KR950018370A - 실란 조성물 - Google Patents

실란 조성물 Download PDF

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KR950018370A
KR950018370A KR1019940030400A KR19940030400A KR950018370A KR 950018370 A KR950018370 A KR 950018370A KR 1019940030400 A KR1019940030400 A KR 1019940030400A KR 19940030400 A KR19940030400 A KR 19940030400A KR 950018370 A KR950018370 A KR 950018370A
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group
carbon atoms
silane
following formula
coupling agent
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KR1019940030400A
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KR100308770B1 (ko
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브이. 비숍 크레이그
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클라우스 로메르
맥긴-로코, 인코포레이티드
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/38Improvement of the adhesion between the insulating substrate and the metal
    • H05K3/389Improvement of the adhesion between the insulating substrate and the metal by the use of a coupling agent, e.g. silane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • B32B2255/205Metallic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/08Reinforcements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202Conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/204Di-electric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2398/00Unspecified macromolecular compounds
    • B32B2398/10Thermosetting resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/08PCBs, i.e. printed circuit boards
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/901Printed circuit
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)
  • Silicon Polymers (AREA)
  • Manufacturing Of Printed Wiring (AREA)

Abstract

본 발명은 (A) 실란 커플링제; (B) 하기식 (I), (II)로 특징되는 트리스(실릴 오르가노)아민 또는 알칸을 포함하는 실란조성물임을 특징으로 한다.
여기에서, 각 R은 독립적으로 탄소원자 20이하의 알킬, 알콕시알킬, 아릴, 아랄킬 또는 사이클로알킬기이고; R'는 탄소원자 20이하의 2가 하이드로카본 또는 폴리에테르기이며; R2는 하기식으로 대표되는 작용기이다.
CnH2nX
여기에서 n은 0-20이고 X는 아미노, 이미도, 하이드록시, 알콕시, 할로, 메르캅토, 카르복시, 아실, 비닐, 알릴, 스티릴, 에폭시, 이소시아네이토, 글리시독시 및 아크릴록시기로 이루어진 그룹으로 선택된다. 본 발명의 실란조성물은 열경화성 수지에 유리, 금속 및 산화금속같은 표면을 접합시키는데 있어서 개선된 특성을 제공하는 접착조성물이다. 또한 개선된 내습성도 나타낸다. 본 발명의 실란조성물은 인쇄 회로기판과 같은 다층박판을 제조하는데 사용되는 접착제로서 특히 유용하다.

Description

실란 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (A) 실란 커플링제; (B) 하기식 (I), (II)로 특징되는 트리스(실릴 오르가노)아민 또는 알칸을 포함하는 실란조성물.
    여기에서, 각 R은 독립적으로 탄소원자 20이하의 알킬, 알콕시알킬, 아릴, 아랄킬 또는 사이클로알킬기이고; R'는 탄소원자 20이하의 2가 하이드로카본 또는 폴리에테르기이며; R2는 하기식으로 대표되는 작용기이다.
    CnH2nX
    여기에서 n은 0-20이고 X는 이미노, 아미도, 하이드록시, 알콕시, 할로, 메르캅토, 카르복시, 아실, 비닐, 알릴, 스티릴, 에폭시, 이소시아네이토, 글리시독시 및 아크릴록시기로 이루어진 그룹으로 선택된다.
  2. 제1항에 있어서, (B)가 식 (I)로 특징되는 트리스(실릴오르가노)아민인 실란 조성물.
  3. 제1항에 있어서, 실란 커플링제(A)가 하기식으로 특징되는 실란조성물.
    여기에서 A는 가수분해 기능기이고, X는 1, 2 또는 3이며, B는 알킬 또는 아릴기 또는 하기식으로 대표되는 작용기이다.
    CnH2nX
    여기에서 n은 0-20이고 X는 아미노, 아미도, 하이드록시, 알콕시, 할로, 메르캅토, 카르복시, 아실, 비닐, 알릴, 스티릴, 에폭시, 이소시아네이토, 글리시독시 및 아크릴록시기로 이루어진 그룹으로 선택된다.
  4. 제1항에 있어서, A:B의 몰비가 1:1-5:1의 범위인 실란조성물.
  5. 실란 커플링제(A); 및 (B) 하기식(I)로 특징되는 트리스(실릴오르가노)아민을 포함하는 실란조성물.
    여기에서 각 R은 독립적으로 탄소원자 1-5의 알킬기이다; R1은 탄소원자 1-5의 2가 하이드로카본기이다.
  6. 제5항에 있어서, 실란커플링제(A)가 하기식으로 대표되는 실란조성물.
    여기에서, 각 R은 독립적으로 탄소원자수 20이하의 알킬, 아릴, 아랄킬 똔느 사이클로알킬기이다.; B는 하기식으로 대표되는 작용기이다.
    CnH2nX
    여기에서 n은 0-20이고 X는 이미노, 아미도, 하이드록시, 알콕시, 할로, 메르캅토, 카르복시, 아실, 비닐, 알릴, 스티릴, 에폭시, 이소시아네이토, 글리시독시 및 아크릴록시기로 이루어진 그룹으로 선택된다.
  7. 제5항에 있어서, 실란커플링제(A)가 하기식으로 대표되는 실란조성물.
    여기에서, 각 R은 1-5의 탄소원자를 함유하는 알킬기이고, R4는1-5의 탄소원자를 함유하는 2가 하이드로카빌기이다.
  8. (A) 하기식으로 특징되는 실란커플링제와,
    여기에서, 각 R은 메틸 또는 에틸기이고, R4는 1-5의 탄소원자를 함유하는 2가 하이드로카빌기이다. (B) 하기식으로 특징되는 트리스(실릴오르가노) 아민을 포함하는 실란조성물.
    여기에서, 각 R은 메틸 또는 에틸기이고, 각 R'은 독립적으로 약 1-4의 탄소원자를 함유하는 2가 하이드로카빌기이다.
  9. (A) 최소한 하나의 전기 전도성 물질층; (B) 최소한 하나의 부도전 물질층; 및 (C) 전도성 물질 및 부도전 물질사이에 위치되거나 거기에 접착된 청구범위 1항의 실란조성물의 접착-촉진층을 포함하는 박판.
  10. (A) 최소한 하나의 표면상에 전도성 금속 코팅 또는 금속회로를 갖는 최소한 하나의 부도전 층; (B) 최소한 하나의 절연층; 및 (C) 전도성 금속코팅 또는 금속회로를 갖는 부도전층과 표면과 절연층 사이의 실란층을 포함하는데 실란층이 하기의 실란조성물로 형성된 다층박판. (A) 실란 커플링제; 및 (B) 하기식 (I),(II)로 특징되는 트리스(실릴 오르가노)아민 또는 알칸.
    여기에서, 각 R은 독립적으로 탄소원자 20이하의 알킬, 알콕시알킬, 아랄, 아릴킬 또는 사이클로알킬기이고; R'는 탄소원자 20이하의 2가 하이드로카본 또는 폴리에테르기이며; R2는 하기식으로 대표되는 작용기이다.
    CnH2nX
    여기에서 n은 0-20이고 X는 이미노, 아미도, 하이드록시, 알콕시, 할로, 메르캅토, 카르복시, 아실, 비닐, 알릴, 스티릴, 에폭시, 이소시아네이토, 글리시독시 및 아크릴록시기로 이루어진 그룹으로 선택된다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940030400A 1993-12-08 1994-11-18 실란조성물 KR100308770B1 (ko)

Applications Claiming Priority (2)

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US16394693A 1993-12-08 1993-12-08
US08/163,946 1993-12-08

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KR950018370A true KR950018370A (ko) 1995-07-22
KR100308770B1 KR100308770B1 (ko) 2002-04-24

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EP (1) EP0657394B1 (ko)
JP (1) JPH07228702A (ko)
KR (1) KR100308770B1 (ko)
CA (1) CA2136137C (ko)
DE (1) DE69404017T2 (ko)
IL (1) IL111497A (ko)
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DE69404017T2 (de) 1998-02-19
IL111497A0 (en) 1995-01-24
IL111497A (en) 2001-01-28
DE69404017D1 (de) 1997-08-07
EP0657394A1 (en) 1995-06-14
US6215011B1 (en) 2001-04-10
CA2136137C (en) 2000-11-14
EP0657394B1 (en) 1997-07-02
CA2136137A1 (en) 1995-06-09
JPH07228702A (ja) 1995-08-29
KR100308770B1 (ko) 2002-04-24
TW293025B (ko) 1996-12-11
US5639555A (en) 1997-06-17

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