12-04 2020-03-11 三菱重工エンジニアリング株式会社 Methanol production system and production method
EP3181541B1 (en) * 2015-12-18 2018-08-29 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method and device for the recovery of methanol
EP3181540B1 (en) * 2015-12-18 2019-07-24 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process for the separation of methanol from gas mixtures
RU2616919C1 (en) * 2016-06-02 2017-04-18 Андрей Владиславович Курочкин Unit of complex non-waste gas treatment with methanol production
EP3366663A1 (en) * 2017-02-23 2018-08-29 Casale Sa Process for methanol production

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4546111A (en) * 1983-04-22 1985-10-08 Foster Wheeler Energy Corporation Process for the production of oxygenated organic compounds such as methanol
GB2142331A (en) * 1983-06-29 1985-01-16 Toyo Engineering Corp A process for producing methanol
CA1263671A (en) * 1986-02-10 1989-12-05 David Leon Banquy Process for the production of synthesis gas
DE4130718A1 (en) * 1991-09-14 1993-03-18 Metallgesellschaft Ag PROCESS FOR GENERATING A SYNTHESIS GAS FOR METHANOL SYNTHESIS

Also Published As

Publication number Publication date
CA2213025A1 (en) 1998-04-24
NO973970D0 (en) 1997-08-29
DE19644216A1 (en) 1998-04-30
NO973970L (en) 1998-04-27
NO315938B1 (en) 2003-11-17
EP0839786B1 (en) 2002-08-28
DK0839786T3 (en) 2002-12-30
EP0839786A3 (en) 1999-10-06
CA2213025C (en) 2006-06-13
DE59708052D1 (en) 2002-10-02
SA98180958B1 (en) 2006-05-20
EP0839786A2 (en) 1998-05-06

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