KR930701502A - 폴리프로필렌계 수지 및 그의 조성물 - Google Patents

폴리프로필렌계 수지 및 그의 조성물

Info

Publication number
KR930701502A
KR930701502A KR1019930700586A KR930700586A KR930701502A KR 930701502 A KR930701502 A KR 930701502A KR 1019930700586 A KR1019930700586 A KR 1019930700586A KR 930700586 A KR930700586 A KR 930700586A KR 930701502 A KR930701502 A KR 930701502A
Authority
KR
South Korea
Prior art keywords
less
polypropylene resin
peak
nmr
propylene
Prior art date
Application number
KR1019930700586A
Other languages
English (en)
Other versions
KR970009997B1 (ko
Inventor
아키라 타나카
마사루 나카가와
히데오 쿠스야마
스에토 미야자키
타쯔야 다카라자키
Original Assignee
혼고우 무쓰미
이데미쯔 세끼유 가가꾸 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27553541&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR930701502(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from JP3183257A external-priority patent/JP2534414B2/ja
Priority claimed from JP3183630A external-priority patent/JPH059219A/ja
Priority claimed from JP3183631A external-priority patent/JPH0532723A/ja
Priority claimed from JP3183629A external-priority patent/JP2534415B2/ja
Priority claimed from JP3183633A external-priority patent/JP2521381B2/ja
Priority claimed from JP3183634A external-priority patent/JP2521382B2/ja
Application filed by 혼고우 무쓰미, 이데미쯔 세끼유 가가꾸 가부시끼가이샤 filed Critical 혼고우 무쓰미
Publication of KR930701502A publication Critical patent/KR930701502A/ko
Application granted granted Critical
Publication of KR970009997B1 publication Critical patent/KR970009997B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

하기 특성을 갖는 폴리프로필렌계 수지로서 매우 높은 강성, 내열성 및 내충격성을 갖는 것과 함께 이들의 밸런스가 우수한 폴리프로필렌 수지 및 그 조성물을 제공한다.
① 프로필렌 이외의 α-올레핀 단위의 함유량이 4m o 1%이하로서, 하기 특성 ②, ③ 및 ④, ②13C-NMR로 측정한 펜탓드 분율에서 mmmm분율이 96.0%이상, ③ 승온 분별법에서의 주용출피크의 위치(Tmax)가 118.0℃이상이며, 또 그 퍼크의 반치폭(σ)가 4.0도 미만, ④ 극한점도(n)가 0.5㎗/g이상 0.5㎗/g이하를 갖는 프로필렌 중합체를 포함, 또, ⑤ 펄스 NMR로 측정한 고무성분량이 25%를 초과하는 것.

Description

폴리프로필렌계 수지 및 그의 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 승온 분별법에 의한 주용출피크 위치(Tmax) 및 퍼크의 반치폭(σ)를 나타낸 분석 차트이다.
제2도는 고무 성분량과 아이조드(Izod)충격강도의 관계를 나타내는 그래프이다.

Claims (9)

  1. ① 프로필렌 이외의 α-올레핀 단위의 함유량이 4m o 1%이하이며, 또 하기 특성 ②, ③ 및 ④를 갖는 프로필렌 중합체를 포함하는 것 ② :13C-NMR로 측정한 펜탓드 분율에서 mmmm분율이 96.0%이상 ③ : 승온 분별법에서의 주용출퍼크의 위치(Tmax)가 118.0℃이상이며, 또 그 피크의 반치폭(σ)가 4.0도 미만 ④ 극한점도(n)가 0.5㎗/g이상, 5.0㎗/g이하; 및 ⑤ 펄스 NMR로 측정한 고무성분량이 25%를 초과하는 것을 특징으로하는 폴리프로필렌계 수지.
  2. ① 프로필렌 이외의 α-올레핀 단위의 함유량이 4m o 1%이하로서, 또 하기 특성 ②, ③ 및 ④를 갖는 프로필렌중합체를 함유하는 것 ② :13C-NMR로 측정한 펜탓드 분율에서 mmmm분율이 96.0%이상 ③ :승온 분별법에서의 주용출피크의 위치(Tmax)가 117.0℃이상이며, 또 그 피크의 반치폭(σ)가 7.0도 미만 ④ :극한점도(n)가2.0㎗/g이상, 5.0㎗/g이하; 및 ⑤ 펄스 NMR로 측정한 고무성분량이 8%이상인 것을 특징으로 하는 폴리프로필렌계 수지.
  3. ① 프로필렌 이외의 α-올레핀 단위의 함유량이 4m o 1%이하로서 또, 하기 특성 ②, ③ 및 ④를 갖는 프로필렌중합체를 함유하는 것 ② :13C-NMR로 측정한 펜탓드 분율에서 mmmm분율이 96.0%이상 ③ 승온분별법에서의 주용출 퍼크의 위치(Tmax)가 118.0℃이상이며, 또 그 퍼크의 반치폭(σ)가 3.4도 미만 ④ 극한점도(n)가 0.5㎗/g이상, 2.0㎗/g이하; 및 ⑤ 극도[n]가 3.0㎗/g이상인 프로필렌 공중합체를 포함하는 것을 특징으로 하는 폴리프로필렌게 수지.
  4. 하기 특성 ①, ② 및 ③을 갖는 프로필렌 중합체를 함유하는 것을 특징으로 하는 폴리프로필렌 수지. ①13C-NMR로 측정한 펜탓드 분율에서 mmmm분율이 96.0%이상 ② 승온 분별법에서의 주용출 피크의 위치(Tmax)가 118.0℃이상이며, 또 그 피크의 반치폭(σ)가 3.4도 미만 ③ 용융정 탄성측정에서 저장탄성율(G')가 2×105dyn/㎠로 되도록 각주파수를 Wl,2×103dyn/㎠로 되도록 각 주파수를 W2로 할 때에 하기식으로 나타내는 분자량분포지표(PDi)의 값이 15이하 PDi=W2/Wl
  5. 하기 특성 ①, ② 및 ③을 갖는 프로필렌 단독중합체로 이루어진 것을 특징으로 하는 폴리프로필렌 수지. ①13C-NMR로 측정한 펜탓드 분율에서 mmmm분율이 96.0%이상 ② 승온 분별법에서의 주용출피크의 위치(Tmax)가 118.0℃이상이며, 또 그 피크의 반치폭(σ)가 3.4도 미만 ③ 멜트 인텍스가 0.O1g/10분이상, 200g/10분이하.
  6. 하기 특성 ①, ②, ③ 및 ④를 갖는 프로필렌 단독중합체로 이루어진 것을 특징으로 하는 폴리프로필렌수지. ①13C-NMR로 측정한 펜탓드 분율에서 mumm분율이 96.0%이상 ② 승온 분별법에서의 주용출퍼크의 위치(Tmax)가 117.0℃이상이며, 또 그 피크의 반치폭(σ)가 4,0도 미만 ③ 멜트 인텍스가 0.01g/10분이상. 3.0g/10분이하 ④ 230℃로 측정한 용융장력(T)와 MI의 관계가 T≥-5.2 logMI+3.0.
  7. 프로필렌 단독중합체의 중합이 실질적으로 일단계로 행해지는 것인 청구항 1∼청구항 6의 어느 1항에 기재의 폴리프로필렌 수지.
  8. 청구항 1∼청구항 6의 어느 1항의 기재의 폴리프로필렌 수지를 함유하는 것을 특징으로 하는 폴리프로필렌 수지조성물.
  9. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930700586A 1991-06-27 1993-02-26 폴리프로필렌계 수지 및 그의 조성물 KR970009997B1 (ko)

Applications Claiming Priority (14)

Application Number Priority Date Filing Date Title
JP91-183256 1991-06-27
JP3183257A JP2534414B2 (ja) 1991-06-27 1991-06-27 ポリプロピレン系樹脂
JP91-183257 1991-06-27
JP3183630A JPH059219A (ja) 1991-06-28 1991-06-28 ポリプロピレン系樹脂及びその組成物
JP91-183629 1991-06-28
JP91-183633 1991-06-28
JP3183631A JPH0532723A (ja) 1991-06-28 1991-06-28 ポリプロピレン樹脂及びその組成物
JP3183629A JP2534415B2 (ja) 1991-06-28 1991-06-28 ポリプロピレン系樹脂
JP91-183634 1991-06-28
JP3183633A JP2521381B2 (ja) 1991-06-28 1991-06-28 ポリプロピレン樹脂
JP3183634A JP2521382B2 (ja) 1991-06-28 1991-06-28 ポリプロピレン樹脂
JP91-183630 1991-06-28
JP91-183631 1991-06-28
PCT/JP1992/000807 WO1993000375A1 (fr) 1991-06-27 1992-06-25 Resine polypropylene et composition

Publications (2)

Publication Number Publication Date
KR930701502A true KR930701502A (ko) 1993-06-11
KR970009997B1 KR970009997B1 (ko) 1997-06-20

Family

ID=27553541

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930700586A KR970009997B1 (ko) 1991-06-27 1993-02-26 폴리프로필렌계 수지 및 그의 조성물

Country Status (8)

Country Link
US (1) US5332789A (ko)
EP (1) EP0546191B1 (ko)
KR (1) KR970009997B1 (ko)
AU (1) AU649872B2 (ko)
CA (1) CA2089818C (ko)
DE (1) DE69222005T2 (ko)
ES (1) ES2106873T3 (ko)
WO (1) WO1993000375A1 (ko)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4317655A1 (de) * 1993-05-27 1994-12-01 Basf Ag Mehrphasige Blockcopolymerisate des Propylens
CA2125246C (en) * 1993-06-07 2001-07-03 Junichi Imuta Transition metal compound and olefin polymerization catalyst using the same
CA2125247C (en) * 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
US5432009A (en) * 1993-06-17 1995-07-11 Sekisui Kagaku Kogyo Kabushiki Kaisha Film for first-aid sticking plaster
CA2128920C (en) * 1993-07-28 1999-06-01 Akihiko Yamamoto Propylene polymer compositions
JP2839840B2 (ja) * 1994-08-19 1998-12-16 昭和電工株式会社 プロピレン樹脂組成物
AU693917B2 (en) * 1994-09-08 1998-07-09 Showa Denko Kabushiki Kaisha Propylene block copolymer, process for producing the same and resin composition comprising the same
KR100430512B1 (ko) * 1995-08-31 2004-07-23 도요다 지도샤 가부시끼가이샤 프로필렌-에틸렌공중합체조성물및이의제조방법
JP3260268B2 (ja) * 1995-12-18 2002-02-25 宇部興産株式会社 ポリプロピレン系樹脂組成物
DE19726796A1 (de) 1997-06-24 1999-01-07 Basf Ag Propylenpolymerisate
JP2000313777A (ja) * 1999-04-28 2000-11-14 Idemitsu Petrochem Co Ltd プロピレン系共重合体及び該共重合体を成形してなる成形体
EP1094083A3 (en) * 1999-10-19 2001-12-12 Idemitsu Petrochemical Co., Ltd. Catalyst for olefin polymerization, method for producing olefin polymer, and olefin polymer
DE60208177T2 (de) * 2001-03-29 2006-08-17 Idemitsu Kosan Co. Ltd. Propylenpolymerzusammensetzung, formkörper und polyolefincopolymer
TWI295963B (ko) * 2001-05-11 2008-04-21 Toray Industries
JP2003226791A (ja) * 2002-02-04 2003-08-12 Idemitsu Petrochem Co Ltd ポリプロピレン系複合樹脂組成物
JP7023164B2 (ja) 2017-04-14 2022-02-21 住友化学株式会社 プロピレン樹脂組成物及び成形体
CN112745583B (zh) * 2019-10-30 2022-07-29 中国石油化工股份有限公司 高光泽抗冲聚丙烯组合物及其制备方法
CN112745581B (zh) * 2019-10-30 2022-07-26 中国石油化工股份有限公司 一种高流动高结晶抗冲聚丙烯材料及其制备方法
CN112745582B (zh) * 2019-10-30 2022-07-26 中国石油化工股份有限公司 一种超高抗冲聚丙烯材料及其制备方法
CN112745580B (zh) * 2019-10-30 2022-09-09 中国石油化工股份有限公司 一种高流动高抗冲耐高温的聚丙烯材料及其制备方法和应用

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58138721A (ja) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd プロピレンランダム共重合体
JPS58201806A (ja) * 1982-05-19 1983-11-24 Chisso Corp 後加工シ−ト用および吹込成形用高溶融粘弾性ポリプロピレンとその製造法
JPS5922913A (ja) * 1982-07-15 1984-02-06 Chisso Corp 高剛性成形品用ポリプロピレン樹脂
JPH0699532B2 (ja) * 1982-12-17 1994-12-07 三井東圧化学株式会社 高光沢射出成形体
JPS59122506A (ja) * 1982-12-28 1984-07-16 Sumitomo Chem Co Ltd 軟質プロピレン重合体
JPS59172507A (ja) * 1983-03-23 1984-09-29 Mitsui Petrochem Ind Ltd ポリプロピレンの製造方法
JPH075668B2 (ja) * 1987-02-04 1995-01-25 チッソ株式会社 高結晶性ポリプロピレン
AU620356B2 (en) * 1987-11-25 1992-02-20 Shell Oil Company Ultra high melt flow rate propylene polymers
JPH0233047A (ja) * 1988-07-21 1990-02-02 Nec Corp 用紙搬送機構
DE68922698T2 (de) * 1988-11-04 1995-11-09 Sumitomo Chemical Co Kristallines Polypropylen und daraus gefertigte Zusammensetzungen.
US5077341A (en) * 1989-06-19 1991-12-31 Chisso Corporation Process for producing a high-stiffness polypropylene and a highly stereoregular polypropylene
JPH0330605A (ja) * 1989-06-29 1991-02-08 Suzutec Co Ltd 野菜用ポツトシート播種装置
FR2649708B1 (fr) * 1989-07-17 1991-10-25 Bp Chem Int Ltd Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite
EP0850990A1 (en) * 1989-11-28 1998-07-01 Idemitsu Petrochemical Co., Ltd. Flexible polypropylene resins, propylene based elastomer compositions and process for production of olefin polymers
AU658581B2 (en) * 1990-10-09 1995-04-27 Qenos Pty Ltd Propylene polymers

Also Published As

Publication number Publication date
CA2089818A1 (en) 1992-12-28
KR970009997B1 (ko) 1997-06-20
EP0546191B1 (en) 1997-09-03
AU2166692A (en) 1993-01-25
DE69222005T2 (de) 1998-03-26
EP0546191A4 (en) 1994-11-09
ES2106873T3 (es) 1997-11-16
DE69222005D1 (de) 1997-10-09
CA2089818C (en) 1996-01-30
EP0546191A1 (en) 1993-06-16
WO1993000375A1 (fr) 1993-01-07
US5332789A (en) 1994-07-26
AU649872B2 (en) 1994-06-02

Similar Documents

Publication Publication Date Title
KR930701502A (ko) 폴리프로필렌계 수지 및 그의 조성물
CA2178742A1 (en) Novel Resin Composition
AU667410B2 (en) Polypropylene compositions having good transparency and improved impact resistance
ATE424435T1 (de) Polyolefinische zusammensetzungen mit hoher bleichungsresistenz
EP0831125A4 (en) THERMOPLASTIC RESIN COMPOSITION AND INJECTION MOLDING OBTAINED FROM IT
DK0411627T3 (da) Polymersammensætning i form af sfæroidiske partikler
TW357177B (en) Composition of irradiated and non-irradiated olefin polymer materials with reduced gloss
CN112538215B (zh) 一种抗冲击、耐低温高透明聚丙烯组合物
CA2222076A1 (en) Polypropylene resin compositions
EP0273228A2 (en) Polypropylene composition
KR940007121A (ko) 비튜멘 및 비튜멘의 개질용으로 적당한 중합체 조성물의 혼합물
KR910020089A (ko) 폴리프로필렌 내충격성 공중합체 조성물
MY143053A (en) Polypropylene-based resins and polypropylene-based resin compositions
KR900004829A (ko) 플라스토엘라스토머 폴리올레핀계 조성물 및 다이나믹가황법에 의한 이들의 제법
KR950018227A (ko) 폴리프로필렌수지조성물
CA2183694A1 (en) Resin composition and molded article of the same
JPS6454010A (en) Random ethylene copolymer and its use
MY121010A (en) Polycarbonate resin composition
AU661317B2 (en) Polyacetal resin composition
EP1081189A4 (en) PROPYLENE RESIN COMPOSITION AND AUTOMOTIVE INTERIOR PARTS THAT CONTAIN
US4319005A (en) Ternary thermoplastic molding composition containing polypropylene copolymers
KR920002703A (ko) 폴리(아릴렌 설피드)성형 조성물
KR950703612A (ko) 폴리아미드 수지 조성물
Seefried Jr et al. Thermoplastic urethane elastomers V. Compatible and incompatible blends with various polymers
US4319001A (en) Ternary thermoplastic molding composition containing ethylene-propylene copolymer

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20051025

Year of fee payment: 9

LAPS Lapse due to unpaid annual fee