KR950703038A - PEROXY BLEACHING COMPOSITION STABILIZED WITH ETHYLENEDIAMINE-N, N'-DISUCCINIC ACID Stabilized with Ethylenediamine-N, N'-Disuccinic Acid - Google Patents

PEROXY BLEACHING COMPOSITION STABILIZED WITH ETHYLENEDIAMINE-N, N'-DISUCCINIC ACID Stabilized with Ethylenediamine-N, N'-Disuccinic Acid Download PDF

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KR950703038A
KR950703038A KR1019950700419A KR19950700419A KR950703038A KR 950703038 A KR950703038 A KR 950703038A KR 1019950700419 A KR1019950700419 A KR 1019950700419A KR 19950700419 A KR19950700419 A KR 19950700419A KR 950703038 A KR950703038 A KR 950703038A
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composition
bleaching
detergent composition
ethylenediamine
weight
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KR1019950700419A
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마르셀 바이유리 제라르
시알라 스테파노
알렉산더 소리 그래함
셈 에르솔마츠 세미
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자코버스 코넬리스 라써
더 프록터 앤드 갬블 캄파니(The Procter & Gamble Company)
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Publication of KR950703038A publication Critical patent/KR950703038A/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 퍼옥시 화합물 및 에틸렌디아민-N.N′-디석신산 또는 이의 염을 포함하는 표백 조성물에 관한 것이다. 표백 조성물은 수용액에서 우수한 표백 안정성을 나타내고 적어도 일부가 60℃ 이상의 온도에서 수행되는 표백 공정에 특히 유용하다. 조성물은 또한 우수한 저장 안정성을 갖는다. 표백 조성물은 셀룰로스 섬유 물질 및 합성 직물의 표백시 사용할 수 있고 세제 조성물의 성분으로서도 유용하다.The present invention relates to a bleaching composition comprising a peroxy compound and ethylenediamine-N.N'-disuccinic acid or salts thereof. Bleaching compositions are particularly useful in the bleaching process, which exhibits good bleaching stability in aqueous solutions and at least a part is carried out at temperatures of at least 60 ° C. The composition also has good storage stability. Bleaching compositions can be used in the bleaching of cellulose fiber materials and synthetic fabrics and are also useful as a component of detergent compositions.

Description

에틸렌디아민-N,N′-디석신산으로 안정화시킨 퍼옥시 표백 조성물(PEROXY BLEACHING COMPOSITION STABILIZED WITH ETHYLENEDIAMINE-N,N′-DISUCCINIC ACID)PEROXY BLEACHING COMPOSITION STABILIZED WITH ETHYLENEDIAMINE-N, N'-DISUCCINIC ACID Stabilized with Ethylenediamine-N, N'-Disuccinic Acid

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (27)

과산화수소, 및 과산화수소, 유기 퍼옥시산 및 이들의 혼합물의 부가 화합물로부터 선택된 퍼옥시 화합물(a) 및 에틸렌디아민-N,N′-디석신산 또는 알칼리 금속, 알칼리토 금속, 암모늄 또는 이의 치환된 암모늄염 또는 이들의 혼합물의 조성물(b) 0.05 내지 2중량%(여기서, (a) : (b)의 중량비는 800 : 1 내지 10 : 1 이다)를 포함하는 표백 조성물.Peroxy compound (a) and ethylenediamine-N, N'-disuccinic acid or alkali metal, alkaline earth metal, ammonium or substituted ammonium salts thereof selected from hydrogen peroxide and addition compounds of hydrogen peroxide, organic peroxy acids and mixtures thereof A bleaching composition comprising 0.05 to 2% by weight of a composition (b) of the mixture thereof, wherein the weight ratio of (a) to (b) is 800: 1 to 10: 1. 제1항에 있어서, 에틸렌디아민-N,N′-디석신산이 [S,S] 이성체 형태인 표백 조성물.The bleaching composition of claim 1, wherein the ethylenediamine-N, N'-disuccinic acid is in the [S, S] isomeric form. 제1항 또는 제2항에 있어서, 에틸렌디아민-N,N′-디석신산 성분이 조성물의 0.05 내지 1중량% 수준으로 존재하고 중량비가 400 : 1 내지 20 : 1인 표백 조성물.The bleaching composition according to claim 1 or 2, wherein the ethylenediamine-N, N'-disuccinic acid component is present at a level of 0.05 to 1% by weight of the composition and has a weight ratio of 400: 1 to 20: 1. 제1항 내지 제3항 중의 어느 한 항에 있어서, 에틸렌디아민-N.N′-디석신산 성분이 조성물의 0. 1 내지 0.5중량% 수준으로 존재하고 중량비가 200 : 1 내지 40 : 1인 표백 조성물.The bleaching composition according to any one of claims 1 to 3, wherein the ethylenediamine-N.N'-disuccinic acid component is present at 0.1 to 0.5% by weight of the composition and has a weight ratio of 200: 1 to 40: 1. 제1항 내지 제4항 중이 어느 한 항에 있어서, 퍼옥시산 표백 전구체가 혼입된 표백 조성물.The bleaching composition according to any one of claims 1 to 4, wherein a peroxy acid bleaching precursor is incorporated. 제1항 내지 제5항 중의 어느 한 항에 있어서, 퍼옥시 화합물이 과산화수소이며 셀룰로스 섬유 및 합성 텍스타일의 표백에 유용한 표백 조성물.The bleaching composition according to any one of claims 1 to 5, wherein the peroxy compound is hydrogen peroxide and useful for bleaching cellulose fibers and synthetic textiles. 제6항에 있어서, 규산 나트륨을 함유하지 않는 표백 조성물.The bleaching composition of claim 6 which does not contain sodium silicate. 퍼옥시 화합물이 무기 과수화물 염이며 세제 조성물의 3 내지 40중량%수준으로 존재하고, 세제 조성물의 1 내지 80중량%의 비인산염 세제 빌더 화합물 및 이들의 혼합물을 추가로 포함하는 제1항 내지 제5항 중의 어느 한 항에 따르는 표백 조성물을 포함하는 세제 조성물.The peroxy compound is an inorganic perhydrate salt and is present at a level of 3 to 40% by weight of the detergent composition, further comprising 1 to 80% by weight of the non-phosphate detergent builder compound of the detergent composition and mixtures thereof. A detergent composition comprising the bleaching composition according to claim 5. 제8항에 있어서, 에틸렌디아민 -N,N′-디석신산 성분이 마그네슘 염의 형태인 세제 조성물.9. The detergent composition of claim 8, wherein the ethylenediamine-N, N'-disuccinic acid component is in the form of a magnesium salt. 제8항 또는 제9항에 있어서, 음이온성 계면활성제, 양이온성 계면활성제, 비이온성 계면활성제, 양쪽성 계면활성제, 쯔비터이온성 계면활성제 및 이들의 혼합물로부터 선택된 저 발포 계면활성제 0.5 내지 10중량%가 혼입된 접시닦이 기계용 세제 조성물.The low foaming surfactant according to claim 8 or 9, wherein the low foaming surfactant is selected from anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, zwitterionic surfactants and mixtures thereof. Detergent composition for dishwasher machine. 제10항에 있어서, 전분분해효소, 단백질분해효소, 지질분해효소 및 이들의 혼합물로부터 선택된 효소가 혼입된 접시닦이 기계용 세제 조성물.The detergent composition according to claim 10, wherein an enzyme selected from starch, protease, lipolytic enzyme and mixtures thereof is incorporated. 제8항 또는 제9항에 있어서, 음이온성 계면활성제, 양이온성 계면활성제, 비이온성 계면활성제, 양쪽성 계면활성제, 쯔비터이온성 계면활성제 및 이들의 혼합물로 부터 선택된 계면활성제 3 내지 30중량%를 포함하는 세탁용 세제 조성물.10 to 30% by weight of the surfactant according to claim 8 or 9 selected from anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, zwitterionic surfactants and mixtures thereof. Laundry detergent composition comprising. 제12항에 있어서, 비인산염 세제 빌더 화합물이 결정성 적층 규산 나트륨, 알루미노규산나트륨 제올라이트, 알칼리 금속 탄산염 및 탄산수소염, 카복실산염 및 폴리카복실산염. 및 말레산 무수물/아크릴산 공중합체로부터 선택된 세탁용 세제 조성물.The non-phosphate detergent builder compound of claim 12, wherein the non-phosphate detergent builder compound is a crystalline laminated sodium silicate, sodium aluminosilicate zeolite, alkali metal carbonate and hydrogen carbonate, carboxylate and polycarboxylic acid salt. And a laundry detergent composition selected from maleic anhydride / acrylic acid copolymer. 제13항에 있어서, 결정성 적층 규산 나트륨 세제 빌더 화합물이 일반식 NaMSixO2x+1.yH2O의 물질(여기서, M은 나트륨 또는 수소이고, x는 1.9 내지 4의 수이고, y는 0 내지 20의 수이다)인 세탁용 세제 조성물.The method of claim 13, wherein the crystalline laminated sodium silicate detergent builder compound is a substance of the general formula NaMSixO 2 x + 1.yH 2 O, wherein M is sodium or hydrogen, x is a number from 1.9 to 4, y is 0 Laundry detergent composition). 제12항 내지 제14항 중의 어느 한 항에 있어서, 결정성 적층 규선염 물질이 σ-Na2Si2O5(Na SKS-6)인 세탁용 세제 조성물.The laundry detergent composition according to any one of claims 12 to 14, wherein the crystalline laminated silicate material is σ-Na 2 Si 2 O 5 (Na SKS-6). 제12항 내지 제15항 중의 어느 한 항에 있어서, 음이온성 계면활성제가 C12내지 C20알킬 설페이트 염과 몰당 평균 1 내지 7개의 에톡시 그룹을 함유하는 수용성 C11내지 C19알킬 에톡시설페이트 염과의 혼합물(여기서, 알킬 설페이트 : 알킬 에톡시설페이트 염의 중량비는 2 : 1 내지 19 : 1이다)을 포함하는 세탁용 세제 조성물.The water-soluble C 11 to C 19 alkyl ethoxysulfate according to any of claims 12 to 15, wherein the anionic surfactant contains an average of 1 to 7 ethoxy groups per mole with a C 12 to C 20 alkyl sulfate salt. A laundry detergent composition comprising a mixture with a salt, wherein the weight ratio of alkyl sulfate to alkyl ethoxysulfate salt is from 2: 1 to 19: 1. 제16항에 있어서, 알킬 설페이트 염이 C14내지 C15알킬 설페이트 염이고, 알킬 에톡시설페이트 염이 몰당 평균 3개의 에톡시 그룹을 함유하는 C12내지 C15알킬 에톡시설페이트 염이며 이들의 중량비가 3.5 : 1 내지 10 : 1인 세탁용 세제 조성물.The method of claim 16 wherein the alkyl sulfate salt is a C 14 to C 15 alkyl sulfate salts, and alkyl ethoxy sulfate salt is a mole average of three to an ethoxy sulfate salt to C 12 to C 15 alkyl containing a methoxy group, their weight ratio A detergent composition for laundry having a value of 3.5: 1 to 10: 1. 제12항 내지 제17항 중의 어느 한 항에 있어서, 비이온성 계면활성제가 다음 일반식의 폴리하이드록시 지방산 아이드 또는 알콕실화된 이의 유도체인 세탁용 세제 조성물.18. The laundry detergent composition of claim 12, wherein the nonionic surfactant is a polyhydroxy fatty acid eye or alkoxylated derivative of the following general formula. 상기식에서, R1은 H C1내지 C4하이드록시카빌, 2-하이드록시에틸, 2-하이드록시프로필 또는 이들의 혼합물이고, R2는 C5내지 C31하이드로카빌이며, E는 쇄에 직접 연결된 하이드록시 그룹 3개 이상을 갖는 직쇄 탄화수소 쇄를 갖는 폴리하이드록시하이드로카빌이다.Wherein R 1 is HC 1 to C 4 hydroxycarbyl, 2-hydroxyethyl, 2-hydroxypropyl or a mixture thereof, R 2 is C 5 to C 31 hydrocarbyl, and E is directly linked to the chain Polyhydroxyhydrocarbyl having a straight chain hydrocarbon chain having 3 or more hydroxy groups. 제12항 내지 제18항 중의 어느 한 항에 있어서, 비이온성 계면활성제가 알콜 1몰당 에틸렌 옥사이드 평균 3 내지 8몰을 함유하는 C9내지 C151급 알콜 에톡실레이트인 세탁용 세제 조성물.19. The laundry detergent composition of claim 12, wherein the nonionic surfactant is a C 9 to C 15 primary alcohol ethoxylate containing an average of 3 to 8 moles of ethylene oxide per mole of alcohol. 제19항에 있어서, 1급 알콜 에톡실레이트가 알콜 1몰당 에틸렌 옥사이드 평균 3 내지 5몰을 함유하는 C12내지 C151급 알콜인 세탁용 세제 조성물.20. The laundry detergent composition of claim 19, wherein the primary alcohol ethoxylate is a C 12 to C 15 primary alcohol containing an average of 3 to 5 moles of ethylene oxide per mole of alcohol. 제12항 내지 제20항 중의 어느 한 항에 있어서, 고체 퍼옥시산 표백제 전구체가 1 내지 20중량% 혼입되어 있는 세탁용 세제 조성물.The laundry detergent composition according to any one of claims 12 to 20, wherein 1-20 wt% of the solid peroxy acid bleach precursor is incorporated. 제21항에 있어서, 무기 과수화물 염이 조성물의 5 내지 30중량%의 수준으로 존재하는 과탄산 나트륨이고 고체 퍼옥시산 표백제 전구체가 조성물의 1 내지 10중량% 수준으로 존재하는 TAED인 세탁용 세제 조성물.22. The laundry detergent of claim 21 wherein the inorganic perhydrate salt is sodium percarbonate present at a level of 5-30% by weight of the composition and the TAED presenting a solid peroxy acid bleach precursor at a level of 1-10% by weight of the composition. Composition. 제12항 내지 제22항 중의 어느 한 항에 있어서, 세제 효소, 오염 현탁재, 재부착 방지제, 광학 증백제, 서즈 억제제, 향료 및 이들의 혼합물로부터 선택된 추가의 세제 성분을 포함하는 세탁용 세제 조성물.23. A laundry detergent composition according to any one of claims 12 to 22 comprising an additional detergent component selected from detergent enzymes, contaminating suspensions, anti-reposition agents, optical brighteners, suds inhibitors, perfumes and mixtures thereof. . 퍼옥시 화합물이 과산화수소, 유기 퍼옥시산 및 이들의 혼합물로부터 선택되며 pH가 0.5 내지 6인 액체 상태의 제1항 내지 제5항 중의 어느 한 항에 따르는 표백 조성물을 포함하는 조성물.A composition comprising a bleaching composition according to any one of claims 1 to 5 in a liquid state, wherein the peroxy compound is selected from hydrogen peroxide, organic peroxy acid and mixtures thereof. 제24항에 있어서, 퍼옥시 화합물이 액체 조성물에 용해되거나 분산되어 있으며 유낙액 또는 현탁액으로서 혼입되어 있는 조성물.The composition of claim 24, wherein the peroxy compound is dissolved or dispersed in the liquid composition and incorporated as a drop or suspension. 제24항 또는 제25항에 있어서, 액체에 용해되거나 분산되어 있거나 유탁액 또는 현탁액으로서 혼입되어 있는 퍼옥시산 표백제 전구체가 혼입되어 있는 조성물.The composition according to claim 24 or 25, wherein a peroxy acid bleach precursor is incorporated which is dissolved or dispersed in a liquid or incorporated as an emulsion or suspension. 제24항 내지 제26항 중의 어느 한 항에 있어서, 경질 표면 세정제, 세탁용 첨가제, 오염 예비처리 조성물, 또는 카펫 또는 실내장식물 세정제로서 배합된 조성물.27. The composition of any one of claims 24 to 26, formulated as a hard surface cleaner, laundry additive, contamination pretreatment composition, or carpet or upholstery cleaner. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950700419A 1992-08-01 1993-07-21 PEROXY BLEACHING COMPOSITION STABILIZED WITH ETHYLENEDIAMINE-N, N'-DISUCCINIC ACID Stabilized with Ethylenediamine-N, N'-Disuccinic Acid KR950703038A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9216408.6 1992-08-01
GB929216408A GB9216408D0 (en) 1992-08-01 1992-08-01 Stabilized bleaching compositions
PCT/US1993/006837 WO1994003553A1 (en) 1992-08-01 1993-07-21 Peroxy bleaching composition stabilized with ethylenediamine-n,n'-disuccinic acid

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KR950703038A true KR950703038A (en) 1995-08-23

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GB (1) GB9216408D0 (en)
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AU666403B2 (en) 1996-02-08
AU4778593A (en) 1994-03-03
EP0652924A4 (en) 1995-06-14
MA22947A1 (en) 1994-04-01
GB9216408D0 (en) 1992-09-16
WO1994003553A1 (en) 1994-02-17
CN1084560A (en) 1994-03-30
TR28150A (en) 1996-02-29
MX9304665A (en) 1994-03-31
TW255911B (en) 1995-09-01
CA2141611A1 (en) 1994-02-17
EP0652924A1 (en) 1995-05-17
JPH07509523A (en) 1995-10-19

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