KR960022633A - 개질된 폴리이소시아누레이트 발포체, 이의 제조방법 및 이를 함유하는 폴리올 조성물 - Google Patents

개질된 폴리이소시아누레이트 발포체, 이의 제조방법 및 이를 함유하는 폴리올 조성물 Download PDF

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KR960022633A
KR960022633A KR1019950004864A KR19950004864A KR960022633A KR 960022633 A KR960022633 A KR 960022633A KR 1019950004864 A KR1019950004864 A KR 1019950004864A KR 19950004864 A KR19950004864 A KR 19950004864A KR 960022633 A KR960022633 A KR 960022633A
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South Korea
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general formula
polyisocyanurate foam
formula
polyol
modified polyisocyanurate
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KR1019950004864A
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English (en)
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KR0184631B1 (ko
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모리히로 마쓰모토
노보루 요시다
기요타케 모리모토
사토시 나카무라
Original Assignee
나가노 다쓰오
다이도코한 가부시키가이샤
모치즈키 아키히로
닛신보세키 가부시키가이샤
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Publication of KR960022633A publication Critical patent/KR960022633A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3215—Polyhydroxy compounds containing aromatic groups or benzoquinone groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/325—Polyamines containing secondary or tertiary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/06—Oligomerisation to carbodiimide or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/60—Compositions for foaming; Foamed or intumescent adhesives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/901—Cellular polymer containing a carbodiimide structure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/902—Cellular polymer containing an isocyanurate structure

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

프레온 등으로 대표되는 증발형 발포제를 사용하지 않고서도 기계적 물성이 우수한 개질된 폴리이소시아누레이트 발포체를 제조하는 것을 목적으로 한다.
유기 폴리이소시아네이트, 폴리올, 물 및 일반식(I) 또는 일반식(III)의 방향족 화합물(a)을 이소시아네이트의 삼량체화 촉매 (b)와 포스포릴렌 옥사이드로 이루어진 카보디이미드화 촉매의 존재하에서 반응시킨다.
상기 식에서, R1및 R2는 각각 H 또는 CH3이고, R3및 R4는 각각또는여기서, n은 1 내지 4이다)이고, R5및 R6는 각각 탄소수 1 내지 4의 알킬기이다.

Description

개질된 폴리이소시아누레이트 발포체, 이의 제조방법 및 이를 함유하는 폴리올 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 유기 폴리이소시아네이트, 폴리올, 물 및 아래 일반식(I) 또는 일반식(II)의 방향족 화합물(a)을 이소시아네이트의 삼량체화 촉매 (b) 및 아래 일반식(III) 또는 일반식(IV)의 포스포릴렌 옥사이드(c)로 이루어진 카보디이미드화 촉매의 존재하에서 반응시킴을 특징으로 하는 개질된 폴리이소시아누레이트 발포체의 제조방법.
    상기 식에서, R1및 R2는 각각 H 또는 CH3이고, R3및 R4는 각각또는(여기서, n은 1 내지 4이다)이고, R5및 R6는 각각 탄소수 1 내지 4의 알킬기이고, R7은 치환되거나 치환되지 않은 알킬, 페닐, 나프틸 또는 벤질기이고, R8, R9, R10, R11, R12및 R13은 각각 H, Cl 또는 탄소수 1 내지 4의 알킬기이다.
  2. 제1항에 있어서, 일반식(I) 또는 일반식(II)의 방향족 화합물을, 이 화합물과 유기 폴리이소시아네이트, 폴리올 및 물의 합계중량을 기준으로 하여 0.5내지 10.0중량%의 양으로 사용하는 개질된 폴리이소시아누레이트 발포체의 제조방법.
  3. 폴리올, 물, 제1항에 따른 일반식(I) 또는 일반식(II)의 방향족 화합물, 이소시아네이트의 삼량체화 촉매 및 제1항에 따른 일반식(III)또는 일반식(IV)의 포스포릴렌옥사이드로 이루어진 폴리올 조성물.
  4. 제1항 또는 제2항에 따른 제조방법에 의해 제조된 개질된 폴리이소시아누레이트 발포체.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019950004864A 1994-12-07 1995-03-10 개질된 폴리이소시아누레이트 발포체, 이의 제조방법 및 이를 함유하는 폴리올 조성물 KR0184631B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP94-304019 1994-12-07
JP6304019A JP2584955B2 (ja) 1994-12-07 1994-12-07 変性ポリイソシアヌレート発泡体及びその製造法並びにポリオール組成物

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KR960022633A true KR960022633A (ko) 1996-07-18
KR0184631B1 KR0184631B1 (ko) 1999-05-15

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US (1) US5627220A (ko)
EP (1) EP0716106A3 (ko)
JP (1) JP2584955B2 (ko)
KR (1) KR0184631B1 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE294207T1 (de) 1998-09-10 2005-05-15 Dow Global Technologies Inc Geeignete polyole für die herstellung von wassergeschäumtem polyurethanhartschaumstoff
US20040176494A1 (en) * 2003-03-05 2004-09-09 Feske Elbert F. Preparation of flame retarded polyisocyanurate foams
US8258198B2 (en) * 2004-05-28 2012-09-04 Air Products And Chemicals, Inc. Fast demold/extended cream time polyurethane formulations
EP1997616B1 (en) * 2007-06-01 2009-08-26 Sika Technology AG Honeycomb sandwich panels and the use of a two component polyurethane adhesive in the manufacture thereof
KR100935701B1 (ko) * 2008-05-28 2010-01-07 한국신발피혁연구소 내가수분해성이 우수한 저비중 폴리우레탄 발포체 조성물
WO2013134247A1 (en) 2012-03-06 2013-09-12 Basf Se Method of producing a flexible polyurethane foam article
CN108250404A (zh) * 2017-12-28 2018-07-06 青岛海尔股份有限公司 聚氨酯硬质泡沫塑料及其制备方法
BR112020013119A2 (pt) * 2018-01-16 2020-12-01 Huntsman International Llc mistura de reação para fazer um poli-isocianurato, processo para fazer um poli-isocianurato, material compreendendo poli-isocianurato, uso do material compreendendo poli-isocianurato, e, material compósito.

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US3657161A (en) 1967-10-31 1972-04-18 Baychem Corp Polycarbodiimide-polyisocyanurate foam
US3919128A (en) * 1973-05-18 1975-11-11 Ici America Inc Urethane-modified polyisocyanurate foams
US3894972A (en) 1973-12-21 1975-07-15 Basf Wyandotte Corp Process for the preparation of carbodiimide-isocyanurate foams
US3928256A (en) 1974-02-25 1975-12-23 Basf Wyandotte Corp Process for the preparation of carbodiimide-isocyanurate foams
US3922238A (en) * 1974-05-23 1975-11-25 Basf Wyandotte Corp Carbodiimide-isocyanurate foams containing urethane linkages
US3994837A (en) 1974-10-02 1976-11-30 Basf Wyandotte Corporation Urethane-modified carbodiimide-isocynurate foams prepared from TDI-rich isocyanates
US3998766A (en) 1974-12-26 1976-12-21 Basf Wyandotte Corporation Urethane modified carbodimide-isocyanurate foams from organic polyisocyanates and oxyalkylated mannich polyols
US3981829A (en) 1974-12-30 1976-09-21 Basf Wyandotte Corporation Process for the preparation of carbodiimide-isocyanurate foams
US4040992A (en) 1975-07-29 1977-08-09 Air Products And Chemicals, Inc. Catalysis of organic isocyanate reactions
US3994893A (en) 1975-11-03 1976-11-30 E. R. Squibb & Sons, Inc. 4-Amino derivatives of pyrozolo[1,5-a]quinoxaline-3-carboxylic acid and esters
US4166164A (en) 1977-12-05 1979-08-28 Basf Wyandotte Corporation Process for the preparation of carbodiimide-isocyanurate foams
GB8902228D0 (en) 1989-02-01 1989-03-22 Ici Plc Carbodiimide-isocyanurate rigid foams
GB9126741D0 (en) * 1991-12-17 1992-02-12 Ici Plc Polyurethane foams
US5223551A (en) * 1991-12-26 1993-06-29 Uop Urea-modified isocyanurates and method of making rigid foams thereof
JP2604953B2 (ja) * 1992-10-23 1997-04-30 日清紡績株式会社 変性ポリイソシアヌレート発泡体の製造法

Also Published As

Publication number Publication date
EP0716106A2 (en) 1996-06-12
KR0184631B1 (ko) 1999-05-15
US5627220A (en) 1997-05-06
JPH08157550A (ja) 1996-06-18
EP0716106A3 (en) 1997-02-19
JP2584955B2 (ja) 1997-02-26

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