KR960706549A - 전동액용 유성성 마찰증가 첨가제(oil soluble friction increasing additives for power transmission fluids) - Google Patents

전동액용 유성성 마찰증가 첨가제(oil soluble friction increasing additives for power transmission fluids) Download PDF

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KR960706549A
KR960706549A KR1019960702878A KR19960702878A KR960706549A KR 960706549 A KR960706549 A KR 960706549A KR 1019960702878 A KR1019960702878 A KR 1019960702878A KR 19960702878 A KR19960702878 A KR 19960702878A KR 960706549 A KR960706549 A KR 960706549A
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substituted
hydrocarbyl
nitrogen
branched hydrocarbyl
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레이몬드 프레데릭 와츠
리카르도 알프레도 블로취
안토니오 구티에레즈
로저 키이쓰 니버트
잭 라이어
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존 제이. 마혼
엑손 케미칼 패턴츠 인코포레이티드
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Abstract

(a) 총 약 12개 내지 약 50개의 탄소원자를 함유하는 치환 또는 비치환되고, 포화 또는 불포화된, 분지된 유용성 하이드로카빌기, (b) 연결기, 및 (c) 질소-함유 극성 기(이 극성 기는 1개 이상의 질소원자 및 임의적으로는 붕소, 산소 및 황원자로 구성된 그룹에서 선택된 1개 이상의 원자를 함유하고, 상기 연결기에 의해 상기 분지된 하이드로카빌 기에 결합됨)를 포함하는 마찰 증가량의 유용성 마찰 증가 반응생성물을, 윤활점성을 갖는 다량의 오일에 첨가하는 것을 포함하는, 유성 조성물(예:ATF)의 정마찰 계수를 증가시키는 방법.

Description

전동액용 유성성 마찰증가 첨가제(OIL SOLUBLE FRICTION INCREASING ADDITIVES FOR POWER TRANSMISSION FLUIDS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (a) 총 약 12개 내지 약 50개의 탄소원자를 함유하는 치환 또는 비치환되고, 포화 또는 불포화된, 분지된 유용성 하이드로카빌기, (b) 연결기, 및 (c) 질소-함유 극성 기(이 극성 기는 1개 이상의 질소원자 및 임의적으로는 붕소, 산소 및 황원자로 구성된 그룹에서 선택된 1개 이상의 원자를 함유하고, 상기 연결기에 의해 상기 분지된 하이드로카빌 기에 결합됨)를 포함하는 마찰 증가량의 유용성 마찰 증가 반응생성물을, 윤활점성을 갖는 다량의 오일에 첨가하는 것을 포함하는, 유성 조성물의 정마찰 계수를 증가시키는 방법.
  2. 제1항에 있어서, 상기 마찰 증가 반응생성물이 일반식A-L-P로 나타내지고, 이 때 A가 상기 치환 또는 비치환되고, 포화 또는 불포화된 분지된 하이드로카빌기를 나타내고; L이 상기 연결기를 나타내고; P가 상기 질소 함유 극성 기를 나타내며; 상기 분지된 하이드로카빌기(A)가 일반식(여기에서, R은 간섭하지 않는 헤테로원자로 임의로 치환된 C1내지 C12하이드로카빌기이고; R1, R2및 R3은 독립적으로 H, 또는 간섭하지 않는 헤테로원자로 임의로 치환된 C1내지 C12하이드로카빌이고; x는 1 내지 17이며; y는 0 내지 10임)를 갖는 방법.
  3. 제2항에 있어서, 상기 연결기(L)가, (i) (a) 카복실기가 비시닐이고 (b) 상기 인접 탄소원자 하나 이상이 일불포화의 일부인 일불포화된 C4내지 C10의 이 카복실산; (ii) ⒤의 유도체; (ⅲ) 탄소-탄소 이중결합이 카복시기에 대해 알릴형인 일불포화된 C3내지 C10일카복실산; (ⅳ) (ⅲ)의 유도체: 및 (v)일반식(여기에서, X는 OH, Cl 및 SO3H로 구성된 그룹에서 선택된 작용기임)을 갖는 메틸렌 치환된 방향족 물질로 구성된 그룹에서 선택된 물질의 잔기를 포함하는 방법.
  4. 제3항에 있어서, 상기 극성 기(P)가 총2개 내지 약 60개의 탄소원자 및 2개 내지 약 15개의 질소원자를 함유하는 폴리아민 잔기를 포함하고, 상기 질소원자 1개 이상이 1급 또는 2급 아미노기에 존재하는 방법.
  5. (a) 질소원자 2개 내지 약 15개(이중 1개 이상은 1급 또는 2급 아미노 질소임) 및 탄소원자 약 2개 내지 약 60개를 갖는 폴리아민과, (b) (i) C12내지 C50의 분지쇄 하이드로카빌-치환된 C4내지 C10이카복실산, 무수물 또는 에스테르, (ii) C12내지 C50의 분지쇄 하이드로카빌-치환된 C3내지 C10의 일카복실산, 무수물 또는 에스테르, 및 (ⅲ) 일반식(여기에서 R6은 C12내지 C50의 분지된 하이드로카빌 치환기를 나타내고, X는 OH, CI 및 SO3H로 구성된 그룹에서 선택된 작용기를 나타냄)의 C12내지C50의 분지된 하이드로카빌 치환된 방향족 화합물로 구성된 그룹에서 선택된 물질의 반응생성물을 포함하는 마찰 증가 유효량의 마찰 증가제를, 윤활점성을 갖는 다량의 오일에 첨가하는 것을 포함하는 윤활유 조성물의 정마찰 계수를 증가시키는 방법.
  6. 제5항에 있어서, 상기 마찰 증가제가 분지된 하이드로카빌 치환된 숙신이미들를 포함하고, 상기 분지된 하이드로카빌 치환기가 약 150 내지 약 700의 수평균 분지량을 갖는 C2내지 C10의 올레핀 중합체를 포함하는 방법.
  7. 제6항에 있어서, 상기 마찰 증가제가 폴리이소부테닐 숙신이미드를 포함하는 방법.
  8. 제7항에 있어서, 상기 폴리이소부테닐 잔기가 약 350 내지 약 600의 수평균 분자량을 갖는 방법.
  9. 제7항에 있어서, 상기 폴리이소부테닐 잔기가 약 400 내지 약 500의 수평균 분자량을 갖는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019960702878A 1993-12-20 1994-12-06 유성 조성물의 정류 마찰계수를 증가시키는 방법 KR100240364B1 (ko)

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CA2176570A1 (en) 1995-06-29
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BR9408359A (pt) 1997-08-26
JPH09506927A (ja) 1997-07-08
AU687150B2 (en) 1998-02-19
SG48385A1 (en) 1998-04-17
DE69432154T2 (de) 2003-11-27
AU1431495A (en) 1995-07-10
EP0738314B1 (en) 2003-02-19
CA2176570C (en) 2004-03-30
WO1995017489A1 (en) 1995-06-29
US5872082A (en) 1999-02-16
JP4302769B2 (ja) 2009-07-29

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