KR940009639B1 - Manufacturing method and structure of highly integrated memory cell capacitor - Google Patents

Manufacturing method and structure of highly integrated memory cell capacitor Download PDF

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KR940009639B1
KR940009639B1 KR1019910022954A KR910022954A KR940009639B1 KR 940009639 B1 KR940009639 B1 KR 940009639B1 KR 1019910022954 A KR1019910022954 A KR 1019910022954A KR 910022954 A KR910022954 A KR 910022954A KR 940009639 B1 KR940009639 B1 KR 940009639B1
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polysilicon
bit line
groove
gate
node
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KR1019910022954A
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KR930014970A (en
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최주호
한석빈
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금성일렉트론 주식회사
문정환
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/01Manufacture or treatment
    • H10B12/02Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
    • H10B12/03Making the capacitor or connections thereto
    • H10B12/033Making the capacitor or connections thereto the capacitor extending over the transistor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/01Manufacture or treatment
    • H10B12/02Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
    • H10B12/03Making the capacitor or connections thereto
    • H10B12/036Making the capacitor or connections thereto the capacitor extending under the transistor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • H10B12/31DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells having a storage electrode stacked over the transistor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • H10B12/48Data lines or contacts therefor
    • H10B12/485Bit line contacts

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Semiconductor Memories (AREA)
  • Semiconductor Integrated Circuits (AREA)

Abstract

The high integration memory cell capacitor is disclosed in which a groove is formed on a bit line, a node polysilicon is formed on the right and left of the groove to be connected to a node polysilicon formed on the side of a pillar placed on the groove, and hemispherical grain polysilicon is formed on the right and left of the groove, thereby increasing the capacitance of the node capacitor.

Description

고집적 메모리 셀 캐패시터 제조방법 및 그 구조Manufacturing method and structure of high density memory cell capacitor

제 1 도는 종래의 메모리 셀 캐패시터 제조방법 및 구조도.1 is a method and structure diagram of a conventional memory cell capacitor manufacturing method.

제 2 도는 본 발명의 메모리 셀 캐패시터 제조방법 및 구조도.2 is a method and structure diagram of a memory cell capacitor manufacturing method of the present invention.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

21 : 실리콘 기판 22 : 게이트21 silicon substrate 22 gate

23 : 산화막 24 : 폴리실리콘23: oxide film 24: polysilicon

25 : 사이드 월 26 : 유전체막25 side wall 26 dielectric film

27 : 질화막 28 : 선택적 폴리실리콘27: nitride film 28: selective polysilicon

29 : 질화막 30 : 산화막29: nitride film 30: oxide film

31 : 노드용 폴리실리콘 32 : 유전체막31 polysilicon for node 32 dielectric film

33 : 플레이트33: Plate

본 발명은 고집적 메모리 셀 캐패시터 제조방법 및 구조에 관한 것으로 , 특히 게단형 게이트 구조위에 반구형상의 노드 캐패시터를 형성하며 필라 형성시 폴리실리콘 단층을 이용하여 노드 및 플레이트 캐패시터 용량을 증가시킨 캐패시터 제조방법 및 그 구조에 관한 것이다.The present invention relates to a method and a structure for manufacturing a highly integrated memory cell capacitor, and in particular, to form a hemispherical node capacitor on a gated gate structure and to increase the capacity of a node and plate capacitor using a polysilicon monolayer when forming a pillar, and a method thereof. It's about structure.

종래의 캐패시터 제조방법에 첨부된 도면 제 1 도를 참조하여 설명하면 다음과 같다.Referring to Figure 1 attached to a conventional capacitor manufacturing method as follows.

먼저, 제 1a 도와 같이, 실리콘 기판(1)에 워드라인으로 게이트(2)를 형성하고 산화막(3)을 입힌 후 사이드 월을 형성한다. 그후 제 1b 도와 같이 폴리실리콘(4) 및 텅스텐 실리사이드(5)를 형성하고 산화막(6)을 입힌 후 사이드월을 다시 형성한다. 계속해서 제1c 도와 같이, 질화막(7) 및 산화막(8)을 형성시키고 에칭하여 상기 텅스텐 실리사이드(5) 상부의 산화막(6)위에 필라를 형성한다. 이어서 제 1d 도와 같이, 노드캐패시터용 폴리실리콘(9)을 얇게 도포하고, 산화막(10)을 도포한 후 산화막(8)이 나타날 때까지 에치백한다. 그후 제 1e 도와 같이 상기 산화막(8)을 습식식각하여 제거하고, 제 1f 도와 같이, 유전체막(11)으로서 Ta2O3를 입히고 플레이트(12)로서 텅스텐을 데포지션하므로 캐패시터를 완성하게 된다.First, as shown in FIG. 1A, the gate 2 is formed on the silicon substrate 1 with a word line, the oxide film 3 is coated, and a sidewall is formed. Thereafter, polysilicon 4 and tungsten silicide 5 are formed as shown in FIG. 1B, the oxide film 6 is coated, and sidewalls are formed again. Subsequently, as in the 1c diagram, the nitride film 7 and the oxide film 8 are formed and etched to form pillars on the oxide film 6 above the tungsten silicide 5. Subsequently, as shown in the 1d diagram, the polysilicon 9 for the node capacitor is applied in a thin layer, the oxide film 10 is applied, and then etched back until the oxide film 8 appears. Thereafter, the oxide film 8 is wet-etched and removed as in the 1e chart, and Ta 2 O 3 is coated as the dielectric film 11 and tungsten is deposited as the plate 12, as in the 1f chart, thereby completing the capacitor.

이와같은 종래의 방식으로 제조된 캐패시터는 용량에 한계가 있으므로 고집적 셀에는 적합하지 못하다.Capacitors manufactured in this conventional manner are limited in capacity and therefore not suitable for highly integrated cells.

따라서 본 발명에서는 게이트 구조를 게단형으로 만들고, 그 위에 반구형상의 노드 캐패시터를 형성하며 필라를 형성하므로 캐패시터의 용량을 증가시키도록 하였다.Therefore, in the present invention, the gate structure is made into a cut-off type, a hemispherical node capacitor is formed thereon, and a pillar is formed thereon, thereby increasing the capacity of the capacitor.

이하 첨부된 도면 제 2 도를 참조하여 본 발명의 캐패시터 제조방법을 상술하면 다음과 같다.Hereinafter, a method of manufacturing a capacitor of the present invention will be described with reference to FIG. 2.

먼저 제 2a 도와 같이, 실리콘 기판(21)상에 게이트 산화막을 성장시킨 후 폴리실리콘을 도포하여 제1마스크로 게이트를 1차 패터닝하고 상기 제1 마스크보다 상대적으로 작은 제2마스크로 상기 게이트를 2차 패터닝하여 "ㅗ"자형 게이트(22)를 형성한다.First, as shown in FIG. 2A, a gate oxide film is grown on the silicon substrate 21, and then polysilicon is applied to first pattern the gate using a first mask, and the gate is formed using a second mask that is relatively smaller than the first mask. Differential patterning forms the " ㅗ " shaped gate 22. As shown in FIG.

이어서 제 2b 도와 같이, 기 형성된 게이트(22)위에 산화막(23)을 씌운 후 사이드 월을 형성한다. 계속해서 제 2c 도와 같이, 이온주입으로 소스/드레인을 형성하고 폴리실리콘(24)을 도포하여 비트라인을 형성하고 진동상태에서 약 500~600℃로 열처리하여 표면에 반구형상을 만든후, PR 마스크를 이용하여 게이트 상부의 소정 부위에서 상기 폴리실리콘(24)을 식각한다.Subsequently, as shown in FIG. 2B, an oxide film 23 is covered on the previously formed gate 22 to form sidewalls. Subsequently, as shown in FIG. 2C, a source / drain is formed by ion implantation, polysilicon 24 is applied to form a bit line, and heat treated at about 500 to 600 ° C. in a vibration state to form a hemispherical shape on the surface. Etch the polysilicon 24 at a predetermined portion of the upper portion of the gate using.

이어서 제 2d 도와 같이, 포토 공정으로 상기 비트라인 중앙부를 소정폭만큼 깍아 흠을 내고, PR을 벗겨낸 후 게이트 상의 비트라인 측면에 산화막 사이드 월(25)을 형성한다.Subsequently, as shown in FIG. 2D, the bit line center portion is scraped off by a photo process by a predetermined width, the PR film is peeled off, and an oxide film sidewall 25 is formed on the side of the bit line on the gate.

그후 제 2e 도와 같이, 비트라인을 유전체막(26)인 Ta2O5로 격리시킨 후, 질화막(27)을 도포한다. 계속해서 상기 질화막(27)을 포토에치하여 비트라인 상부의 홈 중앙에 기둥모양의 질화막을 형성하고, 상기 기둥 모양의 질화막 양편의 비트라인 홈을 선택적으로 폴리실리콘(28)으로 채운다. 이어서 제 2f 도와 같이, 질화막(29) 및 산화막(30)을 도포한 후 포토에치하여 상기 질화막(27)상에 질화막 및 산화막 기둥을 형성한다. 계속해서 제 2g 도와 같이, 노드용 폴리실리콘(31)을 도포하고, PR을 산화막(30)상의 노드 폴리실리콘 상부까지 도포한 후 에치백하여 산화막(39)을 제거한다. 이어서 제 2h 도와 같이, 전면에 유전체막(332)으로서 Ta2O5를 도포한 후 플레이트(33)용 텅스텐을 도포하여 캐패시터를 완성한다.Thereafter, as shown in FIG. 2E, the bit line is isolated by Ta 2 O 5 , which is the dielectric film 26, and the nitride film 27 is applied. Subsequently, the nitride film 27 is photoetched to form a columnar nitride film in the center of the upper groove of the bit line, and the bit line grooves on both sides of the columnar nitride film are selectively filled with polysilicon 28. Next, as shown in FIG. 2F, the nitride film 29 and the oxide film 30 are coated and then photoetched to form the nitride film and the oxide pillar on the nitride film 27. Subsequently, as in the second diagram, the polysilicon 31 for the node is applied, and PR is applied to the upper portion of the node polysilicon on the oxide film 30 and then etched back to remove the oxide film 39. Subsequently, as shown in FIG. 2h, Ta 2 O 5 is applied as the dielectric film 332 on the entire surface, and then tungsten for plate 33 is applied to complete the capacitor.

이와같이 제조되는 본 발명의 캐패시터 셀을, 게이트가 "ㅗ"자형으로 형성되어 있으며, 비트라인 상부에는 홈이 형성되고 이 홈의 중앙분리절연막을 제외한 좌우에는 노드 폴리실리콘이 형성되어 홈 상부의 기둥측면에 형성되는 노드 폴리실리콘과 연결되고 비트라인 홈 좌우 측면의 상부에는 반구형 폴리실리콘이 형성되어 있다.In the capacitor cell of the present invention manufactured as described above, the gate is formed in a “ㅗ” shape, a groove is formed in the upper part of the bit line, and node polysilicon is formed on the left and right sides of the groove except for the center separation insulating film. Hemispherical polysilicon is formed on top and left and right sides of the bit line grooves connected to the node polysilicon formed in the groove.

이와같은 제조방법 및 구조로 형성된 캐패시터를 사용하므로 다음과 같은 효과를 얻을 수 있다.Since the capacitor formed by the manufacturing method and structure as described above is used, the following effects can be obtained.

첫째, "ㅗ"자형 게이트 구조와 비트라인의 일부를 반구형 구조로 형성하므로 노드 폴리실리콘과 플레이트의 길이를 증가시켜서 캐패시터의 용량을 증가시킨다.First, since the "ㅗ" shaped gate structure and a part of the bit line are formed in a hemispherical structure, the capacity of the capacitor is increased by increasing the length of the node polysilicon and the plate.

둘째, 비트라인을 에치하여 홈을 형성한 후 질화막과 폴리실리콘을 이용하여 비트라인 위에 필라(Pillar)를 높이 올리지 않고도 노드 캐패시터의 용량을 증가시킬 수 있다.Second, after the groove is formed by etching the bit line, the capacity of the node capacitor may be increased without using a pillar on the bit line using a nitride film and polysilicon.

Claims (2)

고집적 메모리 셀 캐패시터 제조방법에 있어서, 실리콘 기판에 게이트 산화막을 성장시킨 후 게이트 폴리실리콘을 도포하여 제1마스크로 게이트를 1차 패터닝하고, 상기 제1마스크보다 상대적으로 작은 제2마스크로 1차 패터닝된 게이트를 2차 패터닝하여 "ㅗ"자형 게이트를 형성하는 단계(a)와, 게이트에 산화막 및 사이드 월을 형성하고 비트라인용 폴리실리콘을 도포한 후 진공 상태에서 소정의 온도로 열처리하므로 표면에 반구형상을 형성하는 단계(b)와, 비트라인용 폴리실리콘을 식각하여 비트라인을 형성한 후 비트라인 중앙부에서 소정의 폭만큼 깍아 홈을 내고 비트라인 측면에 산화막 사이드 월을 형성하는 단계(c)와, 노출된 비트라인에 유전체막을 형성하고, 비트라인에 형성된 홈 중앙에는 질화막을 형성하고, 홈대의 상기 질화막 좌우부에는 선택적 폴리실리콘을 성장시키는 단계(d)와, 상기 홈대의 질화막 상에 질화막 및 산화막 기둥을 형성하고 전면에 노드용 폴리실리콘을 도포하며, PR을 입혀 상기 산화막 기둥위의 노드용 폴리실리콘 및 산화막을 제거한 후 유전체막 및 플레이트를 도포하는 단계(e)를 포함하는 것을 특징으로 하는 고집적 메로리 셀 캐패시터 제조방법.In the method of manufacturing a highly integrated memory cell capacitor, a gate oxide film is grown on a silicon substrate, followed by applying a gate polysilicon to pattern the gate first with a first mask, and first patterning with a second mask relatively smaller than the first mask. Patterning the gate to form a "ㅗ" -shaped gate by secondary patterning, forming an oxide film and a sidewall on the gate, applying polysilicon for the bit line, and heat-treating at a predetermined temperature in a vacuum state, thereby (B) forming a hemispherical shape, and forming a bit line by etching polysilicon for the bit line, then cutting a groove by a predetermined width at the center of the bit line and forming an oxide sidewall on the side of the bit line (c). A dielectric film is formed in the exposed bit line, and a nitride film is formed in the center of the groove formed in the bit line. (D) growing a selective polysilicon, forming a nitride film and an oxide pillar on the nitride film of the groove, applying polysilicon for the node on the front surface, and applying PR to apply the polysilicon and oxide layer for the node on the oxide pillar And removing (e) the dielectric film and the plate after the removal. 고집적 메모리 셀 캐패시터 구조에 있어서, 게이트가 "ㅗ"자형으로 형성되고, 비트라인 상부에는 홈이 형성되고 이 홈의 중앙 분리 절연막을 제외한 좌우부분에는 노드 폴리실리콘이 형성되어 홈 상부의 기둥측면에 형성되는 노드 폴리실리콘과 연결되고, 비트라인 홈 좌우측면의 상부에는 반구형 폴리실리콘이 형성되는 것을 특징으로 하는 고집적 메모리 셀 캐패시터 구조.In the highly integrated memory cell capacitor structure, a gate is formed in a “ㅗ” shape, a groove is formed in the upper part of the bit line, and node polysilicon is formed in the left and right portions except for the center isolation insulating film of the groove and is formed on the pillar side of the upper part of the groove. The high density memory cell capacitor structure is connected to the node polysilicon is formed, hemispherical polysilicon is formed on the upper left and right sides of the bit line groove.
KR1019910022954A 1991-12-13 1991-12-13 Manufacturing method and structure of highly integrated memory cell capacitor KR940009639B1 (en)

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KR940009639B1 true KR940009639B1 (en) 1994-10-15

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