KR940011420A - 시클로헥실기 함유 글리시딜 에테르 - Google Patents

시클로헥실기 함유 글리시딜 에테르 Download PDF

Info

Publication number
KR940011420A
KR940011420A KR1019930023984A KR930023984A KR940011420A KR 940011420 A KR940011420 A KR 940011420A KR 1019930023984 A KR1019930023984 A KR 1019930023984A KR 930023984 A KR930023984 A KR 930023984A KR 940011420 A KR940011420 A KR 940011420A
Authority
KR
South Korea
Prior art keywords
hydrogen
general formula
radicals
containing glycidyl
unsubstituted
Prior art date
Application number
KR1019930023984A
Other languages
English (en)
Other versions
KR100286593B1 (ko
Inventor
볼레프 하인즈
크라메르 안드레아스
Original Assignee
베르너 발데크
시바-가이기 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 베르너 발데크, 시바-가이기 아게 filed Critical 베르너 발데크
Publication of KR940011420A publication Critical patent/KR940011420A/ko
Application granted granted Critical
Publication of KR100286593B1 publication Critical patent/KR100286593B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/02—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C215/04—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated
    • C07C215/06—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic
    • C07C215/12—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic the nitrogen atom of the amino group being further bound to hydrocarbon groups substituted by hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/52—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups or amino groups bound to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/18—Ethers having an ether-oxygen atom bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C43/196—Ethers having an ether-oxygen atom bound to a carbon atom of a ring other than a six-membered aromatic ring containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3218—Carbocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 낮은 염소 함량 및 낮은 점도를 갖는 특징이 있으며 예컨대, 반응성 희석재, 가용제 또는 접착제 강화제로서 에폭시 수지 배합물에서 사용될 수 있거나, 또는 그 자체로도 중합되어 거의 물을 흡수하지 않고 양호한 옥의 내후성을 갖는 피복제 또는 성형 수지로서 사용될 수 있는, 제1항에 따른 일반식(Ⅰ) 내지 (Ⅳ)의 시클로헥실기 함유 글리시딜 에테르에 관한 것이다.

Description

시클로헥실기 함유 글리시딜 에테르
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기식 (Ⅰ),(Ⅱ),(Ⅲ) 또는 (Ⅳ)의 시클로헥실기 함유 글리시딜 에테르;
    상기식에서, R1,R2및 R3는 각각 독립적으로 수소, 비치환 또는 치환된 C1-C10알킬 라디칼 또는 수소화된 아릴 라디칼이고; R4및 R5는 각각 독립적으로 수소 또는 C1-C20알킬 라디칼이며; R6는 수소, 비치환 또는 치환된 C1-C10알킬 라디칼 또는 수소화된 아릴 라디칼이고; X는 일반식 -CH2-, (CH3)2-, -C(CF3)2- -CO-, -O-, -S-, -SO2-,의 브릿지 구성이며; Y=0(n=1일때)이거나 N(n=2일때)이고; m은 숫자 1,2 또는 3이며, n=1(Y=0일 때) 또는 2(Y=N일때)이고; o는 숫자 1 내지 30이며, Z는 직접 결합 또는 일반식 -CH2-, 또는의 브릿지 구성원이다.
  2. 제1항에 있어서, 화합물이 대칭적이며 일반식(Ⅰ)의 X 및 Y가 서로에 대해 p-위치에 있고, 일반식(Ⅱ)의 Y 3개가 C 또는 Z에 대해 각각 p-위치에 있는 일반식(Ⅰ) 내지 (Ⅳ)의 시클로핵실기 함유 글리시딜 에테르.
  3. 제1항에 있어서, 하기와 같은 일반식(Ⅰ) 내지 (Ⅳ)의 시클로헥실기 함유 글리시딜 에테르: R1,R2및 R3는 수소 및/또는 C1-C10알킬 라디칼, 특히 CH3라디칼이고; R4및 R5는 수소 및/또는 CH3이며; R6는 수소이고; X는 일반식 -CH2-, -(CH3)2-, -C(CF3)2- -CO-, -O-, 또는 -SO2-의 브릿지 구성원이며, Y는 0이고; n은 1이며; Z는 직접 결합 또는 브릿지 구성원 -CH2-이고; m은 숫자 2 또는 3이며; 0는 숫자 1 내지 20이고 특히 1 내지 15이다.
  4. 제1항에 있어서, 하기와 같은 일반식(Ⅰ)의 시클로헥실기 함유 글리시딜 에테르; R1,R2및 R3는 수소 및/또는 C1-C10알킬 라디칼, 특히 CH3라디칼이고; R4및 R5는 수소 및/또는 CH3이며; Y는 0이고; n은 숫자 1이며; X는 일반식 -CH2-, (CH3)2-, -C(CF3)2- -CO-, -O-, 또는 -SO2-의 브릿지 구성원이다.
  5. 제1항에 있어서, 하기와 같은 일반식(Ⅱ)의 시클로헥실기 함유 글리시딜 에테르: R1,R2및 R3는 수소 및/또는 C1-C10알킬 라디칼, 특히 CH3라디칼이고; R4및 R5는 수소 및/또는 CH3이며; R6는 수소이고; Y는 0이고; n은 1이며; Z는 직접 결합 또는 브릿지 구성원 -CH2-이다.
  6. 제1항에 있어서, 하기와 같은 일반식(Ⅲ)의 시클로헥실기 함유 글리시딜 에테로: R1,R2및 R3는 수소 및/또는 C1-C10알킬 라디칼, 특히 CH3라디칼이고; R4및 R5는 수소 및/또는 CH3이며; Y는 0이고; n은 1이며; m은 2 또는 3이다.
  7. 제1항에 있어서, 하기와 같은 일반식(Ⅳ)의 시클로헥실기 함유 글리시딜 에테로: R1,R2및 R3는 수소 및/또는 C1-C10알킬 라디칼, 특히 CH3라디칼이고; R4및 R5는 수소 및/또는 CH3이며; Y는 0이고; n은 1이며; o는 숫자 1 내지 20이며, 특히 1 내지 15이다.
  8. a)하기식(Ⅰa),(Ⅱa),(Ⅲa) 또는 (Ⅳa)의 화합물을 온도 약 50 내지 200℃ 및 압력 1 내지 10바아, 유기 용매에서 염기의 존재하에 에틸렌 옥시드 또는 하기식(A)의 유도체와 반응시키고; (b)이렇게 제조된 일반식(Ⅰb),(Ⅱb),(Ⅲb) 또는 (Ⅳb)의 화합물을 수소 및 촉매에 의해, 바람직하게는 온도 50 내지 200℃ 및 압력 50 내지 200바아, 유기 용매에 있어서, 수소화 반응 시킨후; c)온도 약 40 내지 90℃ 및 압력 50 내지 200토르에서 알칼리 용액을 첨가하면서, 상 전이 촉매의 존재하에 에피할로히드린과 함께 반응시켜, 제1항에 따른 일반식(Ⅰ),(Ⅱ),(Ⅲ) 또는 (Ⅳ)의 시클로헥실기 함유 글리시딜 에테르를 제조하는 방법;
    상기식에서, R1,R2및 R3는 각각 독립적으로 수소, 비치환 또는 치환된 C1-C10알킬 라디칼 또는 수소화된 아릴 라디칼이고; R4및 R5는 각각 독립적으로 수소 또는 C1-C20알킬 라디칼이며; R6는 수소, 비치환 또는 치환된 C1-C10알킬 라디칼 또는 수소화된 아릴 라디칼이고; X는 일반식 -CH2-, (CH3)2-, -C(CF3)2- -CO-, -O-, -S-, -SO2-,의 브릿지 구성이며; Y=0(n=1일때)이거나 N(n=2일때)이고; m은 숫자 1,2 또는 3이며, n=1(Y=0일 때) 또는 2(Y=N일때)이고; o는 숫자 1 내지 30이며, Z는 직접 결합 또는 일반식 -CH2-, 또는의 브릿지 구성원이고, R1′,R2′ 및 R3′는 각각 독립적으로 수소, 비치환 또는 치환된 C1-C10알킬 라디칼 또는 아릴이고, R6′는 수소, 비치환 또는 치환된 C1-C10알킬 또는 아릴이며; X1는 일반식 -CH2-, (CH3)2-, -C(CF3)2- -CO-, -O-, -S-, -SO2-,의 브릿지 구성원이며; Y1=0 또는 NH이고, Z1은 직접 결합 또는 CH2또는다.
  9. a)일반식 (Ⅰa1),(Ⅱa1),(Ⅲa1) 또는 (Ⅳa1)의 화합물을, 바람직하게는 온도 약 50 내지 200℃ 및 압력 50 내지 200바아, 유기 용매에서, 수소 및 촉매에 의해 수소화 반응시키고; b)그 결과 제조된 하기식의 신규 수소화된 하기식(Ⅰb1),(Ⅱb1),(Ⅲb1) 또는 (Ⅳb1)의 화합물을 온도 약 40 내지 90℃ 및 압력 50 내지 200토르에서 알칼리 용액을 첨가하면서, 상 전이 촉매의 존재하에 에피할로히드린과 함께 반응시켜 각각, R4가 CH3이고 R5가 H인 제1항에 따른 일반식(Ⅰ) 내지 (Ⅳ)의 화합물을 제조하는 방법;
    상기식에서, R1,R2및 R3는 각각 독립적으로 수소, 비치환 또는 치환된 C1-C10알킬 라디칼 또는 수소화된 아릴 라디칼이고; R4는 CH3이고, R6는 수소, 비치환 또는 치환된 C1-C10알킬 라디칼 또는 수소화된 아릴 라디칼이고; X는 일반식
    Y=0(n=1일때)이거나 N(n=2일때)이고; m은 숫자 1,2 또는 3이며, n=1(Y=0일 때) 또는 2(Y=N일때)이고; o는 숫자 1 내지 30이며, Z는 직접 결합 또는 일반식 -CH2-, 또는의 브릿지 구성원이다.
  10. 반응성 희석제, 가용제 또는 접착제 강화제로서 에폭시 수시 배합물에서 제1항에 따른 일반식(Ⅰ) 내지 (Ⅳ)의 시클로헥실기 함유 글리시딜 에테르 또는 제8항 및 제9항에 따라 제조된 시클로헥실기 함유 글리시딜 에테르의 용도.
  11. 하기 일반식(Ⅰc),(Ⅱc),(Ⅲc) 또는 (Ⅳc)의 화합물 :
    상기 부호는 제8항에 정의된 바와 같다.
  12. 하기 일반식(Ⅰb1),(Ⅱb1),(Ⅲb1) 또는 (Ⅳb1)의 화합물 :
    상기 부호는 제9항에 정의된 바와 같다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930023984A 1992-11-11 1993-11-10 시클로헥실기 함유 글리시딜 에테르 KR100286593B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH348892 1992-11-11
CH92-4/3488 1992-11-11

Publications (2)

Publication Number Publication Date
KR940011420A true KR940011420A (ko) 1994-06-21
KR100286593B1 KR100286593B1 (ko) 2001-04-16

Family

ID=4257084

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930023984A KR100286593B1 (ko) 1992-11-11 1993-11-10 시클로헥실기 함유 글리시딜 에테르

Country Status (8)

Country Link
US (1) US5668227A (ko)
EP (1) EP0597806B1 (ko)
JP (1) JP3533577B2 (ko)
KR (1) KR100286593B1 (ko)
BR (1) BR9304678A (ko)
DE (1) DE59307934D1 (ko)
ES (1) ES2111732T3 (ko)
TW (1) TW289763B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103615259A (zh) * 2013-12-06 2014-03-05 中国矿业大学(北京) 锚网索-型钢支架耦合支护结构和支护方法

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6130344A (en) * 1997-11-27 2000-10-10 Mitsubishi Chemical Corporation Process for producing compound having epoxy group
JP3480552B2 (ja) * 1998-04-15 2003-12-22 ジャパンエポキシレジン株式会社 エポキシ樹脂組成物
EP1270633B1 (en) * 2001-06-25 2007-12-05 Mitsubishi Chemical Corporation Alicylic epoxy compounds and their preparation process, alicylic epoxy resin composition, and encapsulant for light-emitting diode
EP1359202A1 (de) * 2002-05-03 2003-11-05 Sika Schweiz AG Hitze-härtbare Epoxydharzzusammensetzung
EP1431325A1 (de) * 2002-12-17 2004-06-23 Sika Technology AG Hitze-härtbare Epoxidharzzusammensetzung mit verbesserter Tieftemperatur-Schlagzähigkeit
EP1498441A1 (de) * 2003-07-16 2005-01-19 Sika Technology AG Hitzehärtende Zusammensetzungen mit Tieftemperatur-Schlagzähigkeitsmodifikatoren
JP4779362B2 (ja) * 2005-01-06 2011-09-28 三菱化学株式会社 水素化エポキシ樹脂及びエポキシ樹脂組成物
EP1741734A1 (de) * 2005-07-05 2007-01-10 Sika Technology AG Tieftemperaturschlagzähe hitze-härtbare Epoxidharzzusammensetzung mit Epoxidfestharzen
EP1754721A1 (de) 2005-08-16 2007-02-21 Sika Technology AG Aminogruppen-terminierte Zähigkeitsverbesserer und deren Folgeprodukte und Verwendungen
EP1876194A1 (de) * 2006-06-30 2008-01-09 Sika Technology AG Hitzehärtende Zusammensetzung geeignet zum Verkleben von beschichteten Substraten
EP1916269A1 (de) * 2006-10-24 2008-04-30 Sika Technology AG Blockierte Polyurethanprepolymere und hitzehärtende Epoxidharzzusammensetzungen
EP1916285A1 (de) * 2006-10-24 2008-04-30 Sika Technology AG Derivatisiertes Epoxid-Festharz und dessen Verwendungen
EP1916270A1 (de) 2006-10-24 2008-04-30 Sika Technology AG Hitzehärtende Epoxidharzzusammensetzung mit blockiertem Polyurethanprepolymer
EP1916272A1 (de) 2006-10-24 2008-04-30 Sika Technology AG Hitzehärtende Epoxidharzzusammensetzung enthaltend ein blockiertes und ein epoxidterminiertes Polyurethanprepolymer
WO2008068205A1 (de) 2006-12-07 2008-06-12 Basf Se Epoxidharzzusammensetzungen und verfahren zu ihrer herstellung
EP1972646A1 (de) * 2007-03-20 2008-09-24 Sika Technology AG Epoxidgruppen terminierte Polymer, deren Zusammensetzungen und deren Verwendung als Schlagzähigkeitsmodifikatoren
ATE484547T1 (de) * 2008-01-30 2010-10-15 Sika Technology Ag Auswaschbeständige hitzehärtende epoxidharzklebstoffe
EP2110397A1 (de) 2008-04-16 2009-10-21 Sika Technology AG Auf amphiphilen Block-Copolymer basierendes Polyurethan-Polymer und dessen Verwendung als Schlagzähigkeitsmodifikator
DE502008000478D1 (de) 2008-07-17 2010-05-06 Sika Technology Ag Haftvermittlerverbindungen für beölten Stahl
EP2145924A1 (de) * 2008-07-18 2010-01-20 Sika Technology AG Auf amphiphilen Block-Copolymer basierende Reaktionsprodukte und deren Verwendung als Schlagzähigkeitsmodifikator
US8618321B2 (en) 2010-05-20 2013-12-31 Basf Se Derivatives of tris(2-hydroxyphenyl)methane, their preparation and use
MX341194B (es) * 2010-05-20 2016-08-11 Basf Se Derivados de tris (2-hidroxifenil) metanos, su preparacion y uso.
JP5402955B2 (ja) * 2011-02-01 2014-01-29 三菱化学株式会社 水素化エポキシ樹脂、その製造方法及びエポキシ樹脂組成物
WO2012111186A1 (ja) * 2011-02-15 2012-08-23 株式会社プリンテック 透明樹脂基板
MX360810B (es) 2011-10-18 2018-11-16 Wintershall Holding GmbH Uso de derivados de tris - (2 - hidroxifenil) metano para producción terciaria de petróleo.
US9428432B2 (en) 2011-11-24 2016-08-30 BASF Wintershall Holding GmbH Derivatives of tris(2-hydroxyphenyl)methanes, preparation thereof and use thereof for mineral oil production
EP2782666B1 (de) * 2011-11-24 2016-02-03 Wintershall Holding GmbH Derivate von tris(2-hydroxyphenyl)methanen, deren herstellung und verwendung für die erdölförderung
CN117285698A (zh) * 2015-03-26 2023-12-26 亨斯迈先进材料特许（瑞士）有限公司 用于制备室外制品的热固性环氧树脂组合物以及由此获得的制品

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2538072A (en) * 1947-06-11 1951-01-16 Devoe & Raynolds Co Epoxide preparation
US2883359A (en) * 1953-04-23 1959-04-21 Farbenfabriken Bayer Atkienges Synthetic products of high molecular weight
NL277165A (ko) * 1961-04-13
US3428713A (en) * 1964-06-15 1969-02-18 Du Pont Alkanol amine salts of phosphates
US3327016A (en) * 1964-07-09 1967-06-20 Epoxylite Corp Epoxide compositions cured with 1, 4-bis (aminomethyl) cyclohexane
US3535378A (en) 1966-10-03 1970-10-20 Mobay Chemical Corp Alkylene oxide adducts of methylcyclohexylene diamine
FR1539419A (fr) * 1966-10-03 1968-09-13 Mobay Chemical Corp Produits d'addition d'oxydes d'alcoylène sur la méthylcyclohexylène diamine
US4088614A (en) * 1973-06-26 1978-05-09 Dai-Ichi Kogyo Seiyaku Co., Ltd. Flame resistant polyurethane foam and process for producing the same
DE2528022A1 (de) * 1975-06-24 1977-01-20 Hoechst Ag Verfahren zur herstellung von polyglycidylaethern
JPS54141708A (en) * 1978-04-26 1979-11-05 Osaka Soda Co Ltd Preparation of glycidyl ether
JPS60131289A (ja) * 1983-12-20 1985-07-12 Toho Chem Ind Co Ltd 減感剤組成物
JPS62136658A (ja) * 1985-12-10 1987-06-19 Fuji Photo Film Co Ltd ハロゲン化銀写真感光材料の処理方法
DE3629632A1 (de) * 1986-08-30 1988-03-03 Basf Ag Verfahren zur herstellung von 2,2-di-(p-glycidoxi-cyclohexyl)-propan
US4767883A (en) * 1987-07-24 1988-08-30 Eastman Kodak Company Polymerizable cyclohexyleneoxyalkyl acrylates
JPH0772150B2 (ja) * 1990-07-18 1995-08-02 花王株式会社 α−（アルキルシクロヘキシルオキシ）−β−アルカノール類及びこれを含有する香料組成物
US5128491A (en) * 1991-07-30 1992-07-07 Ciba-Geigy Corporation Process for the preparation of glycidyl ethers of di-secondary alcohols with high monomer content
DE4139255A1 (de) * 1991-11-29 1993-06-03 Basf Ag Verfahren zur herstellung von diglycidyloligoethern
GB9200566D0 (en) * 1992-01-11 1992-03-11 Ciba Geigy Compounds

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103615259A (zh) * 2013-12-06 2014-03-05 中国矿业大学(北京) 锚网索-型钢支架耦合支护结构和支护方法

Also Published As

Publication number Publication date
BR9304678A (pt) 1994-05-17
ES2111732T3 (es) 1998-03-16
JPH06263676A (ja) 1994-09-20
KR100286593B1 (ko) 2001-04-16
JP3533577B2 (ja) 2004-05-31
DE59307934D1 (de) 1998-02-12
US5668227A (en) 1997-09-16
EP0597806A1 (de) 1994-05-18
TW289763B (ko) 1996-11-01
EP0597806B1 (de) 1998-01-07

Similar Documents

Publication Publication Date Title
KR940011420A (ko) 시클로헥실기 함유 글리시딜 에테르
US4533713A (en) Fluoroaliphaticsulfonamides containing oxirane groups and/or N-β-hydroxyalkylene groups
US4786668A (en) Resin materials
KR950032558A (ko) 자외선 흡수제로서의 벤즈아졸의 용도, 신규한 벤즈아졸 및 이의 제조방법
KR920002717A (ko) 분말 피복 조성물
JP5973401B2 (ja) グリシジルグリコールウリル類とその利用
US2925403A (en) New polyepoxides from epoxy-substi-tuted cycloaliphatic alcohols, their preparation and polymers
JPH05239181A (ja) 高モノマー分を有するジ−第二アルコールのグリシジルエーテルの製造方法
SG126709A1 (en) Process for producing modified polypropylene resin
KR850006395A (ko) 글리시딜 화합물의 제조방법
US3778439A (en) Binuclear n-heterocyclic polyglycidyl compounds
US3726895A (en) Diglycidyl derivatives of compounds containing two n-heterocyclic rings
US3489815A (en) Nitro-phenoxy compounds
JP2013151443A (ja) イソシアヌレート化合物
US3872097A (en) Binuclear N-heterocyclic N,N-diglycidyl compounds, processes for their manufacture and their use
US3686174A (en) Certain diglycidyl esters of n-heterocyclic compounds
KR850005428A (ko) 치환된 트리플루오로옥세탄의 제조방법
US5026810A (en) Vinyl ether siloxanes
CA2022814A1 (en) Modified polyarylene ether sulfones
US3849450A (en) Bis(trifluoromethyl)epoxides
KR830004322A (ko) 항알러지 및 항궤양제 1-옥소-1H-티아졸로 [3,2-a]피리미딘-2-카복사미드와 그의 중간물질
JP2013163653A (ja) オキセタン環を有するイソシアヌレート化合物
US3894038A (en) Hydroxyalkyl derivatives of alkylene-bis-hydantoins
KR980002161A (ko) 반응성 염료, 이의 제조방법 및 용도
US4895942A (en) Novel epoxy compounds

Legal Events

Date Code Title Description
N231 Notification of change of applicant
A201 Request for examination
E902 Notification of reason for refusal
N231 Notification of change of applicant
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20031231

Year of fee payment: 4

LAPS Lapse due to unpaid annual fee