KR950012685B1 - Textile softning agent containing bamboo-salt - Google Patents

Abstract

The fabric softening agent composition is composed of 0.05-10wt.pt. of a bamboo salt or a mixture of the bamboo salt and a bactericidal agent, and 4-50 wt. pt. of a cation surfactant. The bactericidal agent is triclosan, trichloro carbanylide, dibromo salicylanylide, tribromo salicylanylide, dichloro trifluoromethyl carbanylide, C13H2NO2 or chloric acid chlorohexidine. The cation surfactant is dialkyl dimethyl quat. ammonium salt, diamido alkoxylated quat. ammonium salt or amido imidazolinium salt. The softening agent has a good antibacterial effect.

Description

[Name of invention]

Fabric softener composition containing bamboo salt

Detailed description of the invention

The present invention relates to a fabric softener composition containing bamboo salt.

More specifically, rinsing after washing with bamboo salt alone for the purpose of inhibiting and sterilizing the growth of microorganisms causing damage to the fiber material, staining of stains, odor generation and proliferation on the fibers and causing sterilization, or using fungicides together with bamboo salt for synergistic effects The present invention relates to a fabric softener composition for a healthy and comfortable life when wearing poetry and clothing.

There are many kinds of bacteria (Bacteria), yeast and mold in our living environment, and these microorganisms grow rapidly if their environmental conditions are suitable for their habitat. Looking at the effects of these microorganisms on the fiber and the human body, the breakdown of the fiber material, staining stains, odor generation, disease and the like.

First, the destruction of the fiber material is the enzyme produced as the microorganisms proliferate on the fibrous polymer material, which acts as an organic catalyst and hydrolyzes the polymer organic constructs. Pseudomonas fluorescens and Bacillus subtils ( Bacillus subtilis) and filamentous fungi include Aspergillus niger and Aspergillus oryzae.

Second, the staining of textile products is a pigment that is formed during the growth of microorganisms to the fiber, causing the staining of pigments, and related bacteria include Pseudomonas aeruginosa (green, blue, purple), Bacillus mesenhatri Bacillus mesentricus (Brown) and the like, as a filamentous fungus Aspergillus niger (black brown), Aspergillus duck (Aspergillus oryzae; yellow, green, yellowish brown), Penicillium citrinum (Penicillium citrinum; Bluish green).

Third, odor generation is the decomposition of nitrogen-containing pollutants secreted by the body into odor gas such as ammonia, and related bacteria include Staphylococcus aureus, Proteus vulgaris, Bacillus faecalis and the like, and candida albicans (Candina albicans) and the like.

Fourth, the microorganisms that can proliferate in fibers and cause diseases are those listed in the following table.

TABLE 1

Bamboo salt is made by using bamboo and salt, and it is made by the process of repeated process of high temperature in the furnace to remove new toxins and to prevent the sterilization and decay. It has been known as a elixir that maximizes its efficacy.

Salt used in the manufacture of bamboo salt is usually used as a natural salt, in addition to edible salt, rock salt, reagent grade sodium chloride and potassium chloride, and bamboo or cotton bamboo is used as bamboo, but there is no need to limit the type of bamboo.

Bamboo salt is a commercially available salt, which repeatedly removes toxins and maximizes the effect of medicines by repeatedly treating the ocher, sterilization and decay salts of bamboo, which produce cells.

Bamboo salt can be prepared by the method of delivering it to ancient books. Cut a bamboo tree (3 years old) suitable for the sea breeze on one side and block it on the other side, squeeze the salt from the barrel into the container, beat the greasy soil in the mountain nine times with a thin sieve, and dry it in the shade. Put red pine leaf, reinforcement mugwort, and jujube leaf about 1cm and seal it with clay soil kneaded about 2cm at the end.

Make several of these bamboos, put pines on a porcelain kiln made of ocher, sprinkle pine nuts, and set fire (room temperature above 1,000 ℃).

After about 24 hours, take it out (at this time, only the salt pillar absorbing the stem of red, red pine, mugwort, and loess) is crushed finely and the salt is added to the new bamboo barrel in the same way as the first. Repeat eight times and use the special stainless steel made underground to make high heat (1,500 ℃ or more). Changes like This mass is bamboo salt and crushed properly.

In general, as a mechanism for suppressing sweat odor, there is a method of suppressing the breakdown of sweat secretions by using antiperspirants in the body to reduce sweat secretion or inhibiting the growth of parasitic microorganisms on the skin using fungicides. .

In order to impart flexibility and antistatic properties to clothing and the like, softeners are mainly composed of water-soluble quaternary ammonium salts, such as quaternary ammonium salts composed of two long chain alkyls and two short chain alkyls, and dispersed in an aqueous medium. It is used in the form that I made. Cationic surfactants are generally known to be bactericidal, but the former quaternary ammonium salts are different from water-soluble quaternary ammonium salts such as mono-long chain alkyl tri-short chain alkyl quaternary ammonium salts or benzylalkonium chloride. Unlikely, the antimicrobial activity is weak.

Conventional superabsorbent fabric softener is to simply absorb the sweat from the body in the summer by reinforcing simple antistatic and softening effect and absorption.

However, there is a drawback that microorganisms decompose sweat absorbed in clothing to produce a smell of odor. In addition, there was a defect such as fiber damage, odor, disease caused by the microorganisms when washing or wearing clothing.

Japanese Patent No. 87-263380 uses a 3-isochiazoron-based antimicrobial agent in a water-soluble fourth grade bivalent surfactant to have antimicrobial activity (preservative) of the product itself, thereby providing a product having high antiseptic property without changing viscosity. Although there was a composition obtained, it was found that the antimicrobial activity of clothing was weak due to the adsorption of clothes of the disinfectant. In addition, Japanese Patent No. 80-149367 improves the antimicrobial properties by adding a small amount of an anionic surfactant in order to improve the antimicrobial properties of di-alkyl quaternary ammonium salts, but the system is very unstable and clothing is worn. There was no antimicrobial activity of the city.

Accordingly, an object of the present invention is to adsorb the bamboo salt alone or a mixture of bamboo salt and fungicide in the fabric softener to prevent or damage the development of microorganisms parasitic on the clothing or body to prevent clothing damage and to prevent odor (sweat), the occurrence of disease It is to provide a fabric softener composition to prevent.

The fabric softener composition according to the present invention contains bamboo salts and fungicides, so as to adsorb on the clothes as well as to have antimicrobial properties can meet the needs of consumers to have a comfortable and healthy life.

The fabric softener composition according to the present invention may use bamboo salt alone, but uses sterilization together with bamboo salt to increase the bactericidal effect. The fungicides usable in the present invention are triclosan, trichlor carbanide (TCC; C ₁₃ HCl ₃ N ₂ O), dibromo salicylanilide, tribromo salicylanilide, dichloro trifluoro methyl carbox Vanillide, halogarban (Irgasan CF-3; C ₁₃ H ₂ NO ₂ ), chlorhexidine hydrochloride [cl cl) 2 HCl]. In addition, Bardac 208M (Bardac 208M; the brand name of Lonza), Irgasan digot-300 (Irgasan DP-300), Chiram (irritant; Chloro xylenol (allergic), chlorcresol (soluble in water, irritant) and the like can also be used.

In the fabric softener composition according to the present invention, bamboo salt alone or a mixture of bamboo salt and salt is contained in an amount of 0.005 to 10 parts by weight, preferably 0.05 to 4.0 parts by weight, based on the total amount of the composition.

The fabric softener composition according to the present invention may further contain a cationic surfactant selected from dialkyl dimethyl quaternary ammonium salts, diamido alkoxylated quaternary ammonium salts and amido imidazolinium salts, wherein the alkyl group is C _12- Saturated or unsaturated fatty acids of C ₂₂ are preferred. Cationic surfactant is used 4 to 50 parts by weight, preferably 5 to 15 parts by weight.

In addition, 1 to 20 parts by weight, preferably 3 to 6 parts by weight of a nonionic surfactant, higher alcohol, polyhydric alcohol, or the like may be used alone or in combination of two or more thereof.

The present invention will be described in detail with reference to the following Examples.

Typical fabric softener compositions consist of the following compositions.

[Fiber Softener "A"]

* Alkyl groups are C ₁₂ -C ₂₂ saturated or unsaturated, alone or in combination.

** Contains preservatives, pigments, antigelling agents, antifoaming agents.

[Fabric Softener "I"]

* Alkyl groups are C ₁₂ -C ₂₂ saturated or unsaturated, alone or in combination.

** Contains preservatives, pigments, antigelling agents, antifoaming agents.

[Manufacturing method of fungicide-containing fabric softener composition]

Similar to known manufacturing techniques, if the disinfectant (trichloric acid, trichlorcarvanide, etc.) is a water insoluble powder, it is first dissolved in a liquid polyethylene glycol system such as PEG-400, or a polyhydric alcohol such as propylene glycol, ethylene glycol, or twin- It is first dissolved in a surfactant such as 20 and added directly if water-soluble. The addition order is to disperse the cationic surfactant in water and then to prepare a fabric softener.

[Measuring Antibacterial Effect]

Tested according to Korean Industrial Standard (KS) K0692-1984.

The outline of this KS test is to evaluate the antimicrobial activity of the fabric by placing the sterilized test specimen on the agar medium inoculated with the test bacteria and incubating it, then measuring and observing the size of the bacterial low zone resulting from the suppression of bacterial growth around the test specimen. .

Antimicrobial effect = area of basal area-area of sample cloth

Examples of the fabric softener composition and comparative examples of the fabric softener of the Example and the antimicrobial effect test results thereof are as follows.

[Examples 1 to 5]

Bardac 208-M; Lonza Corporation

[Examples 6 to 11]

Bardac 208-M; Lonza Corporation

[Examples 12 to 17]

Irgasan CF-3 (Irgasan CF03); Ciba-Geigy

[Comparative Examples 1 to 8]

Barquat MB-80; Lonza Corporation

[Alkyl dimethyl benzyl ammonium chloride]

As described in the above examples, the addition of bamboo salt to a conventional fabric softener enhances the antimicrobial effect of the fiber, and by using a fungicide such as triclosan, trichlor carbanyl, and Bardak 208M, the antimicrobial effect of the fiber is further enhanced. It can be seen that the increase of the effect was particularly large when 0.005 to 10.0 parts by weight was used.

In particular, when using more than 10.0 parts by weight of the antimicrobial effect is large, but the increase is insignificant because the economic loss is limited to 0.005 to 10 parts by weight, especially from 0.05 to 4.0 parts by weight can be seen that the increase in the antimicrobial increase. In addition, as seen in the comparative example, the use of the antimicrobial agent did not show any antimicrobial activity, and the antimicrobial agent used in Comparative Examples 3 to 8 showed an antimicrobial effect but was excluded due to reports of skin disorders.

Therefore, the fabric softener composition according to the present invention is excellent in the growth inhibitory and sterilizing effect of various microorganisms causing damage to the fiber material, staining stains, odor generation and fibers and causing disease, and is healthy when washing and wearing clothes after washing clothes. It will be seen that the invention is very useful industrially by enabling a comfortable life.

Claims (8)

A fabric softener composition comprising bamboo salt alone or a mixture of bamboo salt and a fungicide. The method of claim 1, wherein the fungicides are triclosan, trichlor carbanilide, dibromo salicylanilide, tribromo salicylanilide, dichloro trifluoro methyl carvanilide, halogarban (C ₁₃ H ₂ NO ₂ And chlorhexidine hydrochloride. The fabric softener composition according to claim 1 or 2, wherein the salt of bamboo salt alone or a mixture of bamboo salt and a fungicide is contained in an amount of 0.005 to 10 parts by weight. 4. The fabric softener composition according to claim 3, which contains 0.05 to 4.0 parts by weight of bamboo salt alone or a mixture of bamboo salt and a fungicide. The fabric softener composition of claim 1 containing a cationic surfactant selected from dialkyl dimethyl quaternary ammonium salts, diamino alkoxylated quaternary ammonium salts and amido imidazolinium salts. 6. The fabric softener composition of claim 5 wherein the alkyl group is a C ₁₂ -C ₂₂ saturated or unsaturated fatty acid. The fabric softener composition according to claim 5, wherein 4 to 50 parts by weight of a cationic surfactant is used. The fabric softener composition according to claim 6, wherein 5 to 15 parts by weight of a cationic surfactant is used.