KR950704187A - 기체로부터 NOx/SOx 산화물을 제거하는 방법(Process for removing NOx/SOx oxides from gases) - Google Patents

기체로부터 NOx/SOx 산화물을 제거하는 방법(Process for removing NOx/SOx oxides from gases)

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Publication number
KR950704187A
KR950704187A KR1019950702056A KR19950702056A KR950704187A KR 950704187 A KR950704187 A KR 950704187A KR 1019950702056 A KR1019950702056 A KR 1019950702056A KR 19950702056 A KR19950702056 A KR 19950702056A KR 950704187 A KR950704187 A KR 950704187A
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South Korea
Prior art keywords
aqueous solution
aqueous
oxides
solution
alkali metal
Prior art date
Application number
KR1019950702056A
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English (en)
Inventor
제이. 캣쳐 제리
에이. 아이아코빌로 스티븐
엘. 던칸 버드
Original Assignee
폴 웨인스타인
올린 코포레이션
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Application filed by 폴 웨인스타인, 올린 코포레이션 filed Critical 폴 웨인스타인
Publication of KR950704187A publication Critical patent/KR950704187A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/507—Sulfur oxides by treating the gases with other liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)

Abstract

기체 스트림으로부터 질소 산화물(NOx)과 황 산화물(SOx)을 제거하는 방법에 대해 기술하였다. 기체상 스트림은 산화 세정기(14)속에서 염소산의 수용액과 접촉시킨다.
그다음, 생성된 산화 기체상 스트림을 세정기(30)속에서 물, 알칼리 화합물의 수용액 또는 황계 환원제의 수용액과 접촉시켜 질소 산화물과 황 산화물을 산화 기체상 스트림으로부터 제거한다. 본 발명의 방법은 유독하거나 촉매를 사용하는 NOx 제거 시스템을 오염시킬 수 있는 입자와 화합물을 함유하는 “분진”기체를 처리하는데 취급할 수 있다.

Description

기체로부터 NOx/SOx 산화물을 제거하는 방법(Process for removing NOx/SOx oxides from gases)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 방법을 수행하기 위한 시스템의 개략도이다. 제1도는 NOx산화물과 SOx산화물을 함유하는 폐 기체를 정제하기 위하여, 참고번호 10으로 제시되어 있는, 본 발명의 방법을 수행하기 위한 시스템을 도시한 것이다.

Claims (10)

  1. (a)NOx산화물, SOx산화물 또는 이들의 혼합물을 함유하는 기체상 스트림을 NOx산화물과 SOx산화물의 산화가능한 종이 산화되기에 충분한 시간 동안 산화 세정기 속에서 약0내지 약100℃에서 필수적으로 염소산 또는 염소산과 알칼리 금속 염소산염의 혼합물의 이루어진 산화수용액과 접촉시키는 단계(여기서, 염소산 공급물 농도는 산화 수용액의 약0.05 내지 약50중량%이고, 산화 수용액은 다른 양이온성 불순물과 음이온성 불순물을 실질적으로 함유하지 않는다), (b)산화가능한 NOx산화물과 SOx산화물의 산화에 의해 생성된 질산, 황산 또는 이들의 혼합물을 함유하는 산화수용액으로부터 산화된 기체상 스트림을 분리하는 단계, (c)산화된 기체상 스트림을 NOx산화물, SOx산화물 또는 이들의 혼합물이 산화된 기체사아 스트림으로부터 실질적으로 전부 제거되기에 충분한 시간 동안 수성 세정기속에서 물, 알칼리성 화합물의 수용액 또는 황계 환원제의 수용액으로 이루어진 그룹으로부터 선택되는 수용액과 접촉시키는 단계 및 (d)NOx산화물 SOx산화물 또는 이들의 혼합물을 실질적으로 함유하지 않는 산화된 기체상 스트림을 당해 수용액으로부터 분리하는 단계를 특징으로 하는, NOx산화물, SOx산화물 또는 이들의 혼합물을 기체상 스트림으로부터 제거하는 방법.
  2. 제1항에 있어서, 산화수용액이 필수적으로 염소산으로 이루어짐을 특징으로 하는 방법.
  3. 제1항에 있어서, 산화 수용액이 필수적으로 염소산과 알칼리 금속 염소산염과의 혼합물로 이루어짐을 특징으로 하는 방법.
  4. 제3항에 있어서, 알칼리 금속 염소산염이 염소산 나트륨임을 특징으로 하는 방법.
  5. 제1항에 있어서, 단계(a)에서의 온도가 약20내지 약80℃인 방법.
  6. 제1항에 있어서, 염소산 공급물 농도가 산화 수용액의 약 1.0 내지 40중량인 방법.
  7. 제1항에 있어서, 산화 수용액이 과산화수소, 알칼리 금속 과산화물, 알콜 및 탄수화물 당으로 이루어진 그룹으로부터 선택되는 환원제를 추가로 함유함을 특징으로 하는 방법.
  8. 제1항에 있어서, 단계(c)에서의 수용액이 황게환원제임을 특징으로 하는 방법.
  9. 제8항에 있어서, 단계(c)에서의 수용액이 알칼리 금속황화물, 알칼리 토금속 황화물, 하이드로황화물, 아황산염, 중아황산염, 하이드로아황산염 및 티오아황산염으로 이루어진 그룹으로부터 선택되는 황계 환원제의 수용액임을 특징으로 하는 방법.
  10. 제1항에 있어서, 단계(b)에 의해 생성된 분리된 산화 수용액이 단계(d)에 의해 생성된 분리된 수용액을 중화시키는 데 사용되는 방법.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019950702056A 1992-11-23 1993-11-15 기체로부터 NOx/SOx 산화물을 제거하는 방법(Process for removing NOx/SOx oxides from gases) KR950704187A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/980,075 US5328673A (en) 1992-11-23 1992-11-23 Process for removal of NOx and SOx oxides from waste gases with chloric acid
US07/980075 1992-11-23
PCT/US1993/011006 WO1994012429A1 (en) 1992-11-23 1993-11-15 PROCESS FOR REMOVING NOx/SOx OXIDES FROM GASES ______________

Publications (1)

Publication Number Publication Date
KR950704187A true KR950704187A (ko) 1995-11-17

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Country Status (10)

Country Link
US (1) US5328673A (ko)
EP (1) EP0669896A4 (ko)
JP (1) JPH08503165A (ko)
KR (1) KR950704187A (ko)
AU (1) AU665889B2 (ko)
BR (1) BR9307511A (ko)
CA (1) CA2149443A1 (ko)
MX (1) MX9307263A (ko)
PH (1) PH30601A (ko)
WO (1) WO1994012429A1 (ko)

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US5328673A (en) 1994-07-12
EP0669896A4 (en) 1997-03-12
PH30601A (en) 1997-07-31
AU665889B2 (en) 1996-01-18
AU5605594A (en) 1994-06-22
EP0669896A1 (en) 1995-09-06
WO1994012429A1 (en) 1994-06-09
JPH08503165A (ja) 1996-04-09
CA2149443A1 (en) 1994-06-09
BR9307511A (pt) 1999-06-01
MX9307263A (es) 1994-07-29

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