GB1474958A - Sulphur oxide removal from gases - Google Patents

Sulphur oxide removal from gases

Info

Publication number
GB1474958A
GB1474958A GB3304674A GB3304674A GB1474958A GB 1474958 A GB1474958 A GB 1474958A GB 3304674 A GB3304674 A GB 3304674A GB 3304674 A GB3304674 A GB 3304674A GB 1474958 A GB1474958 A GB 1474958A
Authority
GB
United Kingdom
Prior art keywords
substrate
surface area
film
tio
contacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3304674A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1474958A publication Critical patent/GB1474958A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)

Abstract

1474958 Removing sulphur oxides; alumina EXXON RESEARCH & ENG CO 26 July 1974 [23 Aug 1973] 33046/74 Heading C1A Sulphur oxides are removed from a gas mixture by contacting the gas with a solid comprising (a) a low surface area refractory substrate and (b) an outer layer deposited on the substrate comprising an adherent adsorptive refractory metal oxide film having a surface area greater than the surface area of the substrate and a transition metal or transition metal oxide. The substrate may be shaped, e.g. sphere, saddle, honeycomb, with a surface area of 1-3 m.<SP>2</SP>/g. (N 2 adsorption, BET). The film surface area is preferably at least 75 m.<SP>2</SP>/g. The substrate may be Al 2 O 3 , TiO 2 , porcelain, clays or a metal, e.g. Ti or steel wire. The adherent film may be a catalyst carrier, e.g. Al 2 O 3 , TiO 2 , ZrO 2 0À001- 0À01 inch thick, and formed by contacting the substrate with metal alkoxide or alkyl, and calcining. The film then be impregnated with a solution of a decomposable compound of the active material. Alternatively, oxide film and active material may be co-precipitated. CuO is a preferred sorbent, which may be regenerated with H 2 /steam at desulphurization temperatures.
GB3304674A 1973-08-23 1974-07-26 Sulphur oxide removal from gases Expired GB1474958A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US39091973A 1973-08-23 1973-08-23

Publications (1)

Publication Number Publication Date
GB1474958A true GB1474958A (en) 1977-05-25

Family

ID=23544498

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3304674A Expired GB1474958A (en) 1973-08-23 1974-07-26 Sulphur oxide removal from gases

Country Status (3)

Country Link
JP (1) JPS5051091A (en)
DE (1) DE2439234C2 (en)
GB (1) GB1474958A (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2340763A1 (en) * 1976-02-12 1977-09-09 Hitachi Ltd PROCESS FOR TREATING AN EXHAUST GAS CONTAINING SULFUR OXIDES
JPS5317591A (en) * 1976-08-02 1978-02-17 Hitachi Ltd Treating method for exhaust gas containing sulfur oxides
US4164544A (en) * 1976-08-27 1979-08-14 United States Steel Corporation Desulfurization of hot reducing gas
DE3443721A1 (en) * 1984-11-30 1986-06-05 Förster, Günther, Dipl.-Ing., 6300 Gießen Fluidized bed reactor for the thermal removal of waste
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
BRPI0911996B8 (en) 2008-05-15 2018-03-20 Shell Int Research process for the production of an alkylene carbonate and / or an alkylene glycol, and process for the production of an alkylene glycol
US8193374B2 (en) 2008-05-15 2012-06-05 Shell Oil Company Process for the preparation of alkylene carbonate and/or alkylene glycol

Also Published As

Publication number Publication date
DE2439234A1 (en) 1975-02-27
DE2439234C2 (en) 1983-11-03
JPS5051091A (en) 1975-05-07

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee