KR950704113A - 상용화제를 갖는 1축 연신 라벨 필름(uniaxially oriented label film with compatibilizer) - Google Patents

상용화제를 갖는 1축 연신 라벨 필름(uniaxially oriented label film with compatibilizer)

Info

Publication number
KR950704113A
KR950704113A KR1019950701022A KR19950701022A KR950704113A KR 950704113 A KR950704113 A KR 950704113A KR 1019950701022 A KR1019950701022 A KR 1019950701022A KR 19950701022 A KR19950701022 A KR 19950701022A KR 950704113 A KR950704113 A KR 950704113A
Authority
KR
South Korea
Prior art keywords
film
label
core layer
polymeric
mixture
Prior art date
Application number
KR1019950701022A
Other languages
English (en)
Inventor
칼 죠세피
미첼 제이. 라코반
도날드 에프. 킴스
Original Assignee
킴 에이. 칼드웰
아베리 데니슨 코오포레이숀
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 킴 에이. 칼드웰, 아베리 데니슨 코오포레이숀 filed Critical 킴 에이. 칼드웰
Publication of KR950704113A publication Critical patent/KR950704113A/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/023—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets using multilayered plates or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C09J123/14—Copolymers of propene
    • C09J123/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241—Polyolefin, e.g.rubber
    • C09J7/243—Ethylene or propylene polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/516—Oriented mono-axially
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2519/00—Labels, badges
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • C09J2301/162—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer the carrier being a laminate constituted by plastic layers only
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0264—Shapes or borders
    • G09F2003/0267—Shapes or borders die cut
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/91—Product with molecular orientation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31913—Monoolefin polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

본 발명은 라벨의 제조에 유용하며, 또한 올레핀계 염기성 물질과 연질의 극성 첨가제(예 : 에틸렌 비닐 아세테이트(EVA)의 혼합물로 부터 형성되는 압출된 1축 연신 필름에 관한 것으로서, 이들의 물리적 특성은 내마모성을 향상시키는 방향 선택적 방식으로 변화하는 반면, 상기 혼합물에 상용화제 또는 커플링제를 사용하는 경우 정합성을 보전할 수 있으며, 양호한 라벨의 정합성에 요구되는 강성도 및 인장 모듈러스를 비롯한 기계 방향 강도 특성들은 횡 방향 신율을 극히 일부 또는 전혀 저하시키지 않으면서, 그리고 횡 방향 인장 모듈러스를 제한적으로 감소시키면서 증가한다.

Description

상용화제를 갖는 1축 연신 라벨 필름(UNIAXIALLV ORIENTED LABEL FILM WITH COMPATIBILIZER)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1A 내지 1D도는 본 발명의 환경과 관련한 특정 제조 단계를 도식적으로 나타낸 것이다,
제2도 및 제3도는 본 발명의 수행시 사용되는 면 재료 구조체의 부분 단면도이다,
제4A내지 4C도는 본 발명에 적합한 캐스트 필름 압출 및 연속 라인 공정을 도식적으로 나타낸 것이다.

Claims (26)

  1. 올레핀-SPA 혼합물과 상용화제를 함유하되, 약 30 내지 60%의 SPA를 포함하는 하나 이상의 스킨층과, 약 5내지 50%의 SPA를 함유하는 비교적 두꺼운 코어층을 포함하는 2내지 9의 연신비로 1축 연신된 압출-캐스트 다층 필름과, 라벨을 기재에 접착시키기 위해 상기 필름에 결합된 접착재층으로된 다이-절단 중합체성 라벨.
  2. 제1항에 있어서, 상기 코어층이 상용화제를 추가로 함유하는 중합체성 라벨.
  3. 제1항에 있어서, 상기 올레핀-SPA 혼합물층의 연질의 극성 첨가제가 EVA인 중합체성 라벨.
  4. 제3항에 있어서, 상기 혼합물중의 올레핀이 프로필렌 동족 중합체 또는 폴리프로필렌-폴리에틸렌 공중합체 또는 10% 이하의 에틸렌 함량을 갖는 중합체 혼합물을 포함하는 군에서 선택되는 중합체성 라벨.
  5. 제4항에 있어서, 상기 혼합물중의 상기 올레핀의 에틸렌 함량이 5% 이하인 중합체성 라벨.
  6. 제3항에 있어서, 상기 코어층이 약 5내지 15%의 EVA를 함유하고, 상기 스킨층과 코어층의 전체 두께가 약 3mil이인 중합체성 라벨.
  7. 제4항에 있어서, 상기 코어층이 약 5내지 15%의 EVA를 함유하고, 상기 스킨층과 코어층의 전체 두께가 약 3mil 이하인 중합체성 라벨.
  8. 제5항에 있어서, 상기 코어층이 약 5내지 15%의 EVA를 함유하고, 상기 스킨층과 코어층의 전체 두께가 약 3mil 이하인 중합체성 라벨.
  9. 제4항에 있어서, 상기 라벨 필름이 4내지 6의 연신비로 1축 연신되는 중합체성 라벨.
  10. 제8항에 있어서, 상기 라벨 필름이 4내지 6의 연신비로 1축 연신되는 중합체성 라벨.
  11. 제2항에 있어서, 상기 올레핀-SPA 혼합물중의 연질의 극성 첨가제가 EVA인 중합체성 라벨.
  12. 제11항에 있어서, 상기 혼합물중의 올레핀이 프로필렌 동족 중합체 또는 폴리프로필렌-폴리에틸렌 공중합체 또는 10% 이하의 에틸렌 함량을 갖는 중합체 혼합물을 포함하는 군에서 선택되는 중합체성 라벨.
  13. 제12항에 있어서, 상기 혼합물중의 상기 올레핀이 에틸렌 함량이 5% 이하인 중합체성 라벨.
  14. 제11항에 있어서, 상기 코어층이 약5내지 15%의 EVA를 함유하고, 상기 스킨층과 코어층의 전체 두께가 약 3mil 이하인 중합체성 라벨.
  15. 제12항에 있어서, 상기 코어층이 약5내지 15%의 EVA를 함유하고, 상기 스킨층과 코어층의 전체 두께가 약 3mil 이하인 중합체성 라벨.
  16. 제13항에 있어서, 상기 코어층이 약5내지 15%의 EVA를 함유하고, 상기 스킨층과 코어층의 전체 두께가 약 3mil 이하인 중합체성 라벨.
  17. 제12항에 있어서, 상기 라벨 필름이 4내지 6의 연신비로 1축 연신되는 중합체성 라벨.
  18. 제16항에 있어서, 상기 라벨 필름이 4내지 6의 연신비로 1축 연신되는 중합체성 라벨.
  19. 이산화티타늄 무광택제와 같은 층전제의 존재 또는 부재하에서 올레핀-SPA혼합물을 가열 및 용융시키는 단게; 상기 용융 혼합물을 압출-캐스팅시켜 층을 갖는 필름을 형성시키는 단계; 및 상기 필름을 고온-연신 및 열처리하여 1축 연신 라벨 필름을 형성시키고, 상기 1축 연신 필름의 기계 방향의 강성도가 최대가 되도록 기계 방향과 횡방향간의 강성도를 다르게 하는 강화 단계를 포함하여, 상기 올레핀-SPA 혼합물로 부터 형성되는 층들을 갖는 연신-필름 다이-절단 라벨을 제조하는 방법에 있어서, 방향 선택성적인 상기 강화 단계에서는 CD신율에 거의 영향을 미치지 않거나 또는 필름의 정합성을 떨어뜨리지 않도록 상기 필름을 강화시키는 것을 포함하며, 상기 강화 단계는, 상기 혼합물중의 상용화제와 함께 상기 압출-캐스팅, 고온-연신 및 열처리 단계를 수행하므로써 그 결과 생성된 필름이 (1) 정합성을 유지하도록 하며, (2)상기와 동일한 조건하에서 상대적 비율이 상기와 동일하되, 상기 상용화제는 갖지 않는 상기와 동일한 올레핀-SPA 혼합물중의 상기와 동일한 원료로 부터 형성되는 상기와 동일한 두께를 갖는 비교용 필름 보다 더욱 우수한 내마모성을 갖도록 하는 단계, 및 상기 필름을 절단하여 개개의 라벨을 형성시키는 단계를 포함하는 것을 특징으로하는 연신-필름 다이-절단 라벨의 제조방법.
  20. 제19항에 있어서, 상기 압출 단계가 약 35내지 60%의 극성 첨가제를 함유하는 상기 스친층을 압출시키기 위한 원료를 선택하는 단계를 포함하여, 상기 형성된 라벨의 면에 해당하는 코어층과 하나 이상의 스킨층을 압출시키는 것을 포함하는 방법.
  21. 제20항에 있어서, 상기 압출 단계가 약 5내지 20%의 극성 첨가제를 함유하는 상기 코어층을 압출시키기 위한 압출 원료를 선택하는 단계를 포함하여, 필름층을 상기 고온-연신이 압출된 라벨 필틈의 전체 두께를 3mil이하로 감소시킬 정도의 두께로 압출시키는 것을 포함하는 방법.
  22. 극성 첨가제와 필름-형성 올레핀계 염기성 물질의 혼합물을 포함하는 하나 이상의 원료를 제공하는 단계; 상기 하나 이상의 원료를 가열 및 압출시키는 단계; 상기 압출물을 고온-연신 및 열처리하여 그 표면에 상기 올레핀계 염기성 물질을 갖는 연신된 라벨 필름을 형성시키는 단계; 상기 필름면상에 잉크층을 인쇄하여 이것을 장식하는 단계; 및 상기 잉크를 갖는 상기 필름을 절단하여 개개의 라벨을 형성시키는 단게를 포함하여, 인쇄 장식된 다이-절단 라벨을 제조하는 방법에 있어서, 상기 하나 이상의 원료내에 함께 가열 및 압출시키기 위한 커플링제출 포함시키므로써 상기 극성 첨가제와 올레핀제 염기성 물질을 화학적으로 결합시키고, 내부에 상기 커플링제를 갖는 상기 필름을 고온-연신시킴으로써, 상기 절단 단계후에 잉크의 모서리 박리현상을 감소시키는 것을 특징으로 하는 인쇄 장식된 다이-절단 라벨의 제조 방법.
  23. 하나 이상의 스킨층과 비교적 두꺼운 코어층을 포함하는, 2내지 9외 연신비로 1축 연신된 압출-캐스트 다층 필름으로 된 다이-절단 중합체성 라벨로서, 두께가 3mil 이하이고, 상기 필름의 기계 방향 인장 모듈러스가 190,000 psi 이상이며, 횡 방향 모듈러스가 약 100,000 또는 그 이하인 중합체성 라벨.
  24. 제23항에 있어서, 상기 필름의 횡 방향 신율이 약 490% 인상인 중합체성 라벨.
  25. 제1항에 있어서, 상기 필름의 기계 방향 인장 모듈러스가 약 190,000 psi 이상인 중합체성 라벨.
  26. 제15항에 있어서, 상기 필름의 횡 방향 신율이 약 100,000psi 이하인 중합체성 라벨.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019950701022A 1993-07-16 1994-07-05 상용화제를 갖는 1축 연신 라벨 필름(uniaxially oriented label film with compatibilizer) KR950704113A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/093,099 US5451283A (en) 1993-07-16 1993-07-16 Method of making a uniaxially oriented label film with compatibilizer
US08/093,099 1993-07-16
PCT/US1994/007491 WO1995002506A1 (en) 1993-07-16 1994-07-05 Uniaxially oriented label film with compatibilizer

Publications (1)

Publication Number Publication Date
KR950704113A true KR950704113A (ko) 1995-11-17

Family

ID=22237079

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950701022A KR950704113A (ko) 1993-07-16 1994-07-05 상용화제를 갖는 1축 연신 라벨 필름(uniaxially oriented label film with compatibilizer)

Country Status (10)

Country Link
US (2) US5451283A (ko)
EP (1) EP0660772A4 (ko)
JP (1) JPH08504700A (ko)
KR (1) KR950704113A (ko)
CN (1) CN1112782A (ko)
AU (1) AU689122B2 (ko)
BR (1) BR9405546A (ko)
CA (1) CA2144650A1 (ko)
TW (1) TW284721B (ko)
WO (1) WO1995002506A1 (ko)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5585193A (en) * 1993-07-16 1996-12-17 Avery Dennison Corporation Machine-direction oriented label films and die-cut labels prepared therefrom
US5451283A (en) * 1993-07-16 1995-09-19 Avery Dennison Corporation Method of making a uniaxially oriented label film with compatibilizer
AU5158896A (en) * 1995-03-31 1996-10-16 Ferguson International Holdings Plc Improvements in and relating to lamination of sheet material s
JPH11512765A (ja) * 1995-09-26 1999-11-02 ザ・ダウ・ケミカル・カンパニー 透明な単層ラベルフィルム材料
AU722889B2 (en) * 1996-02-23 2000-08-10 Avery Dennison Corporation Voided uniaxially oriented films
US5728502A (en) * 1996-03-12 1998-03-17 Minnesota Mining And Manufacturing Company Imaging medium, method of imaging said medium, and image-bearing medium
AU3667997A (en) * 1996-07-10 1998-02-02 Tredegar Industries, Inc. Compression roll oriented film for use in in-mold label applications
US6270871B1 (en) 1996-09-27 2001-08-07 Avery Dennison Corporation Overlaminated pressure-sensitive adhesive construction
US6136439A (en) * 1996-10-23 2000-10-24 Coburn; Theodore R. Monolayer polymeric film and method of fabrication
KR100550371B1 (ko) * 1997-06-03 2006-02-09 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 다층 전자 커터 필름, 그 제조방법 및 이로부터 영상 그래픽을 형성하는 방법
US6703447B2 (en) 1997-11-24 2004-03-09 Theodore R. Coburn High bi-directional strength monolayer polymeric film and method of fabrication
AU1537999A (en) * 1997-11-24 1999-06-15 Theodore R. Coburn High bi-directional strength monolayer polymeric film and method of fabrication
WO1999064239A1 (en) * 1998-06-12 1999-12-16 Avery Dennison Corporation Multilayered thermoplastic film and sign cutting method using the same
US6090034A (en) * 1998-07-02 2000-07-18 Martin Yale Industries, Incorporated Tabber apparatus with removable shaft and retaining member
US7182986B1 (en) * 1998-07-09 2007-02-27 Kuraray Co., Ltd. Container cap
US6210524B1 (en) * 1999-09-03 2001-04-03 Avery Dennison Corporation Method of improving peel-plate dispensability of label constructions
US6376058B1 (en) 1999-12-21 2002-04-23 Avery Dennison Corporation Polypropylene based compositions and films and labels formed therefrom
US20040038795A1 (en) * 2000-03-10 2004-02-26 Jaksch John H. Tabber apparatus and method
US20030039826A1 (en) 2000-03-20 2003-02-27 Sun Edward I. Conformable and die-cuttable biaxially oriented films and labelstocks
US6541098B2 (en) 2000-12-22 2003-04-01 Avery Dennison Corporation Three-dimensional flexible adhesive film structures
US20020109251A1 (en) * 2001-02-09 2002-08-15 Sellepack David M. Polymeric watercraft and manufacture method thereof
US20020109256A1 (en) * 2001-02-09 2002-08-15 Sellepack David M. Polymeric watercraft and manufacture method thereof
US6706342B2 (en) 2001-02-21 2004-03-16 Exxonmobil Oil Corporation Polymeric labels
US6991261B2 (en) 2001-06-22 2006-01-31 Multi-Color Corporation Labels with removable section for in-mold production of in-mold labeled molded containers
WO2003010228A1 (en) * 2001-07-25 2003-02-06 Avery Dennison Corporation Synthetic paper skins and methods of their manufacture
AU2002326492B2 (en) * 2001-07-31 2008-07-17 Avery Dennison Corporation Conformable holographic labels
US6638636B2 (en) 2001-08-28 2003-10-28 Kimberly-Clark Worldwide, Inc. Breathable multilayer films with breakable skin layers
US6998068B2 (en) * 2003-08-15 2006-02-14 3M Innovative Properties Company Acene-thiophene semiconductors
US6977113B2 (en) 2001-10-09 2005-12-20 3M Innovative Properties Company Microfiber articles from multi-layer substrates
GB0209510D0 (en) * 2002-04-26 2002-06-05 Procter & Gamble Containers comprising at least one label made of an elastomeric material adhered to a squeezable resilient wall
KR101186268B1 (ko) 2002-06-26 2012-09-27 애버리 데니슨 코포레이션 폴리프로필렌/올레핀 탄성체 혼합물을 포함하는 배향된 필름
US7312856B2 (en) * 2002-09-12 2007-12-25 Lockheed Martin Corporation Programmable pulse capture device with automatic gain control
WO2004078467A1 (ja) * 2003-03-03 2004-09-16 Iwata Label Co., Ltd. タックラベル、タックラベルの製造方法及び製造装置
US20060225320A1 (en) * 2003-05-06 2006-10-12 Dregalla Michael E Closure element utilizing uniaxial oriented film
MXPA05011848A (es) * 2003-05-06 2006-05-25 Renaissance Mark Inc Banda mejorada de cuello que utiliza pelicula de desgarre recto.
JP4090389B2 (ja) * 2003-06-10 2008-05-28 株式会社日立製作所 核磁気共鳴装置
US7399509B2 (en) 2003-12-23 2008-07-15 Kari Virtanen Thin polyethylene pressure sensitive labels
US8158227B2 (en) * 2005-04-08 2012-04-17 Applied Extrusion Technologies, Inc. Solvent resistant labels and containers including said labels
US20060247382A1 (en) * 2005-05-02 2006-11-02 Lilac W D Monolayer film for label feedstock
EP1803772B1 (en) * 2005-12-30 2008-09-10 Borealis Technology Oy Polypropylene film with improved balance of mechanical properties
DE102006002596A1 (de) * 2006-01-18 2007-07-19 Tesa Ag Verbundfolie
US7638204B2 (en) * 2006-02-28 2009-12-29 Illinois Tool Works Inc. Tier sheet
EP2049333B1 (en) * 2006-06-14 2012-12-05 Avery Dennison Corporation Conformable and die-cuttable machine direction oriented labelstocks and labels, and process for preparing
US9636895B2 (en) 2006-06-20 2017-05-02 Avery Dennison Corporation Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof
AU2007275336B2 (en) 2006-07-17 2012-03-22 Avery Dennison Corporation Asymmetric multilayered polymeric film and label stock and label thereof
US20090036566A1 (en) * 2007-07-30 2009-02-05 City University Of Hong Kong Biodegradable composite, product made therefrom, and method of manufacture thereof
DE102008005561A1 (de) * 2008-01-22 2009-07-23 Tesa Ag Polyolefinfolie und Verwendung derselben
US9752022B2 (en) 2008-07-10 2017-09-05 Avery Dennison Corporation Composition, film and related methods
JP2012511066A (ja) * 2008-12-05 2012-05-17 テーザ・ソシエタス・ヨーロピア 金属部品をプラスチック、ガラス、および金属に貼り付けるための延伸熱可塑性物質ならびにその製造方法
BR112012022175A2 (pt) 2010-03-04 2016-10-25 Avery Dennison Corp película não de pvc e laminado não de pvc
CA2851488A1 (en) 2011-10-11 2013-04-18 Jindal Films Americas Llc Squeezable and conformable oriented polypropylene label
MX346688B (es) 2012-02-20 2017-03-29 Avery Dennison Corp Película multicapa para sistemas multifuncionales de inyección de tinta.
US9676532B2 (en) 2012-08-15 2017-06-13 Avery Dennison Corporation Packaging reclosure label for high alcohol content products
MX2016007964A (es) 2013-12-30 2016-09-09 Avery Dennison Corp Pelicula protectora de poliuretano.
WO2015187646A1 (en) * 2014-06-02 2015-12-10 Avery Dennison Corporation Films with enhanced scuff resistance, clarity, and conformability
JP2018505266A (ja) 2014-12-30 2018-02-22 アベリー・デニソン・コーポレイションＡｖｅｒｙ Ｄｅｎｎｉｓｏｎ Ｃｏｒｐｏｒａｔｉｏｎ フィルムおよびフィルムレーザー変換装置
CN105984745A (zh) * 2015-02-09 2016-10-05 住化电子材料科技（无锡）有限公司 膜层叠体的制造装置及膜层叠体的制造方法
JP6858489B2 (ja) * 2016-03-18 2021-04-14 株式会社フジシール インモールドラベル連続体、及びその製造方法
US10926019B2 (en) 2019-06-05 2021-02-23 Choon Kee Lee Gradient dialysate hemodiafiltration

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4410482A (en) * 1979-03-06 1983-10-18 E. I. Du Pont De Nemours & Co. Process for making laminar articles of polyolefin and a condensation polymer
US4386188A (en) * 1981-01-16 1983-05-31 Sweetheart Plastics, Inc. Thermoformable polymer blend composition
US4615941A (en) * 1984-12-27 1986-10-07 Mobil Oil Corporation Opaque pearlescent films containing dispersed incompatible polymer and polymeric interfacial agent
US4770837A (en) * 1985-01-24 1988-09-13 Mobil Oil Corporation Method for making articles from polymer blends
US4888075A (en) * 1985-02-05 1989-12-19 Avery International Corporation Composite facestocks and liners
US4911477A (en) * 1988-05-11 1990-03-27 Shigenari Shishido Releasable self-adhesive laminate
US5151309A (en) * 1989-07-05 1992-09-29 The Dow Chemical Company Die-cuttable and dispensable deformable labels
US5354597A (en) * 1990-03-30 1994-10-11 Minnesota Mining And Manufacturing Company Elastomeric tapes with microtextured skin layers
US5186782A (en) * 1990-10-17 1993-02-16 Avery Dennison Corporation Method for high speed labelling of deformable substrates
JP3142602B2 (ja) * 1991-07-03 2001-03-07 株式会社ユポ・コーポレーション ラベルの付着した中空容器の製造方法
TW200424B (ko) * 1991-09-09 1993-02-21 Avery Dennison Corp
US5242650A (en) * 1991-09-09 1993-09-07 Avery Dennison Corporation In-mold labelling a coextruded, stretched and annealed label
US5238733A (en) * 1991-09-30 1993-08-24 Minnesota Mining And Manufacturing Company Stretchable nonwoven webs based on multi-layer blown microfibers
US5516393A (en) * 1993-04-29 1996-05-14 Avery Dennison Corporation Labelling of substrates
US5451283A (en) * 1993-07-16 1995-09-19 Avery Dennison Corporation Method of making a uniaxially oriented label film with compatibilizer

Also Published As

Publication number Publication date
EP0660772A4 (en) 1995-09-06
CA2144650A1 (en) 1995-01-26
CN1112782A (zh) 1995-11-29
US5849419A (en) 1998-12-15
TW284721B (ko) 1996-09-01
EP0660772A1 (en) 1995-07-05
JPH08504700A (ja) 1996-05-21
AU7254594A (en) 1995-02-13
AU689122B2 (en) 1998-03-26
WO1995002506A1 (en) 1995-01-26
US5451283A (en) 1995-09-19
BR9405546A (pt) 1999-09-08

Similar Documents

Publication Publication Date Title
KR950704113A (ko) 상용화제를 갖는 1축 연신 라벨 필름(uniaxially oriented label film with compatibilizer)
EP0470760B1 (en) Composite plastics film or sheet
US5324467A (en) Process for preparation of oriented multilayer laminate film
JP3342127B2 (ja) 水分バリヤーフイルム
US5667902A (en) High moisture barrier polypropylene-based film
KR960014027B1 (ko) 습기배리어 필름(moisture barrier film)
KR100786005B1 (ko) 다층 지방족 폴리에스터 필름
AU758780B2 (en) Halogen-free, printable, multilayered shrink films and articles encapsulated therein
US5234733A (en) Heat-sealable shrink film based on polypropylene
MXPA02005888A (es) Composiciones a base de polipropileno y peliculas y etiquetas formadas a partir de ellas.
JPH01156058A (ja) 一軸延伸収縮フイルム
US6703141B1 (en) Matte surface film
JP3561919B2 (ja) 引き裂き性とひねり性の良好なポリエステルフィルムの製造方法
AU712306B2 (en) Opaque films comprising isotactic polypropylene
KR910016485A (ko) 투명성이 높고 광택성이 있는 연신필름
US5332615A (en) Stretched polyethylene multilayer film
JPH09272182A (ja) 熱収縮性多層フィルム
JP4150957B2 (ja) ポリエステル系フィルム及びその製造方法
JPS62268621A (ja) 積層未延伸原反フイルムの製造方法
JP2004524180A (ja) 改良された貼り合せ品質の、同時押出されたヒートシール可能なフィルム
JP2605114B2 (ja) 延伸ポリプロピレン系フィルムの積層物およびその用途
JPH10101128A (ja) 結束紐
JPH02191B2 (ko)
JP4288787B2 (ja) 横方向引裂性積層ポリオレフィンフィルムを層構成に含む積層体
JP2002337289A (ja) 積層ポリエステルフィルム及びそれを用いた包装袋

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid