KR960014360B1 - Detergent composition and its process - Google Patents

Abstract

The detergent containing 100 wt% water and surfactant is composed of 0.5-50 wt% green tea extracts, 1-50 wt% phorphyry granite and 1-20 wt% citric acid. The liquid or paste state detergent is prepared by (a) heating 100 wt% purified water and 1-50 wt% green tea leaves at 90-95 deg.C and filtering the heated solution, (b) cooling the green tea extracts from the room temperature to 70 deg.C, (c) stirring to mixing 1-50 wt% phorphyry granite, 1-25 wt% citric acid and the extracts, (d) adding 50-200 wt% surfactant and water to the mixed solution.

Description

High functional cleaning composition and its manufacturing method

The present invention relates to a high functional cleaning composition and a method for producing the same, and more particularly, to a high functional cleaning composition containing a green tea extract, elvan powder and citric acid in a surfactant.

Many compositions are known as detergents that apply to the surface or scalp of the body. These detergents have generally been prepared and used in liquid or solid phase with the addition of flavor and one or two functional ingredients to the surfactant.

Korean Patent Publication No. 93-4587 discloses a hair tonic composition containing an extract of a herb called dong chong xia cao. Hair tonic compositions containing this extract are described in this document to prevent dandruff and scalp pruritus and to promote hair growth.

Meanwhile, Korean Patent Publication No. 93-7914 discloses a composition for topical application to skin or hair containing 1 to 99% by weight of short-chain dialkyl or dialkyl salts and 1 to 99% by weight of monoalkyl or monoalkenyl salts. It is said that the application of this composition to the skin not only effectively establishes the skin but also gives a smooth and soft feeling even after the skin surface is dried.

In addition, Korean Patent Publication No. 94-1002 discloses a composition for removing dandruff containing a horsetail extract, and Korean Patent Publication No. 94-9323 discloses an animal and vegetable oil containing a powder of ganbanite powder and germanium. It describes a method for producing a mixed bath body cleanser solution.

Accordingly, it is an object of the present invention to provide a method for producing a high-functional cleaning composition that softens the skin and suppresses and treats dandruff and skin troubles with excellent cleaning power when applied to the skin and hair.

According to the present invention, in a cleaning composition comprising a surfactant and water, 0.5 to 50 parts by weight of green tea extract, 1 to 50 joules and 1 to citric acid, based on the total weight of the surfactant and water (100 parts by weight) There is provided a cleaning composition comprising 20 parts by weight.

Green tea leaves have been found to contain hundreds of compounds that exhibit a variety of biological activities. Green tea also contains a large amount of tannin, albumin, and vitamin P, compared to fermented tea, and vitamin C is about 10 times higher. Also, about 30 kinds of polyphenolic compounds such as catechins and flavonoids, alkaloids, pigments, amino acids, minerals and various enzymes are included. Catechin, a polyphenolic compound of green tea, has the effect of strengthening capillaries, and when the resistance of capillaries due to senescence decreases with vitamin P and trace elements contained in green tea. In addition, green tea is externally effective in treating oral diseases, skin diseases, burns and radiation damage, and also has a bactericidal effect, which is known to be effective in removing pathogenic bacterial layers present in humans (Aleksey I. Schroeter ( 1993), Scientific Investigations of Tea Biological Activity in Russia and Former Soviet Union, Procedings of The 2nd International Symposium on Green Tea, pp. 57--65).

On the other hand, Nobu-Yo-Yang et al. Noted that catechins (GTC) of green tea were both early and accelerated during the carcinogenesis of the small intestine by nitrosamines, and during the carcinogenesis of the breast by DMABA, and Glu-P-1. Has been shown to exert a strong chemical preventive effect in the carcinogenesis of liver (Nobuyuki Ito et al., Chemoprovention of Chemical Carcinogenesis by Green Tea Components, supra, pp. 23-31), Hassan et al. Ingestion of polyphenolic substances (GTD) suppresses the induction of cancer, and as a result of biological tests for skin cancer in mice, applying GTD to the skin of mice prevents cancer by preventing carcinogens from defects with the DNA of epidermal cells. The two types of carcinogens are said to have significant preventive effects such as edema on the skin, abnormal growth of the epidermis and degradation of the antioxidant defense system of the epidermis. In particular, it has been described that it prevents the occurrence of dermatitis and skin cancer caused by ultraviolet rays and prevents carcinogens from binding to the DNA of epidermal cells (Hasan Mukhtar et al., Anticarcinogenic and antiinflammatory effects of Green Tea in Murine Skin, supra, pp. 35-46).

Moreover, Lee Seo-rae et al. Said that green tea extract has an excellent effect of removing heavy metals (Eserae et al., Heavy metal removal effect of green tea beverages, pp. 77-87, above), illustrating the effect of green tea on the skin. Such green tea can be easily obtained by immersing the green tea leaves in a known method, i. If necessary, an extraction method using an organic solvent may also be considered.

Green tea extract may be included in the cleaning composition from the minimum amount capable of exerting its medicament up to the maximum amount capable of forming the cleaning composition. However, in consideration of the cost of the drug effect, it is preferably contained in the range of 0.5 to 50 parts by weight based on the weight (100 parts) of the cleaning composition containing the surfactant and water.

Elvan is widely used in water purification products, cosmetics, and pharmaceuticals, and its use is expanding to textiles. Elvanite is SiO ₂ (54.9%), Fe ₃ O ₄ (4.2%), C ₃ O (2.6%), MgO (1.3%), Na ₂ O (5.1%), K ₂ O (1.4%), MnO ₂ (1.2%), TiO ₂ (2.1%), Al ₂ O ₃ (19.2%), GeO (0.2%), P ₂ O ₂ (0.2%), ZYO ₂ (1.6%), moisture (1.4%), others It is a composite composed of components (4.6%), and the composition ratio may vary depending on the product.

Elvan is known to have excellent effects on skin diseases such as eczema, athlete's foot, blemishes, acne, freckles, and dandruff, and is known to have hemostatic and anti-inflammatory effects. Moreover, it is believed that elvan has a beneficial effect due to far infrared rays because it emits a large amount of far infrared rays which is beneficial to the human body (연구소 式 會 社 パ テ ツ ク シ ヤ パ ソ, N.E.S research institute), and its pharmacological action is also described in the synonym. The organic material has a natural frequency of heat according to the material. When the organic material coincides with the frequency of the far infrared rays, the strong far-infrared rays of the elvan have a beneficial effect on the skin because the molecules self-heat internally and activate the cells by the action of resonance and resonance.

Elvan can be included in the cleaning composition from the minimum amount that can exert its efficacy to the maximum amount that can form the cleaning composition. However, in consideration of the cost of the drug effect, it is preferably contained in the range of 1 to 50 parts by weight based on the weight (100 parts) of the cleaning composition containing the surfactant and water.

Citric acid, on the other hand, is a major substance in the Kriggs cycle discovered by Dr. Krebs, which is known to rapidly decompose lactic acid, a fatigue substance in the body, and to facilitate metabolism. Citric acid may also be included in the cleaning composition from the minimum amount that can exert its efficacy in the cleaning composition to the maximum amount that can form the cleaning composition. However, in consideration of the cost of the drug effect, it is preferably contained in the range of 0.5 to 50 parts by weight based on the weight (100 parts) of the cleaning composition containing the surfactant and water.

As a result of preparing a detergent by adding citric acid together with green tea extract and elvan, the present inventors found that not only washing the wastes of skin cleanly, but also disinfecting and moisturizing and further preventing the dandruff of the scalp. In particular, due to the synergistic action of the green tea extract, alum and citric acid of the present invention, the composition of the present invention has been found to be very effective in the treatment of skin problems such as cremation of the face or acne, blemishes.

The surfactant used in the present invention can be used for any of those used in this field, such as anionic, cationic or amphoteric surfactants. Examples of anionic surfactants include higher fatty acid salts, higher alcohol sulfate ester salts, alkylsulfonate salts, higher alkyldisulfonates, sulfonated higher fatty acid salts, higher alkylphosphate esters, higher fatty acid and proteolytic amino acid condensates, and alkylbenzene sulfones. Acid salts, alkylbenzo imidazole sulfonates, naphthenates or amines. Amphoteric surfactants include betaine type or persistol type amphoteric surfactants. Examples of nonionic surfactants include glycerol esters of higher fatty acids, glycol esters of higher fatty acids, pentaerythritol esters, higher alcohol condensates, higher alkylamine condensates or higher fatty acid amide condensates. In addition, any surfactant suitable for the purpose of the present invention may be used, and for example, the formulation of the surfactant described in Korean Patent Publication No. 93-7914 or 93-4587 may be used.

These surfactants have different cleaning powers, foaming ability, and effects on the skin for each raw material, so they must be selected and manufactured according to the intended use. That is, in order to improve affinity for the human skin and to prevent water pollution, it is preferable to use a surfactant prepared based on vegetable oils (such as palm oil). In order to prepare the dishwashing detergent, a surfactant based on mineral oil may be used together with a surfactant based on vegetable oil to enhance washing power.

In addition to the surfactant and the characteristic addition components of the present invention, known cleaning agents, humectants, thickeners, pigments and / or flavor components can be appropriately added to the cleaning composition.

The cleaning composition of the present invention can be prepared in liquid or cream form suitable for use. Liquid compositions can be prepared by increasing the content of water and lowering the content of surfactants and additives. In contrast, creamy compositions can be prepared by increasing the additive components instead of lowering the water content. The preparation of the liquid or creamy composition can be appropriately prepared according to the knowledge in the art.

The composition of the present invention can be prepared as a dishwashing detergent by appropriately selecting the components of the surfactant, which is particularly suitable for home use because it protects hands without losing skin while maintaining good cleaning power. In addition, when washing vegetables, fruits or foods with the composition of the present invention has a sterilizing and deodorizing effect, there is an effect that the freshness is maintained for a long time.

The cleaning composition of the present invention is 1 to 50 parts by weight of green tea leaves in 100 parts by weight of purified water and heated to 90 to 95 ℃ and filtered to provide a green tea extract, after cooling the green tea extract to 70 ℃ at room temperature 1 To 50 parts by weight and 1 to 25 parts by weight of citric acid may be added and stirred, and 50 to 200 parts by weight of surfactant and an appropriate amount of water are added to the resulting mixture.

In another aspect of the present invention, the composition may be prepared by adding silver powder to the composition of the present invention. Silver binds to proteins and has a strong bactericidal action, and has been reported to have astringent action and antiseptic effect (1993, 「無機 藥 化學”, 東 明 Co., Ltd.). Therefore, the addition of silver powder in the range of 0.1 to 5 parts by weight, based on the weight of water and surfactant (100 parts by weight), not only shows bactericidal action when applied to the skin, but also greatly aids in the biological stability of the composition itself. do.

It is to be understood that the additives of the present invention can be appropriately added within the range of the minimum amount that can exert the effect and the maximum amount that no longer enhances the effect.

In addition, according to the condition and purpose of the product, it is preferable to add a medium, a preservative, a moisturizing agent or a cosmetic agent to prepare for the intended use.

Production Example

Preparation of Additive Composition

10 parts by weight of green tea leaves were added to 100 parts by weight of purified water and heated to 90 to 50 ° C to leach the green tea components. The mixture was filtered to remove the leaf components and then cooled to 70 ° C. at room temperature. 10 parts by weight of elvan and 3 parts by weight of citric acid were added thereto and stirred to prepare an additive composition of the present invention.

Example 1

Preparation of bath cleaner (colloid type)

10 kg of sodium lauryl sulfate, 27 kg of sodium lauryl ether sulfate, and 13 kg of triethanolamine laurisulfate were mixed in 43.2 kg of distilled water in a tank. Subsequently, 1 kg of lanolin as a cosmetic moisturizer, 0.5 kg of sodium benzoate as a preservative, and 1 kg of monoglyceride as a lubricant were added thereto, and the mixture was stirred uniformly while heating to 70 ° C.

Again, 4 kg of cocodiethanolamine, 17 kg of the additive composition prepared in Preparation Example, and an appropriate amount of flavor (cody flavor) were added as a thickener, and the mixture was cooled to 40 ° C and added for 10 minutes. When cooled to 30 ° C., stirring was stopped and the product was poured into the vessel.

Example 2

Preparation of kitchen cleaners

To 51.5 kg of distilled water 40 kg of sodium lauryl sulfate, 1.5 kg of lanolin, 4 kg of cocodiethanol amine and 0.5 kg of quaternary ammonium were heated to 60 ° C under stirring. To this mixture was added an additive composition prepared in the production example at 60 ° C. (with 5 parts by weight of elvan) and stirred. The mixture was cooled to 30 ° C. at room temperature and poured into the vessel.

Example 3

Preparation of Silver-Containing Cleaner

0.5 parts by weight of silver powder was further added to 100 parts by weight of distilled water in the preparation example to prepare an additive composition by uniformly stirring, and a cleaner was prepared in the same manner as in Example 1.

Test Example 1

Test of Cleaning Composition for Bath

Three teenage boys, three males in their twenties, two males in their thirties, one male in their 40s, one male in their 50s (10 males in total), five teenage girls, ten females in their twenties, 30 A total of 40 test groups consisted of 10 women in their teens and 5 women in their 40s (30 women in total).

To this test group, the bath cleaning composition of this invention prepared in Example 1 was applied twice a day (morning, evening). The method of use was applied to the skin and hair soaked in water and then rubbed for 1 or 2 minutes as a massage and washed off.

As a result of the test, mild skin diseases (cosmetic poisoning, wound and acne) and itching all improved in 2 to 5 days. In addition, as a result of application to hair all prevent dandruff and improve itching.

In addition, after applying it to the face of a woman with severe acne in her twenties, her symptoms improved for a week, and after one month of continuous use, her acne symptoms disappeared.

However, one woman in her 20s, who had allergies, gave up using allergy symptoms within 3 days of application.

All skin examiners except the above allergic patients showed that as a result of using the composition of the present invention, dandruff and itching were eliminated, and the skin was soft and moist and had a whitening effect. In addition, female subjects responded not only to makeup removal but also to smooth skin and good makeup. Furthermore, the subjects stated that the action of the flavonoids contained in the green tea provided a deodorizing effect, resulting in a fresh cleaning feeling.

Test Example 2

Test of Dish Cleaning Composition

The dishwashing composition prepared in Example 2 was applied to 10 female subjects in their 20s and 30s. These subjects were diluted 10-fold with the cleaning composition and applied to their hands and washed off 5 minutes later. After 10 days of use in this way, the reaction was examined and showed no damage to the hands and a smooth skin. In addition, the eczema symptoms of the subjects with eczema on the finger showed a remarkable effect.

Test Example 3

Vegetable washing test

Lettuce was rinsed with rinse and washed with the dishwashing composition prepared in Example 2 and a commercial dishwashing composition commercially available. The washed lettuce was stored for 5 hours at room temperature. After 5 hours, the lettuce was visually observed. When the general detergent was used, the lettuce was wilted (die of grass) and was not suitable for eating. On the other hand, when the composition of the present invention was used, the lettuce was kept fresh without being wilted.

As described above, the composition of the present invention, in addition to excellent detergency, removal of waste and foreign substances (heavy metals), skin protection, sterilization, skin diseases (acne, itching, blemish, eczema) by the mutual complementary and synergistic action of green tea extract, ganban stone and citric acid It is clear that the action to prevent and treat). In addition, since the green tea extract has a function of binding to and removing heavy metals, it is believed to have a desirable function in the pharmacological action of the composition of the present invention. Moreover, the advantages of the present invention are obvious because the new type of creamy composition is convenient for use and better in touch, and the composition of the present invention is expected to contribute greatly to the improvement of public health.

Although the present invention has been described with reference to preferred embodiments as described above, it should be understood that substitutions, changes, and transformations apparent to those skilled in the art within the scope of the present invention fall within the scope of the present invention.

Claims (4)

A detergent composition comprising a surfactant and water, comprising 0.5 to 50 parts by weight of green tea extract, 1 to 50 parts by weight of ganban stone and 1 to 20 parts by weight of citric acid, based on the total weight of the surfactant and water (100 parts by weight). High functional cleaning composition. The high functional cleaning composition according to claim 1, wherein the composition is liquid or cream (semi-solid). The high functional cleaning composition according to claim 1 or 2, further comprising 0.1 to 5 parts by weight of silver powder based on the total weight of the surfactant and water. 1 to 50 parts by weight of green tea leaves in 100 parts by weight of purified water and heated to 90 to 95 ℃ and filtered to provide a green tea extract, and after cooling the green tea extract to 70 ℃ at room temperature 1 to 50 parts by weight and citric acid Adding 1 to 25 parts by weight to stir, and adding 50 to 200 parts by weight of surfactant and a suitable amount of water to the resulting mixture.