KR950032010A - 수성 귀금속 제제 및 귀금속 장식품 제조시의 이의 용도 - Google Patents

수성 귀금속 제제 및 귀금속 장식품 제조시의 이의 용도 Download PDF

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KR950032010A
KR950032010A KR1019950003509A KR19950003509A KR950032010A KR 950032010 A KR950032010 A KR 950032010A KR 1019950003509 A KR1019950003509 A KR 1019950003509A KR 19950003509 A KR19950003509 A KR 19950003509A KR 950032010 A KR950032010 A KR 950032010A
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precious metal
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organic
gold
ornaments
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슐쯔 안드레아스
회플러 마르코
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볼프강 메르크, 폴커 빈더
쎄르덱 아크티엔게젤샤프트 케라미쉐 파르벤
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    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/88—Metals
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    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
    • C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
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    • C—CHEMISTRY; METALLURGY
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    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
    • C04B41/5111—Ag, Au, Pd, Pt or Cu
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
    • C04B41/5177—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal characterised by the non-metallic part of the metallising composition
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/25—Metals
    • C03C2217/251—Al, Cu, Mg or noble metals
    • C03C2217/254—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C03C2218/114—Deposition methods from solutions or suspensions by brushing, pouring or doctorblading
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C03C2218/119—Deposition methods from solutions or suspensions by printing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/40—Surface-active agents, dispersants
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/10—Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
    • C04B2111/1006—Absence of well-defined organic compounds
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    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Geochemistry & Mineralogy (AREA)
  • Paints Or Removers (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Surface Treatment Of Glass (AREA)
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  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

본 발명은 수성 귀금속 제제 및 귀금속 장식품 제소시의 이의 용도에 관한 것이다.
귀금속 제제는 유기 또는 유기/수성 용매 시스템을 갖는, 금,은,백금 및 팔라듐으로 이루어진 그룹으로부터 선택된 하나 이상의 귀금속을 기본으로 하는 귀금속 장식품의 제조시에 공지되어 있다. 유기 용매가 필수적으로 존재하지 않는 제제에 대한 필요성이 있다.
본 발명에 따르는 제제는 수용성 염 형태의 염을 형성할 수 있는 하나 이상의 작용 그룹을 갖는 귀금속 티올레이트, 수용성 중합체인 유기 결합제, 계면활성제 유효량 및 용매로서 물과, 유기 용매2중량% 미만을 포함한다. 바람직한 제제는 일반식 Au-S-Q-COOH의 금 티올레이트[여기서, Q는 작용 그룹을 임의로 포함하는 2가 유기 그룹이다], 결합제로서 폴리비닐 피롤리돈 및/또는 하이드록시에틸셀룰로오즈 및 계면활성제로서 알킬벤젠 설포네이트 또는 폴리에테르-폴리실록산 공중합체를 0.1 내지 2.0중량% 포함한다.
필수적으로 유기 용매가 존재하지 않는 제제를 사용하여 고광택의 결함이 없는 장식품을 제조할 수 있다.

Description

수성 귀금속 제제 및 귀금속 장식품 제조시의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 용매 시스템이 물과, 제제를 기준으로 하여, 유기 용매 2중량%미만을 포함함을 특징으로 하는, 수용성형 형태의 염을 형성할 수 있는 하나 이상의 작용 그룹을 갖는 귀금속 티올레이트, 수용성 중합체인 유기 결합제, 수성 용매 시스템 및 계면활성제 유효량을 함유하는, 금, 은, 백금 및 팔라듐으로 이루어진 그룹으로부터 선택된 하나 이상의 귀금속을 기본으로 하는 귀금속 장식품 제조용 귀금속 제제.
  2. 제1항에 있어서, 하나 이상의 카복실 그룹과 1급, 2급 또는 3급 아민 또는 N-헤테로사이클릭 염기를 갖는 귀금속 티올레이트의 염을 포함하는 귀금속 제제.
  3. 제1항 또는 제2항에 있어서, 바람직하게는 200℃이상의 온도에서 분해되기 시작하는, 일반식Au-S-Q-COOH의 금(I)티올레이트[여기서, Q는 추가의 작용 그룹을 임의로 포함하는 2가 유기 그룹이다]의 수용성 염을 포함하는 귀금속 제제.
  4. 제3항에 있어서, 금(I)-N-머캅토-C2-또는 C3-알카노일아미노산 또는 금(I)-N-아실시스테인 계열의 금(I)티올레이트의 수용성 염을 포함하는 귀금속 제제.
  5. 제1항 내지 제4항 중의 한 항에 있어서, 중합체 유기 결합제가 폴리비닐피롤리돈 단독중합체 또는 폴리비닐 피롤릴돈 공중합체, 폴리아프릴산 단독중합체 또는 폴리아크릴산 공중합체, 폴리메타크릴산 단독중합체 또는 폴리메타크릴산 공중합체, 수용성 셀룰로오즈 에테르 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 귀금속 제제.
  6. 제1항에 있어서, 계면활성제로서 0.1 내지 2.0중량%, 바람직하게는 0.2 내지1.0중량%의 폴리옥시에틸렌 폴리디멜틸실록산을 포함하는 귀금속 제제.
  7. 제1항 내지 제5항 중의 어느 한 항에 있어서, 계면활성제로서 아민과의 염 형태인 알킬 그룹의 탄소수가 8 내지 14인 알킬벤젠 설포네이트를 0.1 내지 2중량%, 바람직하게는 0.2 내지 1중량%의 양으로 포함하는 귀금속 제제.
  8. 제1항 내지 제7항 중의 어느 한항에 있어서, 티올레이트가 트리(C1-C3)알킬아민 또는 모노-,디-또는 트리에탄올아민과 염 형태로 존재하고, 제조되는 장식품의 광학 및 용도 특성 및/또는 제제의 가공 특성을 제공하기 위한 통상적인 보조물질을 추가로 포함하는 귀금속 제제.
  9. 제1항 내지 제8항 중의 어느 한 항에 따르는 귀금속 제제를 사용하여 장식층을 제조함을 특징으로하여, 장식층을 분리 층이 제공된 캐리어에 적용시키고, 용매를 증발시킨 다음, 필요에 따라, 건조된 장식층을 막피복시킴으로써 수득한 전사물.
  10. 제1항 내지 제7항 중의 어느 한 항에 따르는 제제 또는 제8항에 따르는 제제를 함유하는 전사물을 사용함을 특징으로 하여, 귀금속 티올레이트를 함유하는 제제 또는 이러한 제제를 함유하는 전사물을 건조 상태로 지지체에 적용시켜 400 내지900℃에서 스토빙시킴으로써 스토빙가능한 지지체, 특히 유리, 자기 또는 세라믹을 장식하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950003509A 1994-02-24 1995-02-23 수성 귀금속 제제 및 귀금속 장식품을 제조하기 위한 이의 용도 KR100337099B1 (ko)

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DE4405932A DE4405932C1 (de) 1994-02-24 1994-02-24 Wäßrige Edelmetallpräparate und deren Verwendung zur Herstellung von Edelmetalldekoren
DEP4405932.9 1994-02-24

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DE19619168C1 (de) * 1996-05-11 1997-10-02 Heraeus Gmbh W C Keramische Färbelösung (grau) und ihre Verwendung
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DE19831141C2 (de) * 1998-07-11 2003-02-27 Dmc2 Degussa Metals Catalysts Edelmetallpräparat und dessen Verwendung zur Herstellung von Edelmetalldekoren durch Direkt- und Indirektdruck
IT1302030B1 (it) * 1998-08-21 2000-07-20 Graziano Vignali Formulazioni coloranti per ceramica, a base di composti idrosolubilidi oro.
DE19941020B4 (de) * 1999-08-28 2007-07-19 Ferro Gmbh Glanzedelmetallpräparat für den Hochtemperaturbrand und Verfahren zur Herstellung von Glanzedelmetalldekoren
IL181126A0 (en) * 2006-11-01 2007-07-04 S B Biotechnologies Ltd Preparation of gold-containing nano-liposome particles and their use in medical therapy
JP5737726B2 (ja) * 2013-09-26 2015-06-17 小島化学薬品株式会社 有機金化合物の製造方法
EP2980051B1 (de) * 2014-08-01 2019-03-13 Heraeus Deutschland GmbH & Co. KG Erzeugung einer Dekorschicht auf keramischen Oberflächen
DE102015117711A1 (de) 2015-10-16 2017-04-20 Ferro Gmbh Abziehbild zur Erzeugung eines Dekors

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DK201081A (da) * 1981-05-06 1982-11-07 Kongelige Porcelainsfabrik A S Male- og trykmedium samt overglasurfarve og trykfarve paa basis af dette medium
DE3807290A1 (de) * 1988-03-05 1989-09-14 Heraeus Gmbh W C Poliergoldpraeparat
DE4040446A1 (de) * 1990-12-18 1992-06-25 Degussa Gold(i)mercaptocarbonsaeureester, verfahren zu ihrer herstellung und verwendung
US5281635A (en) * 1991-05-17 1994-01-25 Johnson Matthey Public Limited Company Precious metal composition

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DE59404208D1 (de) 1997-11-06
EP0669300A3 (de) 1996-03-13
EP0669300B1 (de) 1997-10-01
EP0669300A2 (de) 1995-08-30
TW397870B (en) 2000-07-11
US5545452A (en) 1996-08-13
JPH07315968A (ja) 1995-12-05
JP3904247B2 (ja) 2007-04-11
ES2108360T3 (es) 1997-12-16
DE4405932C1 (de) 1995-05-04
KR100337099B1 (ko) 2002-11-18

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