KR950011412A - 제초제로서 유용한 아릴옥시벤젠 화합물, 이를 포함하는 조성물 및 방법 - Google Patents

제초제로서 유용한 아릴옥시벤젠 화합물, 이를 포함하는 조성물 및 방법 Download PDF

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KR950011412A
KR950011412A KR1019940025581A KR19940025581A KR950011412A KR 950011412 A KR950011412 A KR 950011412A KR 1019940025581 A KR1019940025581 A KR 1019940025581A KR 19940025581 A KR19940025581 A KR 19940025581A KR 950011412 A KR950011412 A KR 950011412A
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phenoxy
methyl
alkyl
nitrophenoxy
acetate
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KR1019940025581A
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아이 콘던 마이클
디이 크루우즈 쥬니어 앨빈
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알퐁스 아아르 노에
아메리칸 사이아나밋드 캄파니
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Publication of KR950011412A publication Critical patent/KR950011412A/ko

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Abstract

하기 구조식 Ⅰ의 아릴옥시벤젠 화합물이 기재되어 있다.
또한, 바람직하지 않은 식물종의 제어를 위한 상기 화합물로 구성되는 조성물 및 방법이 제공되어 있다.

Description

제초제로서 유용한 아릴옥시벤젠 화합물, 이를 포함하는 조성물 및 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 구조식을 갖는 화합물
    상기식에서
    M은 N 또는 CZ이고; X, Y 및 Z는 각각 독립적으로 수소, 할로겐, C1-C4알킬, C1-C4할로알콕시, 시아노 니트로 또는 S(O)pR7이며, 단 X, Y 및 z는 동시에 니트로일 수 없고; P는 0.1 또는 2의 정수이고; R7은 C1-C4알킬 또는 C1-C4할로알킬이고; R6는 C1-C4알킬이고; W 및 W1은 각각 독립적으로 O, S 또는 NR6이고; R8은 수소 똔느 C1-C4알킬이고; m은 0 또는 1의 정수이고; R은 니트로, 할로겐, 시아노, C1-C4알킬설포닐 또는 C1-C4할로알킬설포닐이고; R1은 수소, 할로겐 또는 니트로이고; R2는 수소, 할로겐, C1-C4알킬 또는 C1-C4할로알킬이고; R3및 R4는 각각 독립적으로 수소, C1-C4알킬 또는 C1-C4할로알킬이며, R3및 R4가 함께 취해지면 R3R4가 -(CH2)q-(이때 q는 2,3,4 또는 5의 정수임)을 나타내는 고리를 형성할 수 있고; n은 0,1,2,3,4 또는 5의 정수이고; R5는 시아노, C(O)R9, C(Q)R10, CH2OC(O)R11, CH2OR10, CH(OR12)2또는 N(R10)SO2R13, 또는 CO2R11기로써 치환된 C2-C8알케닐이고; R9은 OH, OR14, NR15R16또는 N(R10)SO2R13이고; Q는 O 또는 NOC(R3R4)CO2R12이고; R10은 수소, 또는 C1-C4알콕시로써 임의로 치환된 C1-C4알킬이고; R11은 수소, 또는 C1-C4알킬 또는 하나 이상의 할로겐, 시아노, 니트로, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 C1-C4할로알콕시기로서 임의로 치환된 페닐이고; R13는 C1-C4알킬이고; R13은 C1-C4알킬, C1-C4할로알킬, 또는 하나 이상의 할로겐, 시아노, 니트로, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 C1-C4할로알콕시기로써 임의의 치환된 페닐이고; R14은 C1-C4알콕시, C1-C4알킬티오, 하로겐, 히드록시, C3-C6시클로알킬, 푸릴, 또는 하나 이상의 할로겐, 시아노, 니트로, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 C1-C4할로 알콕시기로써 임의로 치환된 패닐롯써 임으로 치환된 C1-C6알킬, C1-C4알콕시, 할로겐, C3-C6시클로아킬, 또는 하나 이상의 할로겐, 시아노, 니트로, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 C1-C4할로알콕시기로써 임의로 치환된 페닐로써 임의로 치환된 C3-C6알케닐, C1-C4알콕시 또는 할로겐으로써 임의로 치환된 C3-C6알키닐, C3-C6시클로알킬, N=C(R3R4)CO2R10또는 알칼리 금속, 알칼리토금속, 망간, 구리, 아연, 코발트, 은, 니켈, 암모늄 또는 유기 암모늄 양이온이고; R15및 R13은 각각 독립적으로 수소, C1-C4알킬, 또는 하나 이상의 할로겐, 시아노, 니트로, C1-C4알킬, C1-C4할로알킬, C1-C4알콕시 또는 C1-C4할로알콕시기로써 임의로 치환된 페닐이다.
  2. 제1항에 있어서, 메틸 {0{5-[(2-클로로-a,a,a,6-테트리플루오로-p-톨일)옥시]2-니트로페녹시}페녹시}아세테이트인 화합물.
  3. 제초적으로 효과적 양의 하기 구조식을 갖는 화합물을 바람직하지 않은 식물종의 잎에 또는 그의 씨 또는 다른 전파 기관을 함유하는 흙 또는 물에 적용하는 것으로 구성되는, 상기 바람직하지 않는 식물종의 제어 방법.
    상기식에서, Ar, W, W1, m, n, R, R1, R2, R3, R4및 R5는 제1항에 기재되어 있다.
  4. 제3항에 있어서, 화합물이 하기로 구성되는 군으로부터 선택되는 방법. 메틸 {o-{5-[(2-클로로-a,a,a,5-테트라플루오로-p-톨일)-옥시]2-니트로페녹시}페녹시}아세테이트; {o-{5-[(2-클로로-a,a,a,6-테트라플루오로-p-옥시)-22-니트로페녹시}페녹시}아세톤산; 메틸 {o-{5-[(2,4-디클로로페녹시)-2-니트로페녹시]페녹시}아세테이트; 메틸 {o-{5-[(2-클로로-a,a,a-트리플루오로-p-톨일)-옥시]2-니트로페녹시}페녹시}아세테이트; 메틸 {o-{5-[(2-클로로-a,a,a,6-테트라플루오로-p-톨일)-옥시]2-니트로페녹시}페녹시}벤조에이트; 메틸 {o-{5-[(4-클로로-1-메틸-5-(트리플루오로메틸)피라졸-3-일]옥시}2-니트로페녹시}페녹시}아세테이트; 메틸 {p-{5-[(2-클로로-a,a,a,6-테트라플루오로-p-톨일)-옥시]2-니트로아릴리노}페녹시}아세테이트; 프로필 {p-{5-[(2,4-디클로로페녹시)-2-니트로페녹시}페녹시}아세테이트; 메틸 {o-{2-나트로-5-[(a,a,a,2-테트라플루오로-p-톨일)-옥시]2-니트로아릴리노}페녹시}아세테이트; 메틸 {o-{5-{[1-메틸-5-(트리플루오로메틸)피라졸-3-일]옥시}-2-니트로페녹시}페녹시}아세테이트; 메틸 {o-{5-[2-클로로-4-(메틸설피닐)페녹시]-2-니트로페녹시}페녹시}아세트산; 및 메틸 {o-{5-[2-클로로-4-(메틸설피닐)페녹시]-2-니트로페녹시}페녹시}아세테이트.
  5. 제3항에 있어서, 상기 화합물을 상기 식물의 잎에 약 0.016kg/ha-4.0kg/ha의 율로 적용하는 것으로 구성되는 방법.
  6. 벼가 이양된 후 제초적으로 효과적 양의 하기 구조식을 갖는 화합물을 바람직하지 않은 식물종의 씨 또는 다른 전파 기관을 함유하는 흙 또는 물에 적용하는 것으로 구성되는, 이양된 벼 내 상기 바람직하지 않은 식물종의 제어 방법.
    상기식에서, Ar, W, W1, m, n, R, R1, R2, R3, R4및 R5는 제1항에 기재되어 있다.
  7. 제6항에 있어서, 화합물이 하기로 구성되는 군으로부터 선택되는 방법. 메틸 {o-{5-(2,4-디클로로페녹시)-2-니트로페녹시]페녹시}아세테이트; 메틸 {o-{5-[(2-클로로-a,a,a,6-테트라플루오로-p-톨일)-옥시]2-니트로페녹시}페녹시}아세테이트; {o-{5-[(2-클로로-a,a,a,6-테트라플루오로-p-옥시)-2-니트로페녹시}페녹시}아세트산; 메틸 {o-{5-[(2-클로로-a,a,a-트리플루오로-p-톨일)-옥시]2-니트로페녹시}페녹시}아세테이트; 메틸 {o-{5-[(2-클로로-a,a,a,6a-테트플루오로-p-톨일)-옥시]-2-니트로-페녹시}벤조에이트; 메틸 {o-{5-[(4-클로로-1-메틸-5-(트리플루오로메틸)피라졸-3-일]옥시}2-니트로페녹시}페녹시}아세테이트; 메틸 {o-{5-[(2-클로로-a,a,a,6-테트라플루오로-p-톨일)-옥시]2-니트로아닐리노}페녹시}아세테이트; 프로피 {p-{5-[(2,4-디클로로페녹시)-2-니트로페녹시}페녹시}아세테이트; 메틸 {o-{2-나트로-5-[(a,a,a,2-테트라플루오로-p-톨일)-옥시]페녹시}아세테이트; 메틸 {o-{5-{[1-메틸-5-(트리플루오로메틸)피라졸-3-일]옥시}-2-니트로페녹시}페녹시}아세테이트; {o-{5-[2-클로로-4-(메틸설피닐)페녹시]-2-니트로페녹시}페녹시}아세트산; 및 메틸 {o-{5-[2-클로로-4-(메틸설피닐)페녹시]-2-니트로페녹시}페녹시}아세테이트.
  8. 불활성 고체 또는 액체 부형제, 및 하기 구조식을 갖는 제초적으로 효과적 양의 화합물로 구성되는 제초 조성물.
    상기식에서, Ar, W, W1, m, n, R, R1, R2, R3, R4및 R5는 제1항에 기재되어 있다.
  9. 제8항에 있어서,
    Ar은
    M은 N 또는 CZ이고; X, Y 및 Z는 각각 독립적으로 수소, 할로겐, C1-C4할로알킬 또는 S(O)pR7이고; P는 0.1 또는 2의 정수이고; R7은 C1-C4알킬 또는 C1-C4할로알킬이고; R6는 C1-C4알킬이고; W는 0 또는 NH이고; W1은 0이고; m은 0 또는 1의 정수이고; R은 니트로이고; R1은 수소, 할로겐 또는 니트로이고; R2는 수소이고; R3및 R4는 각각 독립적으로 수소 또는 C1-C4알킬이고; n은 0,1,2,3,4 또는 5의 정수이고; R5는 C(O)R9이고; R9은 OH, OR14이고; R14은 C1-C6알킬, C3-C6알케닐, C3-C6알키닐 또는 알칼리 금속, 알칼리토 금속, 암모늄 또는 트리 (C1-C6알킬) 암모늄 양이온인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940025581A 1993-10-07 1994-10-06 제초제로서 유용한 아릴옥시벤젠 화합물, 이를 포함하는 조성물 및 방법 KR950011412A (ko)

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