KR940014324A - [5-아미노-2-(2-하이드록시에틸아미노)-페닐] (2-하이드록시에틸)설폰의 제조방법 - Google Patents

[5-아미노-2-(2-하이드록시에틸아미노)-페닐] (2-하이드록시에틸)설폰의 제조방법 Download PDF

Info

Publication number
KR940014324A
KR940014324A KR1019930026717A KR930026717A KR940014324A KR 940014324 A KR940014324 A KR 940014324A KR 1019930026717 A KR1019930026717 A KR 1019930026717A KR 930026717 A KR930026717 A KR 930026717A KR 940014324 A KR940014324 A KR 940014324A
Authority
KR
South Korea
Prior art keywords
formula
dye
hydroxyethyl
disazooxy
compound
Prior art date
Application number
KR1019930026717A
Other languages
English (en)
Other versions
KR100294562B1 (ko
Inventor
헤르트 칼-요셉
헹크 헤르만
Original Assignee
롤프 브라운. 귄터 슈마허
바이엘 아크티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 롤프 브라운. 귄터 슈마허, 바이엘 아크티엔게젤샤프트 filed Critical 롤프 브라운. 귄터 슈마허
Publication of KR940014324A publication Critical patent/KR940014324A/ko
Application granted granted Critical
Publication of KR100294562B1 publication Critical patent/KR100294562B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/04—Preparation of sulfones; Preparation of sulfoxides by reactions not involving the formation of sulfone or sulfoxide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/26—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C317/32—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C317/34—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring
    • C07C317/36—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring with the nitrogen atoms of the amino groups bound to hydrogen atoms or to carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/02—Disazo dyes
    • C09B35/039—Disazo dyes characterised by the tetrazo component
    • C09B35/205—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl- or triaryl- alkane or-alkene
    • C09B35/215—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl- or triaryl- alkane or-alkene of diarylethane or diarylethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B43/00—Preparation of azo dyes from other azo compounds
    • C09B43/06—Preparation of azo dyes from other azo compounds by oxidation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
    • C09B62/507—Azo dyes
    • C09B62/513—Disazo or polyazo dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Coloring (AREA)

Abstract

구조식(1)의 설폰을 제조하는 방법은 일반식(5)의 디스아조/디수아조옥시 염료를 환원 분해시킴을 포함한다.
상기식에서, B는 직접 결합 또는 가교원이고, v, w, x 및 y는 각각 독립적으로 0 또는 1이며, 이때, x와 y의 합은 0 또는 1이고 v와 w의 합은 0또는 1이다.

Description

[5-아미노-2-(2-하이드록시에틸아미노)-페닐]2-하이드록시에틸)설폰의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 일반식(5)의 디수아조/디수아조옥시 염료를 환원 분해시킨 다음, 생성된 일반식(2)의 디아미노 화합물을 산성화시키고, 침전시킨 후, 2개의 베타인이 결합된 상태로 존재하는 거의 수불용성인 베타인으로 분리함을 특징으로하여, 구조식(1)의 [5-아미노-2-(2-하이드록시에틸아미노)-페닐]-2-하이드록시에틸)설폰의 제조하는방법.
    상기식에서, B는 직접 결합 또는 가교원이고, v, w, x 및 y는 각각 독립적으로 0 또는 1이며, 이때, x와 y의 합은 0 또는 1이고 v와 w의 합은 0 또는 1이다.
  2. 제 1 항에 있어서, B가 CH2, CH2CH2, SO2, CO, O, CH=CH,NHCONH, OCH2CH2, O,NH 또는 N(C1-C4-알킬)인 일반식(5)의 디스아조/디스아조옥시 염료를 사용함을 특징으로 하는 방법.
  3. 제 1 항 또는 제 2 항에 있어서, B가 CH2CH2또는 CH=CH인 일반식(5)의 디스아조/ 디스아조옥시 염료를 사용함을 특징으로 하는 방법.
  4. 제 1 항 내지 제 3 항 중의 어느 한 항에 있어서, 일반식(5a)의 디스아조/ 디스아조옥시 염료를 사용함을 특징으로 하는 방법.
    상기식에서, B는 CH2CH2또는 CH=CH이고, v, w, x 및 y는 제 1 항에 정의한 바와 같다.
  5. 제 1 항에 있어서, 일반식(5)의 디수아조/디수아조옥시 염료가, 일반식(2)의 디아미노 화합물을 테트라아조화시키고, 테트라아조늄 화합물을 구조식(3)의 2-(2-하이드록시에틸)머캅토-N-(2-하이드록시에틸)아닐린 2당량에 커플링시킨 다음, 생성된 일반식(4)의 디스아조 화합물을 산화시킴으로써 수득되는 방법.
    상기식에서 B는 직접 결합 또는 가교원이고, v, w, x 및 y는 제 1 항에 정의한 바와 같다.
  6. 제 5 항에 있어서, B가 CH2, CH2CH2, SO2, CO, O, CH=CH,NHCONH, OCH2CH2, O,NH 또는 N(C1-C4-알킬)인 디아미노 화합물을 사용하는 방법.
  7. 제 5 항에 있어서, 일반식(2a)의 디아미노 화합물을 사용하는 방법.
    상기식에서, B는 CH2CH2또는 CH=CH이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930026717A 1992-12-08 1993-12-07 [5-아미노-2-(2-하이드록시에틸아미노)-페닐](2-하이드록시에틸)술폰의제조방법 KR100294562B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4241284A DE4241284A1 (de) 1992-12-08 1992-12-08 Verfahren zur Herstellung von [5-Amino-2-(2-hydroxyethylamino)-phenyl](2-hydroxyethyl)sulfon
DEP4241284.6 1992-12-08

Publications (2)

Publication Number Publication Date
KR940014324A true KR940014324A (ko) 1994-07-18
KR100294562B1 KR100294562B1 (ko) 2001-09-17

Family

ID=6474682

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930026717A KR100294562B1 (ko) 1992-12-08 1993-12-07 [5-아미노-2-(2-하이드록시에틸아미노)-페닐](2-하이드록시에틸)술폰의제조방법

Country Status (6)

Country Link
US (1) US5414131A (ko)
EP (1) EP0601406B1 (ko)
JP (1) JPH06199772A (ko)
KR (1) KR100294562B1 (ko)
CN (1) CN1040643C (ko)
DE (2) DE4241284A1 (ko)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2284720T3 (es) 2000-11-21 2007-11-16 Flexsys America L.P. P-fenilendiaminas sustituidas con alquiltio-y aril(heteroil)tio-, su fabricacion y su uso en caucho.
US7718722B2 (en) * 2000-11-21 2010-05-18 Flexsys America L.P. Alkylthio- and aryl(heteroyl)thio-substituted p-phenylenediamines, their manufacture and their use in rubber

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3439756A1 (de) * 1984-02-11 1985-08-14 Bayer Ag, 5090 Leverkusen Triphendioxazin-vinylsulfon-farbstoffe
US5278291A (en) * 1989-12-02 1994-01-11 Bayer Aktiengesellschaft Hydroxyethylthio hydroxyethylamino-phenyl-azo and -azoxy dyestuffs
DE3939966A1 (de) * 1989-12-02 1991-06-06 Bayer Ag Azofarbstoffe und verfahren zur herstellung von (5-amino-2-(2-hydroxyethylamino)phenyl)(2-hydroxyethyl)-sulfon

Also Published As

Publication number Publication date
EP0601406B1 (de) 1996-02-28
JPH06199772A (ja) 1994-07-19
EP0601406A1 (de) 1994-06-15
US5414131A (en) 1995-05-09
DE4241284A1 (de) 1994-06-09
DE59301725D1 (de) 1996-04-04
CN1040643C (zh) 1998-11-11
CN1094033A (zh) 1994-10-26
KR100294562B1 (ko) 2001-09-17

Similar Documents

Publication Publication Date Title
PL295030A1 (en) Method of obtaining substituted derivatives of 2-cyclohexan-1-yl amine
DE69118683D1 (de) Methylpyrrolidonchitosan, verfahren zu dessen herstellung und seine verwendungen
ATE90088T1 (de) 1-chlorpyrimidinyl-1h-1,2,4-triazol-3sulfons|ureamide, verfahren zu ihrer herstellung und ihre verwendung als mittel mit herbizider wirkung.
KR940014324A (ko) [5-아미노-2-(2-하이드록시에틸아미노)-페닐] (2-하이드록시에틸)설폰의 제조방법
DE59108744D1 (de) 8-EN-19, 11 beta-ÜBERBRÜCKTE STEROIDE, DEREN HERSTELLUNG UND DIESE ENTHALTENDE PHARMAZEUTISCHE PRÄPARATE
DE69105338D1 (de) Verfahren zur Herstellung von 1-(2,3,4-Trimethoxybenzyl)-Piperazin durch reduktive Aminierung.
DE3761560D1 (de) Substituierte derivate von n-aethyl(meth)acrylamid, und verfahren zu ihrer herstellung.
PT97738A (pt) PROCESSO PARA A PREPARACAO DE DAIS DE URóNIO
FR2422189A1 (fr) Compose liberateur de colorant azoique et produit photographique le contenant
IL65217A (en) N-(2,2,2-trifluoroethyl)-n-alkyl-azolyloxyacetic acid amides,their preparation and their use as herbicides
KR840007577A (ko) 벤조일우레아 화합물의 제조방법
ATE159521T1 (de) Thioacylierungsmittel und zwischenprodukte, thiopeptide, und verfahren zu deren herstellung und anwendung
DE58909046D1 (de) Polyazofarbstoffe und deren Zwischenprodukte.
ATE118521T1 (de) Beschichtungsmasse, verfahren zu ihrer herstellung sowie deren verwendung.
ATE171936T1 (de) Salpetersäureester von 2-(2,6-dihalophenylamino) phenylacetoessigsäurederivaten und verfahren zu ihrer herstellung
ATE80388T1 (de) Verfahren zur herstellung von 5-gliedrigen, stickstoffhaltigen heteroaromaten.
BR9808047B1 (pt) processo para a preparação de 2-nitroguanidinas 1,3-dissubstituìdas.
DE69119994D1 (de) Verfahren zur Herstellung von Desoxynukleosiden
ATE23993T1 (de) Verfahren zur herstellung von o,o&#39;dithiobenzamiden.
ES2123599T3 (es) Procedimiento para la produccion de 2-halogeno-4,6-dialcoxipirimidinas.
DE69614334D1 (de) Genähte Befestigungsschlinge für ein elastisches Seil, sowie Verfahren zu deren Herstellung
YU146890A (sh) Postopek za pripravo nesimetričnio substituiranih sečnin, karbamatov, tiokarbamatov in substituiranih izocianatov
DE69404932D1 (de) Zwischenprodukte zur Herstellung von Vitamin A und von Carotenoiden und Verfahren zu deren Herstellung
BR9106612A (pt) Compostos disazo,processos para a sua preparacao e sua aplicacao como corantes
ATE89279T1 (de) 1-methoxypyrimidinyl-1h-1,2,4-triazol-3sulfons|urenitroanilide, verfahren zu ihrer herstellung und ihre verwendung als mittel mit herbizider wirkung.

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee