KR970021205A - 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물 - Google Patents

난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물 Download PDF

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KR970021205A
KR970021205A KR1019950035546A KR19950035546A KR970021205A KR 970021205 A KR970021205 A KR 970021205A KR 1019950035546 A KR1019950035546 A KR 1019950035546A KR 19950035546 A KR19950035546 A KR 19950035546A KR 970021205 A KR970021205 A KR 970021205A
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ether
poly
phenylene
resin composition
polyphenylene ether
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KR1019950035546A
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KR0165586B1 (ko
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임종철
장복남
이제흔
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유현식
제일모직 주식회사
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 열가소성 수지 조성물은 (A) 폴리페닐렌 에테르 수지 또는 폴리페닐렌 에테르계 수지와 비닐 방향족 중합체의 혼합물로 이루어진 폴리페닐렌에테르계 수지 100중량부에 대하여, (B) 인계 난연제로서 하기 일반식(Ⅰ)에서 n의 값이 0.3∼0.8범위인 합성된 아릴포스페이트 올리고머 5∼20중량부와 (C) 플루오로계 수지 0.01∼2.0중량부, 및 (D) 스티렌계 충격보강재 0∼40중량부를 혼합시킨 수지 조성물이다. 상기 수지 조성물은 쥬싱현상이 발생하지 않고 가공성과 내충격성이 우수한 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물이다.

Description

난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. (A) 100중량부의 폴리페닐렌 에테르 수지; (B) 인계 난연제로서 하기 일반식을 갖고 n의 평균값이 0.3 내지 0.8의 범위인 5∼20중량부의 합성된 아릴포스페이트 올리고머;
    상기 식에서, R1, R2, R4, 및 R5는 서로 독립적으로 할로겐을 함유하지 않은 C6-C20아릴기 또는 알킬치환된 아릴이고 R3는 히드로키놀 또는 레조시놀 형태임. (C) 0.01∼2.0중량부를 플루오로계 수지, 및 (D) 0∼40중량부의 스티렌계 충격보강재;로 이루어지는 것을 특징으로 하는 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물.
  2. 제1항에 있어서, 상기 폴리페닐렌 에테르 수지(A)가 비닐 방향족 중합체를 더 포함하는 것을 특징으로 하는 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물.
  3. 제1항에 있어서, 상기 폴리페닐렌 에테르 수지(A)가 폴리(2,6-디메틸-1,4-페닐렌)에테르, 폴리(2,6-디에틸-1,4-페닐렌)에테르, 폴리(2,6-디프로필-1,4-페닐렌)에테르, 폴리(2-메틸-6-에틸-1,4-페닐렌)에테르, 폴리(2-메틸-6-프로필-1,4-페닐렌)에테르, 폴리(2-에틸-6-프로필-1,4-페닐렌)에테르, 폴리(2,6-디페닐-1,4-페닐렌)에테르, 폴리(2,6-디메틸-1,4-페닐렌)에테르와 폴리(2,3,6-트리메틸-1,4-페닐렌)에테르의 공중합체, 및 폴리(2,6-디메틸-1,4-페닐렌)에테르와 폴리(2,3,6-트리메틸-1,4-페닐렌)에테르와 공중합체로 이루어지는 군으로부터 선택된 최소한 하나인 것을 특징으로 하는 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물.
  4. 제2항에 있어서, 상기 비닐 방향족 중합체가 폴리스티렌, 고충격 폴리스티렌, 폴리클로로스티렌, 폴리 알파-메틸스티렌, 및 폴리 t-부틸스티렌으로 이루어지는 군으로부터 선택된 최소한 하나인 것을 특징으로 하는 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물.
  5. 제1항에 있어서, 상기 플루오르계 수지(C)는 폴리테트라플루오로에틸렌, 폴리비닐리덴플루오라이드, 테트라플루오로에틸렌과 비닐리덴플루오라이드의 공중합체 , 테트라플루오로에틸렌과 플루오로알킬비닐에테르의 공중합체, 및 테트라플루오로에틸렌과 헥사플루오로프로필렌의 공중합체로 이루어지는 군으로부터 선택된 하나 이상인 것을 특징으로 하는 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물.
  6. 제1항에 있어서, 상기 수지 조성물이 무기물 첨가제, 열안정제, 산화방지제, 광안정제, 안료, 및/또는 염료를 더 포함하는 것을 특징으로 하는 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950035546A 1995-10-16 1995-10-16 난연성을 갖는 폴리페닐렌 에테르계 열가소성 수지 조성물 KR0165586B1 (ko)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100405198B1 (ko) * 2001-07-16 2003-11-12 제일모직주식회사 난연성 열가소성 수지 조성물
KR100437535B1 (ko) * 2001-09-28 2004-06-30 제일모직주식회사 열가소성 난연성 수지 조성물

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100405198B1 (ko) * 2001-07-16 2003-11-12 제일모직주식회사 난연성 열가소성 수지 조성물
KR100437535B1 (ko) * 2001-09-28 2004-06-30 제일모직주식회사 열가소성 난연성 수지 조성물

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