KR930023061A - 가역적 산소 흡착 조성물 - Google Patents

가역적 산소 흡착 조성물 Download PDF

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KR930023061A
KR930023061A KR1019930009143A KR930009143A KR930023061A KR 930023061 A KR930023061 A KR 930023061A KR 1019930009143 A KR1019930009143 A KR 1019930009143A KR 930009143 A KR930009143 A KR 930009143A KR 930023061 A KR930023061 A KR 930023061A
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metal atom
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람프라사드 도라이
피터 페즈 귀도
마틴 펄슈타인 로날드
크리스틴 메이어 잉그리드
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윌리암 에프. 마쉬
에어 프로덕츠 앤드 케미칼스, 인코오포레이티드
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    • B01J20/30—Processes for preparing, regenerating, or reactivating
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
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Abstract

본 발명은 하기 일반식으로 표현되는 고 용량의 고형상태 시아노코발테이트 착물에 관한 것이다;
[(A)a(R4N)b]z+x/z[Co(CN)n]x-ㆍpS
상기식중, A는 알칼리금속원자, 알칼리 토금속원자, Zn, Cd 또는 Hg원자이고; a는 0내지 2.5내의 임의의 수이고, R은 각각 C,-Cle의 치환 또는 비치환된 알킬, 아릴 또는 아르알킬; 또는 장쇄 탄화수소 중합체이고; b는 0이상 3이하의 임의의 수이고; x는 n-2이고; P는 0 이상 내지 6이하의 임의의 수이며 ; S는[ (A)a(R4N)b]z+ㆍCo또는 이것들 모두와 배위결합될 수 있는 리간드이다.
상기 착물은 산소와 화학적으로 결합하여 신규 산소 첨가생성물을 형성할 수 있고, 이로써 산소-함유 유체스트림으로 부터 산소를 선택적으로 제거할 수 있다. 부가생성물상에서 온도를 상승시키거나 또는 O2의 분압을 저하시킴으로써 착물로 부터 결합산소를 회수할 수 있다.

Description

가역적 산소 흡착 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 하기 일반식으로 표시되는 하나 또는 그이상의 시아노코발테이트 착물을 포함하는 고형상태의 조성물 :
    [(A)a(R4N)b]z+x/z[Co(CN)n]x-. pS
    상기식중, A는알칼리 금속원자, 알칼리 토금속원자, Zn, Cd 또는 Hg원자이고; a는 0 내지 2.5이내의 임의의 수이고; R은 각각 C1-C10의 치환 또는 비치환된 알킬, 아릴 또는 아르알킬; 또는 장쇄 탄화수소 중합체이고; b는 0이상 3이하의 임의의 수이고; Z는 1, 2 또는 3이고; n은 3 내지 5의 임의의 수이고; x는 n-2이고; p는 0 이상 6이하의 임의의 수이며; S는 [(A)a(R4N)b]z+, Co또는 이것들 모두와 배위결합될 수 있는 리간드이다.
  2. 제1항에 있어서, S가 N, N-디알킬 아미드, 알킬 락탐, N-알킬 아미드, 암모니아, 아세톤, 킬레이트화 3차아민, N-헤테로고리, 비피리딜 및 치환된 디피리딜, 피라진, 유기 니트릴, 폴리비닐 피리딘 또는 피론리돈을 포함한 중합체, 시안아미드 옴이온, 디시안아미드 음이온, 디시아노메탄 음이온, 할라이드 이온, SCN-, NCS, 및 이들의 혼합물로 이루어진 군중에서 선택되는 조성물.
  3. 제1항에 있어서, S가 유기 아미드인 조성물.
  4. 제3항에 있어서, S가 N, N-디메틸포름아미드, N-메틸-2-피롤리디논, N,N-디메틸아세트아미드 및 이들의 혼합물로 이루어진 군중에서 선택되는 조성물.
  5. 제4항에 있어서, p가 2 내지 3이내인 조성물.
  6. 제1항에 있어서, n이 5인 조성물.
  7. 제1항에 있어서, R이 부틸기인 조성물.
  8. 제1항에 있어서, R이 에틸기인 조성물.
  9. 제1항에 있어서, “a”가 0인 조성물.
  10. 제9항에 있어서, R이 에틸기, 부틸기, 또는 벤질기인 조성물.
  11. 제9항에 있어서, S가 4,4'-디피리딜인 조성물.
  12. 제1항에 있어서, A가 Li인 조성물.
  13. 제1항에 있어서, A가 Na인 조성물.
  14. 제1항에 있어서, S가 아세톤인 조성물.
  15. 산소 및 하나이상의 다른 성분을 함유한 유체 트림을 제1항의 고형상태의 시 아노코발테이트 착물과 접촉시켜 상기 착물이 산소와 선택적으로 결합함으로서 유체 스트림으로 부터 산소를 제거하는 것을 특징으로 하는, 상기 유체로부터 산소를 제거하는 방법.
  16. 제15항에 있어서, 산소 및 질소를 함유한 기류로 부터 산소를 선택적으로 제거하는 방법.
  17. 제15항에 있어서, 아르곤 및 미량의 산소를 함유한 기류로 부터 산소를 선택적으로 제거하는 방법.
  18. 제15항에 있어서. 압력 순환식 흡착방법인 방법.
  19. 제15항에 있어서, 온도 순환식 흡착방법인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930009143A 1992-05-27 1993-05-26 가역적 산소 흡착 조성물 KR960003229B1 (ko)

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US07/890,065 1992-05-27
US07/890,065 US5208335A (en) 1991-03-19 1992-05-27 Reversible oxygen sorbent compositions

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JP (1) JPH06182198A (ko)
KR (1) KR960003229B1 (ko)
BR (1) BR9302050A (ko)
CA (1) CA2097521A1 (ko)
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DE69303771D1 (de) 1996-08-29
EP0571952A1 (en) 1993-12-01
TW250440B (ko) 1995-07-01
BR9302050A (pt) 1993-11-30
CA2097521A1 (en) 1993-11-28
DE69303771T2 (de) 1996-12-12
KR960003229B1 (ko) 1996-03-07
EP0571952B1 (en) 1996-07-24
US5208335A (en) 1993-05-04

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