KR940011524A - 폴리에테르 치환 이미드 화합물 및 그의 용도 - Google Patents

폴리에테르 치환 이미드 화합물 및 그의 용도 Download PDF

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KR940011524A
KR940011524A KR1019930025440A KR930025440A KR940011524A KR 940011524 A KR940011524 A KR 940011524A KR 1019930025440 A KR1019930025440 A KR 1019930025440A KR 930025440 A KR930025440 A KR 930025440A KR 940011524 A KR940011524 A KR 940011524A
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포머 클라우스
베버 라이너
되르즈바흐-랑게 코넬리아
하이다 라인하르트
모레토 한스-하인리히
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게르하르트 뮐러, 로타르 스타일링
바이엘 악티엔게젤샤프트
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    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/03—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the sulfonamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C311/04—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the sulfonamide groups bound to hydrogen atoms or to acyclic carbon atoms to acyclic carbon atoms of hydrocarbon radicals substituted by singly-bound oxygen atoms
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/334—Polymers modified by chemical after-treatment with organic compounds containing sulfur
    • C08G65/3344—Polymers modified by chemical after-treatment with organic compounds containing sulfur containing oxygen in addition to sulfur
    • C08G65/3346—Polymers modified by chemical after-treatment with organic compounds containing sulfur containing oxygen in addition to sulfur having sulfur bound to carbon and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/337—Polymers modified by chemical after-treatment with organic compounds containing other elements
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    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/26—Sulfonamides
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/004—Surface-active compounds containing F

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Abstract

본 발명은 신규한 이미드의 폴리에테르 치환 화합물 및 계면활성제로서의 그의 용도에 관한 것이다. 상기 화합물을 사용하여 계면활성제로 사용할 수 있고 저렴한 비용으로 간단하게 생산할 수 있는 플루오로기를 함유하는 폴리에테르 계면 활성제를 제공할 수 있다.

Description

폴리에테르 치환 이미드 화합물 및 그의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 하나 이상의 플루오로알킬 및 플루오로아릴기를 함유한 하기 일반식(1)의 화함물.
    상기 식 중, RF는 탄소수 1 내지 18의 직쇄 또는 분지쇄 플루오로아킬 잔기, 탄소수 6 내지 12의 플루오로알릴잔기, 탄소수 7 내지 18의 혼합 플루오로알킬아릴 잔기 또는 탄소수 2 내지 18의 플루오로화 모노 또는 폴리에테르이고, R은 (i) 탄소수 1 내지 24의 직쇄 또는 분지쇄 알킬 잔기, 탄소수 6 내지 12의 아릴 잔기 또는 탄소수 7 내지 24의 혼합 알킬아릴 잔기이며, 탄소 사슬에 산소, 질소 또는 황 원자가 개입될 수 있고, 또는 (ii) 추가로 상기 정의된 RF잔기이며, 두 RF잔기는 동일 또는 상이할 수 있고, Yl및 Y2는 각각또는기를 나타내고, m은 0 내지 6의 정수이고, n은 0 내지 6의 정수이고, PE는 5 내지 50의 에틸렌 옥사이드 단위 또는 5 내지 50의 프로필렌 옥사이드 단위 또는 5 내지 50의 에틸렌 옥사이드 및 프로필렌 옥사이드 단위의 혼합물로 이루어진 폴리에테르 사슬이고, RH는 수소 원자 또는 탄소수 1 내지 10의 직쇄 또는 분지쇄 알킬 잔기이다.
  2. 제1항에 있어서, RF가 탄소수 3 내지 10의 직쇄 또는 분지쇄 플루오로알킬 잔기 또는 탄소수 6 내지 12의 플루오로아릴 잔기인, 하나 이상의 플루오로알킬 및 플루오로아릴기를 함유한 이미드 화합물.
  3. 제1항에 있어서, RF가 탄소수 3 내지 10의 직쇄 또는 분지쇄 과플루오로알킬 잔기 또는 탄소수 5 내지 12의 과플루오로아릴 잔기인 하나 이상의 플루오로알킬 및 플루오로아릴기를 함유한 이미드 화합물.
  4. 제1항에 있어서, R이 탄소수 6 내지 14의 직쇄 또는 분지쇄 알킬 잔기, 탄소수 6 내지 12의 아릴 잔기, 탄소수 7 내지 14의 혼합 알킬아릴 잔기 또는 탄소수 3 내지 10의 직쇄 또는 분지쇄 과플루오로알킬 잔기인 이미드 화합물.
  5. 제1항에 있어서, Y1및 Y2가 각각기를 나타내는 이미드 화합물.
  6. 1항에 있어서, m 및 n이 0인 이미드 화합물.
  7. 제1항에 있어서, RH가 탄소수 2 내지 4의 직쇄 알킬 잔기인 이미드 화합물.
  8. 플루오로알킬 또는 플루오로아릴기를 함유하는 하기 일반식(Ⅱ)의 화합물을 3급 아민의 존재하에 하기 일반식(Ⅲ)의 아민과 반응시켜 하기 일반식(Ⅳ)의 화합물로 이루어진 반응 산물을 형성하고, 추가로 일반식(Ⅳ)의 화합물을 3급 아민의 존재하에 하기 일반식(Ⅴ)의 화합물과 반응시키는 것을 특징으로 하는 제1항에 따른, 하나 이상의 플루오로알킬 또는 플루오로아릴기를 함유하는 이미드 화합물의 제조방법.
    상기 식중 RF, m, Yl, PE, RH, R, n 및 Y2는 제1항에 정의한 바와 같고, A1는 할로겐 원자, 히드록시기, 알콕시기 및 카르복시기로 이루어진 군에서 선택된 반응성 이탈기를 나타내고, A2는 Al과 같은 의미이다.
  9. 제1항에 정의된 이미드 화합물 또는 그의 염을 계면 활성제로서 조성물에 가하는 것을 특징으로 하는 제1항에 따른 이미드 화합물 또는 그의 염의 사용방법.
  10. 일반식
    또는 일반식
    를 갖는 이미드 화합물.
  11. 제1항에 있어서, Yl및 Y2가 각각기를 나타내는 이미드 화합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930025440A 1992-11-27 1993-11-26 폴리에테르 치환 이미드 화합물 및 그의 용도 KR100281200B1 (ko)

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Application Number Priority Date Filing Date Title
DE4240008A DE4240008A1 (de) 1992-11-27 1992-11-27 Polyethersubstituierte Imidverbindungen sowie deren Verwendung
DEP4240008.2 1992-11-27

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KR940011524A true KR940011524A (ko) 1994-06-21
KR100281200B1 KR100281200B1 (ko) 2001-02-01

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US (1) US5414120A (ko)
EP (1) EP0600294B1 (ko)
JP (1) JP3220582B2 (ko)
KR (1) KR100281200B1 (ko)
CN (1) CN1035328C (ko)
CA (1) CA2109853A1 (ko)
DE (2) DE4240008A1 (ko)
ES (1) ES2192189T3 (ko)
TW (1) TW279168B (ko)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100378667B1 (ko) * 2000-08-31 2003-03-31 주식회사 참 존 가축분뇨등의 신속한 무취화 및 퇴비화 방법 및 그 조성물
US7037494B2 (en) * 1997-10-14 2006-05-02 The Board Of Regents Of The University Of Texas System Formulations and methods for insect control

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Publication number Priority date Publication date Assignee Title
JP3250777B2 (ja) * 1995-02-13 2002-01-28 セントラル硝子株式会社 イミド類、その塩類およびそれらの製造法
US5874616A (en) * 1995-03-06 1999-02-23 Minnesota Mining And Manufacturing Company Preparation of bis (fluoroalkylenesulfonyl) imides and (fluoroalkysulfony) (fluorosulfonyl) imides
CN102489216B (zh) * 2011-12-06 2014-01-22 华中师范大学 两性含氟离子型表面活性剂的制备方法与应用
GB201609437D0 (en) * 2016-05-27 2016-07-13 Sphere Fluidics Ltd Surfactants

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Publication number Priority date Publication date Assignee Title
DE1140188B (de) * 1957-07-23 1962-11-29 Minnesota Mining & Mfg Verfahren zur Herstellung von N-Polyoxyalkylenperfluoralkansulfon-saeureamiden
FR2088594A5 (ko) * 1970-04-17 1972-01-07 Ugine Kuhlmann
DE2238740C3 (de) * 1972-08-05 1981-07-16 Bayer Ag, 5090 Leverkusen Perfluoralkylgruppenhaltige Polyäther und Verfahren zu deren Herstellung und deren Verwendung
JPS5836037B2 (ja) * 1980-06-27 1983-08-06 ダイキン工業株式会社 含フツ素界面活性剤組成物
FR2527602A1 (fr) * 1982-06-01 1983-12-02 Anvar Bis perhalogenoacyl- ou sulfonyl- imidures de metaux alcalins, leurs solutions solides avec des matieres plastiques et leur application a la constitution d'elements conducteurs pour des generateurs electrochimiques
EP0211578A3 (en) * 1985-07-24 1987-11-11 Research Corporation N-fluoro-n-perfluoromethyl sulfonamides
US4697011A (en) * 1985-07-24 1987-09-29 Research Corporation N-fluoro-N-perfluoromethyl sulfonamides
JPH02180861A (ja) * 1988-10-28 1990-07-13 Minnesota Mining & Mfg Co <3M> アルキルアリールオキシポリ（オキシアルキレン）アミンのスルホンアミド誘導体

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7037494B2 (en) * 1997-10-14 2006-05-02 The Board Of Regents Of The University Of Texas System Formulations and methods for insect control
KR100378667B1 (ko) * 2000-08-31 2003-03-31 주식회사 참 존 가축분뇨등의 신속한 무취화 및 퇴비화 방법 및 그 조성물

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JP3220582B2 (ja) 2001-10-22
CN1035328C (zh) 1997-07-02
CN1089960A (zh) 1994-07-27
JPH07304865A (ja) 1995-11-21
US5414120A (en) 1995-05-09
EP0600294A2 (de) 1994-06-08
EP0600294A3 (de) 1995-04-19
KR100281200B1 (ko) 2001-02-01
DE59310331D1 (de) 2003-03-27
ES2192189T3 (es) 2003-10-01
CA2109853A1 (en) 1994-05-28
TW279168B (ko) 1996-06-21
EP0600294B1 (de) 2003-02-19
DE4240008A1 (de) 1994-06-01

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