KR940014911A - 수산화제 4급암모늄수용액의 제조방법 - Google Patents
수산화제 4급암모늄수용액의 제조방법 Download PDFInfo
- Publication number
- KR940014911A KR940014911A KR1019930029846A KR930029846A KR940014911A KR 940014911 A KR940014911 A KR 940014911A KR 1019930029846 A KR1019930029846 A KR 1019930029846A KR 930029846 A KR930029846 A KR 930029846A KR 940014911 A KR940014911 A KR 940014911A
- Authority
- KR
- South Korea
- Prior art keywords
- quaternary ammonium
- aqueous solution
- ammonium hydroxide
- producing
- hydroxide aqueous
- Prior art date
Links
- 125000001453 quaternary ammonium group Chemical group 0.000 title claims abstract 11
- 239000000908 ammonium hydroxide Substances 0.000 title claims abstract 10
- 238000004519 manufacturing process Methods 0.000 title claims abstract 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract 8
- -1 quaternary ammonium organic acid Chemical class 0.000 claims abstract 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 7
- 239000001301 oxygen Substances 0.000 claims abstract 7
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 7
- 229910052751 metal Inorganic materials 0.000 claims abstract 5
- 239000002184 metal Substances 0.000 claims abstract 5
- 239000003054 catalyst Substances 0.000 claims abstract 4
- 238000000034 method Methods 0.000 claims abstract 4
- 239000007789 gas Substances 0.000 claims abstract 3
- 238000005868 electrolysis reaction Methods 0.000 claims abstract 2
- 239000007864 aqueous solution Substances 0.000 claims 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000004917 carbon fiber Substances 0.000 claims 1
- 239000000969 carrier Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 239000008151 electrolyte solution Substances 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 150000007524 organic acids Chemical group 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 claims 1
- DDDVBYGLVAHHCD-UHFFFAOYSA-M tetraethylazanium;formate Chemical compound [O-]C=O.CC[N+](CC)(CC)CC DDDVBYGLVAHHCD-UHFFFAOYSA-M 0.000 claims 1
- WWIYWFVQZQOECA-UHFFFAOYSA-M tetramethylazanium;formate Chemical group [O-]C=O.C[N+](C)(C)C WWIYWFVQZQOECA-UHFFFAOYSA-M 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract 1
- WUPZNKGVDMHMBS-UHFFFAOYSA-N azane;dihydrate Chemical compound [NH4+].[NH4+].[OH-].[OH-] WUPZNKGVDMHMBS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/01—Products
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/62—Quaternary ammonium compounds
- C07C211/63—Quaternary ammonium compounds having quaternised nitrogen atoms bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
고순도의 수산화제 4급암모늄수용액을 제조하는 방법을 제공하는 것으로서 제4급암모늄유기산염을 과산화수소, 산소 또는 산소함유가스를 백금족금속촉매의 존재하에 반응시켜서 제4급암모늄기산염을 제조하고, 이것을 양이온 교환막을 갖는 전해탱크를 사용해서 전해하는 것을 특징으로 하는 고순도의 수산화제4급암모늄수용액을 제조방법을 제시하는 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 일반식(I)[단, 식중 R1~R4는 탄소수 1~3의 알킬기를 나타내고, 그들은 동일하거나 달라도 된다. X는 유기산기를 나타낸다]로 표시되는 제4급암모늄유기산염의 수용액을 백금족금속촉매의 존재하에 과산화수소, 산소 또는 산소함유가스와 반응시켜서 제4급암모늄무기산염을 합성하고, 그 제4급암모늄무기산염수용액을 전해하는 것을 특징으로 하는 수산화제4급암모늄수용액을 제조방법.
- 제1항에 있어서, 제4급암모늄유기산염이 테트라메틸암모늄포름산염 또는 테트라에틸암모늄포름산염인 것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.
- 제1항에 있어서, 제4급암모늄유기산염과 과산화수소, 산소 또는 산소함유가스중의 산소와의 몰비가 0.5~100인 것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.
- 제3항에 있어서, 제4급암모늄유기산염과 과산화수소와의 몰비는 1~20인 것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.
- 제1항에 있어서, 백금족금속이 피라듐, 백금, 루테늄, 로듐 및 이리듐으로부터 선택된 적어도 1종인 것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.
- 제1항에 있어서, 백금족금속촉매는 백금족금속이 담체에 대해 0.01~20중량% 담지된 촉매인것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.
- 제6항에 있어서, 담체가 활성탄, 탄소섬유, 활성탄소섬유등의 탄소계담체; 실리카, 알루미나, 실리카-알루미나 및 제올라이트의 무기계담체로부터 선택된 담체인 것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.
- 제1항에 있어서, 전해에 있어서 양극실에 공급되는 제4급암모늄무기산염수용액의 농도가 1~60중량%인 것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.
- 제1항에 있어서, 제4급암모늄무기산염을 합성하는 반응온도가 10~200℃인 것을 특징으로 하는 수산화제4급암모늄수용액의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP92-348756 | 1992-12-28 | ||
| JP34875692A JP3277956B2 (ja) | 1992-12-28 | 1992-12-28 | 水酸化第四級アンモニウム水溶液の製造方法 |
| JP93-120173 | 1993-05-21 | ||
| JP12017393A JP3424687B2 (ja) | 1993-05-21 | 1993-05-21 | 水酸化第四級アンモニウム水溶液の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR940014911A true KR940014911A (ko) | 1994-07-19 |
| KR100242979B1 KR100242979B1 (ko) | 2000-02-01 |
Family
ID=26457793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930029846A KR100242979B1 (ko) | 1992-12-28 | 1993-12-27 | 수산화제4급암모늄수용액의 제조방법 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5393386A (ko) |
| EP (1) | EP0608545B1 (ko) |
| KR (1) | KR100242979B1 (ko) |
| DE (1) | DE69309885T2 (ko) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5935392A (en) * | 1995-06-01 | 1999-08-10 | Upscale Water Technologies, Inc. | Electrodes for electrolytic removal of nitrates from water, methods of making same, and apparatus incorporating said electrodes |
| US5958196A (en) * | 1995-06-01 | 1999-09-28 | Upscale Water Technologies, Inc. | Planar carbon fiber and noble metal oxide electrodes and methods of making the same |
| US5746993A (en) * | 1996-10-17 | 1998-05-05 | Advanced Micro Devices, Inc. | Process for manufacture of ultra-high purity ammonium hydroxide |
| KR100822236B1 (ko) * | 2000-11-30 | 2008-04-16 | 토소가부시키가이샤 | 레지스트 박리제 |
| DE102004043632A1 (de) * | 2004-09-07 | 2006-03-09 | Basf Ag | Verfahren zur Herstellung heterocyclischer quartärer Ammonium- und/oder Guanidinium-Verbindungen |
| JP6258512B2 (ja) * | 2014-01-14 | 2018-01-10 | サッチェム，インコーポレイテッド | 選択的金属／金属酸化物エッチングプロセス |
| CN114318376B (zh) * | 2022-01-26 | 2022-08-05 | 肯特催化材料股份有限公司 | 一种四丙基氢氧化铵的制备方法及其制备的季铵碱水溶液 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60100690A (ja) * | 1983-11-02 | 1985-06-04 | Tama Kagaku Kogyo Kk | 水酸化第四アンモニウムの製造方法 |
| JPS60165469A (ja) * | 1984-02-09 | 1985-08-28 | 松下冷機株式会社 | 冷凍装置 |
| JPS61170588A (ja) * | 1985-01-25 | 1986-08-01 | Tama Kagaku Kogyo Kk | 水酸化第四アンモニウム水溶液の製造方法 |
| US4714530A (en) * | 1986-07-11 | 1987-12-22 | Southwestern Analytical Chemicals, Inc. | Method for producing high purity quaternary ammonium hydroxides |
| US4776929A (en) * | 1986-11-25 | 1988-10-11 | Mitsubishi Gas Chemical Company, Inc. | Process for production of quaternary ammonium hydroxides |
-
1993
- 1993-12-15 US US08/168,049 patent/US5393386A/en not_active Expired - Fee Related
- 1993-12-18 DE DE69309885T patent/DE69309885T2/de not_active Expired - Fee Related
- 1993-12-18 EP EP93120484A patent/EP0608545B1/en not_active Expired - Lifetime
- 1993-12-27 KR KR1019930029846A patent/KR100242979B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0608545A1 (en) | 1994-08-03 |
| US5393386A (en) | 1995-02-28 |
| DE69309885T2 (de) | 1997-07-24 |
| KR100242979B1 (ko) | 2000-02-01 |
| EP0608545B1 (en) | 1997-04-16 |
| DE69309885D1 (de) | 1997-05-22 |
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