KR940003612A - 촉매 담체 - Google Patents

촉매 담체 Download PDF

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Publication number
KR940003612A
KR940003612A KR1019930016965A KR930016965A KR940003612A KR 940003612 A KR940003612 A KR 940003612A KR 1019930016965 A KR1019930016965 A KR 1019930016965A KR 930016965 A KR930016965 A KR 930016965A KR 940003612 A KR940003612 A KR 940003612A
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KR
South Korea
Prior art keywords
catalyst carrier
weight
less
absolute gas
gas channel
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KR1019930016965A
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English (en)
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KR100254868B1 (ko
Inventor
비.코라디아 프라모드
엠.도대토 카민
씨.셔먼 다니엘
에이치.거디스 윌리엄
Original Assignee
제임스 제이.조이스 2세
노튼 케미칼 프로쎄스 프로덕츠 코포레이션
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Publication of KR940003612A publication Critical patent/KR940003612A/ko
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Publication of KR100254868B1 publication Critical patent/KR100254868B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

순도가 95%이상인 알파 알루미나를 90중량%이상 포함하는 다공성 담체 물질은 엔진 배기물을 처리하는 촉매용 지지체로서 매우 효과적이고 통상적인 지지체보다 현저히 우수하게 극한 조건을 견뎌낼 수 있다.

Description

촉매 담체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 순도가 95%이상인 90중량%이상의 α-알루미나와 약 10중량%이하의 산소 촉진제를 포함하고, 다공도가 약0.2내지 약0.6㎤/담체g이고, 표면적이 약0.2내지 약10㎡/담체g이며, 평균 공극 크기가 약 0.1내지 약0.1내지 약100μ인 촉매 담체.
  2. 제1항에 있어서, 존재하는 실리게이트와 알루미노실리게이트의 양이 2중량%미만인 촉매 담체.
  3. 제1항에 있어서, 산소 촉진제가 약1내지 약 5중량%의 양으로 존재하는 촉매 담체.
  4. 제7항에 있어서, 산소 촉진제가 세륨, 몰리브레늄, 비나듐, 망간, 크로뮴, 티타늄, 란타늄, 니오븀, 지르코니아 및 희토류 금속으로 이루어진 그룹 중에서 선택되는 금속인 촉매 담체.
  5. 제1항에 있어서, 절대적 가스 채널을 갖는 단일체 형태인 촉매 담체.
  6. 제5항에 있어서, 구조중의 개방 셀 밀도가 약 100내지 약 400ce11/in2인 촉매 담체.
  7. 제5항에 있어서, 단일체가 절대적 가스 채널을 갖는 개방 정면을 포함하고 채널이 개방 정면의 약 25%를 구성하는 촉매 담체.
  8. 제5항에 있어서, 절대적 가스 채널의 최소 단면 직경이 약 l㎜이상인 촉매 담체.
  9. 제5항에 있어서, 인접한 절대적 가스 채널 사이의 벽 두께가 5㎜미만인 촉매 담체.
  10. 제5항에 있어서, 단일체의 평균 측면 및 정면 파열 강도가 20lb이상인 촉매 담체.
  11. 제1항에 있어서, 필형 입자 형태인 촉매 담체.
  12. 제11항에 있어서, 마모 손실률이 25%/h미만인 촉매 담체.
  13. 절대적 가스 채널을 갖고 75중량%이상의 α-알루미나, 1내지 5중량%의 산소 촉진제(이때, 산소 촉진제는 회토류 금속과 주기율표의 IVA, VA, VIA및 VⅡA족의 금속의 산화물중에서 선택된 산화물이다)및 2%미만의 실리케이트 및/또는 알루미노실리게이트 불순물을 포함하며, 다공도가 0.3내지 0.5㎤/담체g이고, 표면적이고 약 0.3내지 약4㎡/담체g이며, 평균 공극 크기가 약 0.2내지 약 5μ인 단일체 형태의 촉매 담체.
  14. 제13항에 있어서, 절대적 가스 채널이 개방 정면의 약 40%이상을 차지하는 촉매 담체.
  15. 제13항에 있어서, 개방 셀 밀도가 약200내지 약400ce11/in2이고 인접한 절대적 가스 채널 사이의 벽 두께가 약 3㎜미만인 촉매 담체.
  16. 제13항에 있어서, 알루미나 성분이 98%이상의 α-알루미나인 촉매 담체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930016965A 1992-08-31 1993-08-30 촉매 담체 KR100254868B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US7/937,257 1992-08-31
US07/937,257 US5266548A (en) 1992-08-31 1992-08-31 Catalyst carrier

Publications (2)

Publication Number Publication Date
KR940003612A true KR940003612A (ko) 1994-03-12
KR100254868B1 KR100254868B1 (ko) 2000-05-01

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US (1) US5266548A (ko)
EP (1) EP0585879B1 (ko)
JP (1) JPH06154599A (ko)
KR (1) KR100254868B1 (ko)
CN (1) CN1050530C (ko)
AU (1) AU655114B2 (ko)
CA (1) CA2101955C (ko)
DE (1) DE69324201T2 (ko)
ES (1) ES2129056T3 (ko)
RU (1) RU2111789C1 (ko)

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Also Published As

Publication number Publication date
CA2101955C (en) 1998-02-24
DE69324201D1 (de) 1999-05-06
EP0585879A1 (en) 1994-03-09
CN1050530C (zh) 2000-03-22
AU4442493A (en) 1994-03-10
KR100254868B1 (ko) 2000-05-01
CN1084102A (zh) 1994-03-23
US5266548A (en) 1993-11-30
EP0585879B1 (en) 1999-03-31
AU655114B2 (en) 1994-12-01
DE69324201T2 (de) 1999-11-25
ES2129056T3 (es) 1999-06-01
RU2111789C1 (ru) 1998-05-27
JPH06154599A (ja) 1994-06-03
CA2101955A1 (en) 1994-03-01

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