KR940703077A - 전기화학적 방법 - Google Patents
전기화학적 방법Info
- Publication number
- KR940703077A KR940703077A KR1019940701280A KR19940701280A KR940703077A KR 940703077 A KR940703077 A KR 940703077A KR 1019940701280 A KR1019940701280 A KR 1019940701280A KR 19940701280 A KR19940701280 A KR 19940701280A KR 940703077 A KR940703077 A KR 940703077A
- Authority
- KR
- South Korea
- Prior art keywords
- semiconductor
- thin film
- forming
- anode
- positive electrolyte
- Prior art date
Links
- 238000002848 electrochemical method Methods 0.000 title 1
- 239000004065 semiconductor Substances 0.000 claims abstract 23
- 238000000034 method Methods 0.000 claims abstract 20
- 239000003014 ion exchange membrane Substances 0.000 claims abstract 4
- 230000008021 deposition Effects 0.000 claims abstract 3
- 239000010409 thin film Substances 0.000 claims 14
- 239000003792 electrolyte Substances 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 229910052793 cadmium Inorganic materials 0.000 claims 2
- 239000008151 electrolyte solution Substances 0.000 claims 2
- 239000012528 membrane Substances 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- -1 VIB compound Chemical class 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- 238000005341 cation exchange Methods 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 239000002659 electrodeposit Substances 0.000 claims 1
- 238000004070 electrodeposition Methods 0.000 claims 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical group OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 229920003303 ion-exchange polymer Polymers 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- UUWCBFKLGFQDME-UHFFFAOYSA-N platinum titanium Chemical compound [Ti].[Pt] UUWCBFKLGFQDME-UHFFFAOYSA-N 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/34—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies not provided for in groups H01L21/0405, H01L21/0445, H01L21/06, H01L21/16 and H01L21/18 with or without impurities, e.g. doping materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02551—Group 12/16 materials
- H01L21/02562—Tellurides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02367—Substrates
- H01L21/0237—Materials
- H01L21/02422—Non-crystalline insulating materials, e.g. glass, polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02436—Intermediate layers between substrates and deposited layers
- H01L21/02439—Materials
- H01L21/02469—Group 12/16 materials
- H01L21/02474—Sulfides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
- H01L21/02617—Deposition types
- H01L21/02623—Liquid deposition
- H01L21/02628—Liquid deposition using solutions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/1828—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIBVI compounds, e.g. CdS, ZnS, CdTe
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/543—Solar cells from Group II-VI materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S205/00—Electrolysis: processes, compositions used therein, and methods of preparing the compositions
- Y10S205/915—Electrolytic deposition of semiconductor
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Electromagnetism (AREA)
- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
반도체의 개선된 전해 디포지션을 이온교환 막에 의해 캐소드와 애노드를 분리시킴으로써 얻었다. 이 방법은 광기전셀의 제조에서 IIB/VIB 반도체의 디포지션에 유용하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- 캐소드와 애노드 사이에 전류를 통과시켜 전해조로부터 재료를 전해 디포지션시키는 방법에 의한 반도체의 박막형성 방법에 있어서, 양전해액 구획과 음전해액 구획으로 분리하기 위한 이온교환막에 의해 반도체가 디포지션되는 전해조로부터 애노드가 분리되는 것을 특징으로 하는 반도체의 박막 형성방법.
- 제1항에 있어서, 반도체가 IIN/VIB 화합물인 것을 특징으로 하는 반도체의 박막 형성방법.
- 제2항에 있어서, 반도체가 Cd와 Te를 함유하고 있는 화합물인 것을 특징으로 하는 반도체의 박막 형성방법.
- 전항 중 어느 한 항에 있어서, 반도체 화합물이 캐소드상에 전해 디포지션되는 것을 특징으로 하는 반도체의 박막 형성방법.
- 전항 중 어느 한 항에 있어서, 애노드가 소모성 전극인 것을 특징으로 하는 반도체의 박막 형성방법.
- 제5항에 있어서, 애노드가 카드뮴 애노드인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 제1항 내지 제4항 중 어느 한 항에 있어서, 애노드가 비소모성 애노드인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 제7항에 있어서, 애노드가 백금 또는 백금티타늄인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 전항 중 어느 한 항에 있어서, 캐소드가 투명한 도전층, 그 다음에는 CdS층으로 피복된 유리판인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 전항 중 어느 한 항에 있어서, 이온교환막이 양이온 교환막인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 전항 중 어느 한 항에 있어서, 이온교환막이 퍼플루오르술폰산기를 함유하는 폴리머인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 제11항에 있어서, 폴리머가 술폰네이트기를 함유한 비닐 에테르공모노머와 테트라플루오르에틸렌과 공중합된 산물인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 전항 중 어느 한 항에 있어서, 양 전해액 구획내에 있는 양전해액과 음전해액에 구획내에 있는 음전해액이 다른 화합물로 되어 있는 것을 특징으로 하는 반도체의 박막 형성 방법.
- 제13항에 있어서, 애노드가 비소모성 전극이며 양전해액이 묽은 황산수용액인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 제13항에 있어서, 애노드는 Cd 애노드이며 양전해액은 묽은 HCl 수용액인 것을 특징으로 하는 반도체의 박막 형성 방법.
- 전항 중 어느 한 항에 있어서, 양전해액 구획내에 있는 양전해액이 전착과정 동안에 연속적으로 제거되고 새로운 양전해액으로 공급되는 것을 특징으로 하는 반도체의 박막 형성 방법.
- 캐소드와 애노드 사이에 전류를 통과시켜 IIB/VIB원소들을 함유한 이온들을 가진 전해조로부터 전착되는 IIB/VIB반도체층, 즉 CdS층을 포함하는 광기전셀에 있어서, IIB/VIB 반도체가 전해조로부터 디포지션되고 애노드는 전해조와 분리되며 반도체가 이온교환 폴리머 막에 의해 디포지션되는 것을 특징으로 하는 광기전셀.※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB919122169A GB9122169D0 (en) | 1991-10-18 | 1991-10-18 | Electrochemical process |
GB9122169.7 | 1991-10-18 | ||
PCT/GB1992/001888 WO1993008594A1 (en) | 1991-10-18 | 1992-10-15 | Electrochemical process |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940703077A true KR940703077A (ko) | 1994-09-17 |
KR100268822B1 KR100268822B1 (ko) | 2000-10-16 |
Family
ID=10703174
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940701280A KR100268822B1 (ko) | 1991-10-18 | 1992-10-15 | 반도체의 박막 형성방법 |
Country Status (12)
Country | Link |
---|---|
US (1) | US5478445A (ko) |
EP (1) | EP0538041A1 (ko) |
JP (1) | JP3130940B2 (ko) |
KR (1) | KR100268822B1 (ko) |
CN (1) | CN1092718C (ko) |
AU (1) | AU672761B2 (ko) |
GB (1) | GB9122169D0 (ko) |
IN (1) | IN186800B (ko) |
MY (1) | MY109064A (ko) |
TW (1) | TW232716B (ko) |
WO (1) | WO1993008594A1 (ko) |
ZA (1) | ZA928025B (ko) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5968364A (en) * | 1993-03-16 | 1999-10-19 | Henkel Corporation | Process for the removal of toxic cyanide and heavy metal species from alkaline solutions |
US8852417B2 (en) | 1999-04-13 | 2014-10-07 | Applied Materials, Inc. | Electrolytic process using anion permeable barrier |
US8236159B2 (en) * | 1999-04-13 | 2012-08-07 | Applied Materials Inc. | Electrolytic process using cation permeable barrier |
US6638239B1 (en) | 2000-04-14 | 2003-10-28 | Glaukos Corporation | Apparatus and method for treating glaucoma |
AU2002259152A1 (en) | 2001-05-08 | 2002-11-18 | Bp Corporation North America Inc. | Improved photovoltaic device |
US20050146875A1 (en) * | 2004-01-07 | 2005-07-07 | Tideland Signal Corporation | Side-emitting led marine signaling device |
JP2008522040A (ja) * | 2004-11-30 | 2008-06-26 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 導電性表面の膜制限選択性電気めっき |
US20120175262A1 (en) * | 2011-01-10 | 2012-07-12 | EncoreSolar, Inc. | Method and apparatus for electrodeposition of group iib-via compound layers |
US9005409B2 (en) | 2011-04-14 | 2015-04-14 | Tel Nexx, Inc. | Electro chemical deposition and replenishment apparatus |
US9017528B2 (en) | 2011-04-14 | 2015-04-28 | Tel Nexx, Inc. | Electro chemical deposition and replenishment apparatus |
US9303329B2 (en) | 2013-11-11 | 2016-04-05 | Tel Nexx, Inc. | Electrochemical deposition apparatus with remote catholyte fluid management |
TWI593841B (zh) * | 2015-03-27 | 2017-08-01 | 黃思倫 | 電化學法萃取植物纖維之萃取方法 |
CN106868563B (zh) * | 2015-12-11 | 2019-01-25 | 中国海洋大学 | 一种硒化物薄膜修饰泡沫镍电极的制备方法及其应用 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4400244A (en) * | 1976-06-08 | 1983-08-23 | Monosolar, Inc. | Photo-voltaic power generating means and methods |
US4192721A (en) * | 1979-04-24 | 1980-03-11 | Baranski Andrzej S | Method for producing a smooth coherent film of a metal chalconide |
US4388483A (en) * | 1981-09-08 | 1983-06-14 | Monosolar, Inc. | Thin film heterojunction photovoltaic cells and methods of making the same |
US4465565A (en) * | 1983-03-28 | 1984-08-14 | Ford Aerospace & Communications Corporation | CdTe passivation of HgCdTe by electrochemical deposition |
JPS60140406A (ja) * | 1983-12-28 | 1985-07-25 | Mitsubishi Heavy Ind Ltd | 船舶誘導装置 |
US4536260A (en) * | 1984-05-14 | 1985-08-20 | University Of Guelph | Thin film cadmium selenide electrodeposited from selenosulphite solution |
IN167516B (ko) * | 1986-05-06 | 1990-11-10 | Standard Oil Co Ohio | |
JP2509635B2 (ja) * | 1987-09-21 | 1996-06-26 | 財団法人相模中央化学研究所 | 金属カルコゲナイド粒子分散膜の製造方法 |
GB9022828D0 (en) * | 1990-10-19 | 1990-12-05 | Bp Solar Ltd | Electrochemical process |
-
1991
- 1991-10-18 GB GB919122169A patent/GB9122169D0/en active Pending
-
1992
- 1992-10-13 IN IN920DE1992 patent/IN186800B/en unknown
- 1992-10-15 KR KR1019940701280A patent/KR100268822B1/ko not_active IP Right Cessation
- 1992-10-15 AU AU27560/92A patent/AU672761B2/en not_active Ceased
- 1992-10-15 JP JP05507532A patent/JP3130940B2/ja not_active Expired - Fee Related
- 1992-10-15 WO PCT/GB1992/001888 patent/WO1993008594A1/en active Search and Examination
- 1992-10-15 EP EP92309428A patent/EP0538041A1/en not_active Ceased
- 1992-10-15 MY MYPI92001877A patent/MY109064A/en unknown
- 1992-10-15 US US08/211,775 patent/US5478445A/en not_active Expired - Lifetime
- 1992-10-16 ZA ZA928025A patent/ZA928025B/xx unknown
- 1992-10-17 TW TW081108266A patent/TW232716B/zh active
- 1992-10-17 CN CN92112353A patent/CN1092718C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
IN186800B (ko) | 2001-11-10 |
EP0538041A1 (en) | 1993-04-21 |
ZA928025B (en) | 1994-04-18 |
WO1993008594A1 (en) | 1993-04-29 |
KR100268822B1 (ko) | 2000-10-16 |
MY109064A (en) | 1996-11-30 |
CN1071977A (zh) | 1993-05-12 |
GB9122169D0 (en) | 1991-11-27 |
JPH07502303A (ja) | 1995-03-09 |
CN1092718C (zh) | 2002-10-16 |
TW232716B (ko) | 1994-10-21 |
AU2756092A (en) | 1993-05-21 |
JP3130940B2 (ja) | 2001-01-31 |
US5478445A (en) | 1995-12-26 |
AU672761B2 (en) | 1996-10-17 |
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