KR960034252A - 아미노-변형 우레탄아크릴레이트 - Google Patents

아미노-변형 우레탄아크릴레이트 Download PDF

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KR960034252A
KR960034252A KR1019960006027A KR19960006027A KR960034252A KR 960034252 A KR960034252 A KR 960034252A KR 1019960006027 A KR1019960006027 A KR 1019960006027A KR 19960006027 A KR19960006027 A KR 19960006027A KR 960034252 A KR960034252 A KR 960034252A
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meth
acrylate
urethane
isocyanate
epoxy
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KR1019960006027A
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English (en)
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라이히 볼프강
벡크 에리히
카일 에드문트
예거 울리히
라카이 마티아스
프리즈 베르너
암바흐 에베르하르트
Original Assignee
귄터 슈타인호프·안드레아스 비베르바흐
바스프 악티엔게젤샤프트
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Priority claimed from DE1995108308 external-priority patent/DE19508308A1/de
Priority claimed from DE1995108310 external-priority patent/DE19508310A1/de
Application filed by 귄터 슈타인호프·안드레아스 비베르바흐, 바스프 악티엔게젤샤프트 filed Critical 귄터 슈타인호프·안드레아스 비베르바흐
Publication of KR960034252A publication Critical patent/KR960034252A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4615—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen
    • C08G18/4669—Addition products of unsaturated polyesters with amino compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/6795—Unsaturated polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

본 발명은 (a) 하나 이상의 유리 히드록실기를 가질 수 있는 폴리에테르(메트)아크릴레이트 또는 폴리에스테르(메트)아크릴레이트를, 0.5 내지 60몰%의 (메트)아크릴레이트기가 아미노 화합물과의 미하엘 첨가 생성물의 형태로 존재할 정도로, 하나 이상의 히드록실기를 갖는 일차 또는 이차 아미노 화합물과 반응시키고, (b)계속해서 (a) 포함된 생성물을 이소시아네이트와 반응시킴으로써 수득할 수 있는 우레탄(메트)아크릴레이트에 관한 것이다.

Description

아미노-변형 우레탄아크릴레이트
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 하나 이상의 유리 히드록실기를 갖고, 0.5 내지 60몰%의 (메트)아크릴레이트기가 일차 또는 이차 아민과의 미하엘 첨가 생성물의 형태로 존재하는, 폴리에테르(메트)아크릴레이트, 폴리에스테르(메트)아크릴레이트 또는 에폭시(메트)아크릴레이트를 이소시아네이트와 반응시킴으로서 수득할 수 있는 우레탄(메트)아크릴레이트.
  2. 제1항에 있어서, ⒜ 하나 이상의 유리 히드록실기를 가질 수 있는 폴리에테르(메트)아크릴레이트, 폴리에스테르(메트)아크릴레이트 및 에폭시(메트)아크릴레이트를, 0.5 내지 60몰%의 (메트)아크릴레이트기가 아미노 화합물과의 미하엘 첨가 생성물의 형태로 존재할 정도로, 하나 이상의 히드록실기를 갖는 일차 또는 이차 아미노 화합물과 반응시키고, ⒝계속해서 ⒜에 포함된 생성물을 이소시아네이트와 반응시킴으로써 수득할 수 있음을 특징으로 하는 우레탄(메트)아크릴레이트.
  3. 제1항 또는 제2항에 있어서, 폴리에스테르아크릴레이트가 사용됨을 특징으로 하는 우레탄(메트)아크릴레이트.
  4. 제1항 내지 3항 중 어느 한 항에 있어서, 폴리에테르(메트)아크릴레이트, 폴리에스테르(메트)아크릴레이트 및 에폭시 (메트)아크릴레이트가 분자 중에 1 내지 5개의 (메트)아크릴레이트기를 가짐을 특징으로 하는 우레탄(메트)아크릴레이트.
  5. 제1항 내지 4항 중 어느 한 항에 있어서, 0.5 내지 30몰%의 (메트)아크릴레이트기가 2 내지 6개의 아민수소 원자(N-H) 및 히드록실기를 갖는 아미노 화합물의 첨가에 의해 미하엘 첨가 생성물로 전환됨을 특징으로 하는 우레탄(메트)아크릴레이트.
  6. 제1항 내지 4항 중 어느 한 항에 있어서, 이소시아네이트가 분자 중에 2 내지 5개의 이소시아네이트를 가짐을 특징으로 하는 우레탄(메트)아크릴레이트.
  7. 하나 이상의 유리 히드록실기를 갖고, 0.5 내지 30몰%의 (메트)아크릴레이트기가 일차 또는 이차 아민과의 미하엘 첨가 생성물의 형태로 존재하는, 폴리에테르(메트)아크릴레이트, 폴리에스테르(메트)아크릴레이트 또는 에폭시(메트)아크릴레이트를 이소시아네이트와 반응시키는 것으로 이루어지는 제1항에 따르는 우레탄(메트)아크릴레이트의 제조 방법.
  8. 상기 단계⒜ 및 ⒝를 수행하는 것으로 이루어지는 제2항에 따르는 우레탄(메트)아크릴레이트의 제조방법.
  9. 제7항 또는 8항에 있어서, 이소시아네이트가, 히드록실기에 대해 이소시아네이트기가 거의 등몰일 정도의 양으로 사용됨을 특징으로 하는 방법.
  10. 제1항 내지 9항 중 어느 한 항에 따르는 우레탄(메트)아크릴레이트를 함유하는 방사선 경화성 재료.
  11. 제1항 내지 6항 중 어느 한 항에 따르는 우레탄(메트)아크릴레이트 또는 제10항에 따르는 방사선 경화성재료를 피복 재료로서 사용하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960006027A 1995-03-09 1996-03-08 아미노-변형 우레탄아크릴레이트 KR960034252A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE1995108308 DE19508308A1 (de) 1995-03-09 1995-03-09 Aminomodifizierte Urethanacrylate
DE19508310.5 1995-03-09
DE1995108310 DE19508310A1 (de) 1995-03-09 1995-03-09 Aminmodifizierte Urethanacrylate
DE19508308.3 1995-03-09

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KR960034252A true KR960034252A (ko) 1996-10-22

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US (2) US5734002A (ko)
EP (1) EP0731121A3 (ko)
JP (1) JPH08259660A (ko)
KR (1) KR960034252A (ko)
CA (1) CA2171264A1 (ko)

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EP4273200A1 (en) 2022-05-06 2023-11-08 IGM Group B.V. Photoinitiator package comprising specialised bisacylphosphine oxide photoinitiators and optical brightener sensitizers
WO2023214012A1 (en) 2022-05-06 2023-11-09 Igm Group B. V. Photoinitiator package comprising phosphine oxide photoinitiators, oxazole-based sensitizers and amine additives
WO2023214013A1 (en) 2022-05-06 2023-11-09 Igm Group B. V. Photoinitiator package comprising phosphine oxide photoinitiators, coumarin-based sensitizers and amine additives
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US5734002A (en) 1998-03-31
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EP0731121A2 (de) 1996-09-11
EP0731121A3 (de) 1997-06-11

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