KR960006665B1 - Process for the carbonylation of conjugated dienes - Google Patents
Process for the carbonylation of conjugated dienes Download PDFInfo
- Publication number
- KR960006665B1 KR960006665B1 KR87013726A KR870013726A KR960006665B1 KR 960006665 B1 KR960006665 B1 KR 960006665B1 KR 87013726 A KR87013726 A KR 87013726A KR 870013726 A KR870013726 A KR 870013726A KR 960006665 B1 KR960006665 B1 KR 960006665B1
- Authority
- KR
- South Korea
- Prior art keywords
- phosphorus
- antimony
- electron
- conjugated dienes
- aryl group
- Prior art date
Links
- 230000006315 carbonylation Effects 0.000 title abstract 2
- 238000005810 carbonylation reaction Methods 0.000 title abstract 2
- 150000001993 dienes Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract 3
- 239000011574 phosphorus Substances 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical class [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- MRUDNSFOFOQZDA-UHFFFAOYSA-N 2,6-dichlorobenzoic acid Chemical compound OC(=O)C1=C(Cl)C=CC=C1Cl MRUDNSFOFOQZDA-UHFFFAOYSA-N 0.000 abstract 1
- XGWFJBFNAQHLEF-UHFFFAOYSA-N 9-anthroic acid Chemical compound C1=CC=C2C(C(=O)O)=C(C=CC=C3)C3=CC2=C1 XGWFJBFNAQHLEF-UHFFFAOYSA-N 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- 229910052785 arsenic Chemical group 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8603101 | 1986-12-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR960006665B1 true KR960006665B1 (en) | 1996-05-22 |
Family
ID=19848955
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR860013726A KR880007427A (ko) | 1986-12-05 | 1986-12-02 | 공역 디엔의 카르보닐화 방법 및 이를 위한 촉매 시스템 |
| KR87013726A KR960006665B1 (en) | 1986-12-05 | 1987-12-02 | Process for the carbonylation of conjugated dienes |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR860013726A KR880007427A (ko) | 1986-12-05 | 1986-12-02 | 공역 디엔의 카르보닐화 방법 및 이를 위한 촉매 시스템 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4824817A (ko) |
| EP (1) | EP0271145B1 (ko) |
| JP (1) | JP2739644B2 (ko) |
| KR (2) | KR880007427A (ko) |
| CN (1) | CN1023218C (ko) |
| AT (1) | ATE66456T1 (ko) |
| AU (1) | AU593413B2 (ko) |
| CA (1) | CA1313177C (ko) |
| DE (1) | DE3772344D1 (ko) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR880007418A (ko) * | 1986-12-10 | 1988-08-27 | 오노 알버어스 | 공역 디엔의 선택적 카르보닐화 방법 및 이를 위한 유기 질소-함유 열기를 갖지 않는 촉매 시스템 |
| ES2081469T5 (es) * | 1989-12-29 | 2001-09-01 | Dow Chemical Co | Procedimiento continuo para la telomerizacion de dienos conjugados. |
| US5166411A (en) * | 1990-02-05 | 1992-11-24 | Shell Oil Company | Carbonylation catalyst system |
| US5026901A (en) * | 1990-03-29 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Palladium catalyzed carboalkoxylation of butadiene |
| GB9111583D0 (en) * | 1991-05-30 | 1991-07-24 | Shell Int Research | Carbonylation catalyst system |
| US5258546A (en) * | 1991-05-30 | 1993-11-02 | Shell Oil Company | Carbonylation catalyst system |
| SG49630A1 (en) * | 1992-04-08 | 1998-06-15 | Shell Int Research | Carbonylation process using palladium phosphine catalyst |
| EP0577205B1 (en) * | 1992-06-29 | 1997-10-08 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of conjugated dienes |
| KR100295155B1 (ko) * | 1992-06-29 | 2001-11-05 | 오노 알버어스 | 알켄산유도체제조방법 |
| KR960031420A (ko) * | 1995-02-22 | 1996-09-17 | 미키엘 크램윈켈. | 부티디엔 또는 부타디엔 유도체의 카르보닐화 방법 |
| US5495041A (en) * | 1995-02-22 | 1996-02-27 | Dsm N.W. | Process for the preparation of a pentenoate ester |
| DE19510324A1 (de) * | 1995-03-22 | 1996-09-26 | Basf Ag | Verfahren zur Herstellung von 3-Pentensäureestern durch Carbonylierung von Alkoxybutenen |
| US5886236A (en) * | 1997-04-15 | 1999-03-23 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing aldehyde acid salts |
| US5925754A (en) * | 1997-04-15 | 1999-07-20 | Union Carbide Chemicals & Plastics Technology Corporation | Epsilon caprolactam compositions |
| US5962680A (en) * | 1997-04-15 | 1999-10-05 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for producing epsilon caprolactams |
| US6049005A (en) * | 1997-10-07 | 2000-04-11 | Dsm N.V. | Process to prepare a pentenoic acid anhydride |
| US6010975A (en) * | 1998-06-19 | 2000-01-04 | Industrial Technology Research Institute | Catalyst composition for preparing 3-pentenoic ester from butadiene |
| TW524801B (en) * | 1999-03-22 | 2003-03-21 | Shell Int Research | Process for the carbonylation of conjugated dienes |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3887595A (en) * | 1973-03-05 | 1975-06-03 | Shell Oil Co | Carbonylation process |
| US4243829A (en) * | 1976-10-04 | 1981-01-06 | Charles U. Pittman, Jr. | Production of 1,7-octadiene from butadiene |
| US4172087A (en) * | 1978-02-13 | 1979-10-23 | Texaco Development Corporation | Process for preparing unsaturated aliphatic esters from aliphatic dienes |
| FR2450802A1 (fr) * | 1979-03-07 | 1980-10-03 | Inst Francais Du Petrole | Procede de fabrication d'acetate d'allyle par oxydation du propylene |
| US4292437A (en) * | 1979-06-27 | 1981-09-29 | E. I. Du Pont De Nemours And Company | Preparation of isobutyric acid and esters |
| GB2058074B (en) * | 1979-08-23 | 1983-10-12 | Secr Defence | Palladium complexes |
| US4582817A (en) * | 1981-04-27 | 1986-04-15 | National Distillers And Chemical Corporation | Process for the preparation of alkyl nonadienoate esters |
| US4471067A (en) * | 1981-11-09 | 1984-09-11 | Celanese Corporation | Dimeric carbonylation of 1,3-alkadiene |
| US4501822A (en) * | 1982-01-26 | 1985-02-26 | Celanese Corporation | Hydroesterification of 1-alkene |
| GB8501919D0 (en) * | 1985-01-25 | 1985-02-27 | Shell Int Research | Carbonylation of allenically unsaturated compounds |
| GB8509641D0 (en) * | 1985-04-15 | 1985-05-22 | Shell Int Research | Carboxylic di-esters/acids |
-
1986
- 1986-12-02 KR KR860013726A patent/KR880007427A/ko unknown
-
1987
- 1987-11-16 CA CA000551899A patent/CA1313177C/en not_active Expired - Fee Related
- 1987-11-23 US US07/124,128 patent/US4824817A/en not_active Expired - Lifetime
- 1987-11-25 EP EP87202333A patent/EP0271145B1/en not_active Expired - Lifetime
- 1987-11-25 DE DE8787202333T patent/DE3772344D1/de not_active Expired - Fee Related
- 1987-11-25 AT AT87202333T patent/ATE66456T1/de not_active IP Right Cessation
- 1987-12-02 KR KR87013726A patent/KR960006665B1/ko not_active IP Right Cessation
- 1987-12-03 JP JP62304704A patent/JP2739644B2/ja not_active Expired - Fee Related
- 1987-12-03 AU AU82067/87A patent/AU593413B2/en not_active Ceased
- 1987-12-03 CN CN87107284A patent/CN1023218C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2739644B2 (ja) | 1998-04-15 |
| CA1313177C (en) | 1993-01-26 |
| JPS63154641A (ja) | 1988-06-27 |
| KR880007427A (ko) | 1988-08-27 |
| EP0271145B1 (en) | 1991-08-21 |
| ATE66456T1 (de) | 1991-09-15 |
| EP0271145A3 (en) | 1988-07-20 |
| CN87107284A (zh) | 1988-06-15 |
| CN1023218C (zh) | 1993-12-22 |
| AU8206787A (en) | 1988-06-09 |
| EP0271145A2 (en) | 1988-06-15 |
| AU593413B2 (en) | 1990-02-08 |
| US4824817A (en) | 1989-04-25 |
| DE3772344D1 (de) | 1991-09-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20040421 Year of fee payment: 9 |
|
| LAPS | Lapse due to unpaid annual fee |