KR930019229A - 블록 공중합체, 이로 부터 제조된 생체흡수성 필름 또는 망, 및 수술용 봉합선 또는 봉합사, 및 상기 필름 또는 망의 살균 방법 - Google Patents
블록 공중합체, 이로 부터 제조된 생체흡수성 필름 또는 망, 및 수술용 봉합선 또는 봉합사, 및 상기 필름 또는 망의 살균 방법 Download PDFInfo
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- KR930019229A KR930019229A KR1019930002983A KR930002983A KR930019229A KR 930019229 A KR930019229 A KR 930019229A KR 1019930002983 A KR1019930002983 A KR 1019930002983A KR 930002983 A KR930002983 A KR 930002983A KR 930019229 A KR930019229 A KR 930019229A
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- A61L17/00—Materials for surgical sutures or for ligaturing blood vessels ; Materials for prostheses or catheters
- A61L17/14—Post-treatment to improve physical properties
- A61L17/145—Coating
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/08—Radiation
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/08—Radiation
- A61L2/081—Gamma radiation
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/08—Materials for coatings
- A61L29/085—Macromolecular materials
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/08—Materials for coatings
- A61L31/10—Macromolecular materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/664—Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/20—Targets to be treated
- A61L2202/24—Medical instruments, e.g. endoscopes, catheters, sharps
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
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- Heart & Thoracic Surgery (AREA)
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- Engineering & Computer Science (AREA)
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- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials For Medical Uses (AREA)
- Polyesters Or Polycarbonates (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Polyethers (AREA)
- Medicinal Preparation (AREA)
- Paints Or Removers (AREA)
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Abstract
본 발명은 마찰에 관해서 상당히 개선된 성질을 갖는 의학적 또는 수의학적 사용을 위한 재료에 관한 것이다. 본발명은 또한 적합한 내부성질, 그러나 부적당한 마찰성질을 갖는 현재의 재료로부터 상기 재료의 제조에 관한 것이다. 본 발명은 또한 개선된 마찰성질을 제공하는 친수성 피막재료에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 상처를 통과하는 다수의 엘라스토머 봉합선 고리를 나타낸다. 상기 기술은 혈관조직을 포함하는 많은 조직에 대해 사용할 수 있다.
제2도는 37℃의 탈이온수에 침지된 공중합체 막대의 평형 물함량 그래프이다.
제3도는 마찰을 측정하기 위해 사용되는 장치를 나타낸다.
Claims (11)
- A블록이 ε-카프로락톤 결합이 임의적으로 배열된 생체내에서 가수분해되기 쉬운 결합을 포함함을 개선점으로하는, ε-카프로락톤 결합을 갖는 A 블록 및 풀리(산화알킬렌)을 갖는 B 블록으로 구성되는 블록 공중합체.
- 제1항에 있어서, 알파-히드록시산의 고리형 에스테르 및 ε-카프로락톤의 결합으로 구성되는 A 블록, 및 수평균 분자량 약 5,000 내지 20,000을 갖는 풀리(산화알킬렌)으로 구성되는 B 블록을 갖는, 16℃또는 그 이하의 유리 전이온도를 갖는 ABA 또는 AB 블록 공중합체.
- 제2항에 있어서, 고리형 에스테르는 글리콜리드이고/이거나, B블록은 풀리(산화에틸렌)또는 폴리(산화에틸렌-공동-산화프로필렌)인 공중합체.
- 제3항에 있어서, A블록에서 글리콜리드 대 ε-카프로락톤 성분의 비율은 5 내지 50중량% 글리콜리드 및 95 내지 50중량% ε-카프로락톤 범위내이고, B 블록은 상기 공중합체의 약95중량%까지를 구성하는 공중합체.
- 제2항 내지 제4항중 하나에서와 같은 ABA 공중합체로부터 제조된 윤활제로 피복된 카테테르, 수술용 바늘, 뼈나사, 핀 또는 막대, 수술용 클립 또는 스테이플, 및 필름으로 구성되는 군으로부터 선택된 의학적 또는 수술기구.
- 지방족 폴리에스테르 결합으로 본질적으로 구성되는 A블록 및 풀리(산화알킬렌)으로 구성되는 B블록을 갖는 AB 블록 공중합체, 및 지방족 폴리에스테르 결합으로 본질적으로 구성되는 A 블록 및 (a) 산화에틸렌 단독중합체; (b) 산화에틸렌과 고리형 에테르의 블록 또는 랜덤 공중합체; 또는 (c)로 구성되는 군으로 부터 선택된 첫번째 고리형 에테르 및(이때 x 및 y는 동일 또는 상이한 1 내지 약 9이고, R은 C1내지 C6알킬기이다)로 구성되는 군으로 부터 선택된 두번째 고리형 에테르의 블록 또는 랜덤 공중합체로부터 양 말단의 히드록실 수소를 제거하여 얻은 B블록을 가각 갖는 ABA 블록 공중합체로 구성되는 군으로부터 선택된 공중합체로부터 제조되는, 포유동물의 생체내 조직에 대한 부착 방지 장벽으로서 유용한 생체흡수성 필름, 또는 생체흡수성 피막을 갖는 편직되거나 직조된 망.
- 나일론, 폴리에스테르, 실크 및 폴리프로필렌으로 구성되는 군으로부터 선택된 생체적합성 중합체로부터 제조되고, 제2항 내지 제4항중 하나에서와 같은 ABA 블록 공중합체로 피복된 수술용 봉합선 또는 봉합사.
- 제7항에 있어서, 폴리에스테르가 폴리부테스테르인 단일 필라멘트로서의 수술용 봉합선 또는 봉합사.
- 제1항 내지 제4항중 하나에서와 같은 블록 공중합체로부터 제조되는 생체흡수성 피막을 가지며 피복안된 수술용 봉합선 또는 봉합사보다 적어도 약 10% 적고 약 2㎝까지의 두께를 갖는 포유동물 조직을 통해 약 2 내지 20의 통과 후에도 남아 있는 감소된 조직 마찰을 갖는 수술용 봉합선 또는 봉합사.
- 미생물에 침투되지 않는 밀봉 용기에 필름, 망, 봉합선 또는 봉합사를 충전하고; 충전된 봉합선 또는 봉합사를 감마 조사시설에 노출시키고; 상기 충전된 봉합선 또는 봉합사를 적어도 약 1.5Mrad에서 조사하고; 조사된 충전 봉합선 또는 봉합사를 감마 조사시설로부터 제거함을 특징으로하는 제6항의 필름 또는 망, 또는 제7항의 봉합선 또는 봉합사를 살균하는 방법.
- 제7항의 수술용 봉합선으로 포유동물 조직의 외과적 개구를 폐쇄하고, 수술용 봉합선의 적어도 한 끝에서 잡아당김으로써 상기 포유동물의 조직을 접근시키는 방법.※ 참고 사항 : 최초 출원 내용에 의하여 공개되는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/843,053 | 1992-03-02 | ||
US07/843,053 US5352515A (en) | 1992-03-02 | 1992-03-02 | Coating for tissue drag reduction |
Publications (1)
Publication Number | Publication Date |
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KR930019229A true KR930019229A (ko) | 1993-10-18 |
Family
ID=25288957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019930002983A KR930019229A (ko) | 1992-03-02 | 1993-02-27 | 블록 공중합체, 이로 부터 제조된 생체흡수성 필름 또는 망, 및 수술용 봉합선 또는 봉합사, 및 상기 필름 또는 망의 살균 방법 |
Country Status (13)
Country | Link |
---|---|
US (4) | US5352515A (ko) |
EP (1) | EP0558965B1 (ko) |
JP (2) | JP3494382B2 (ko) |
KR (1) | KR930019229A (ko) |
AT (1) | ATE195540T1 (ko) |
AU (1) | AU671976B2 (ko) |
CA (1) | CA2090565C (ko) |
DE (1) | DE69329210T2 (ko) |
ES (1) | ES2149784T3 (ko) |
MX (1) | MX9301047A (ko) |
PL (1) | PL297901A1 (ko) |
TW (1) | TW229217B (ko) |
ZA (1) | ZA931445B (ko) |
Families Citing this family (137)
Publication number | Priority date | Publication date | Assignee | Title |
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US5352515A (en) * | 1992-03-02 | 1994-10-04 | American Cyanamid Company | Coating for tissue drag reduction |
US6241747B1 (en) | 1993-05-03 | 2001-06-05 | Quill Medical, Inc. | Barbed Bodily tissue connector |
US8795332B2 (en) | 2002-09-30 | 2014-08-05 | Ethicon, Inc. | Barbed sutures |
CA2162899C (en) * | 1993-05-27 | 2006-07-25 | Michael S. Wiggins | Polymeric thickeners for aqueous compositions |
US5925065A (en) * | 1993-06-11 | 1999-07-20 | United States Surgical Corporation | Coated gut suture |
CA2123647C (en) * | 1993-06-11 | 2007-04-17 | Steven L. Bennett | Bioabsorbable copolymer and coating composition containing same |
US5939191A (en) * | 1993-06-11 | 1999-08-17 | United States Surgical Corporation | Coated gut suture |
KR0148704B1 (ko) * | 1994-01-10 | 1998-08-17 | 김상응 | 생체분해성 약물전달용 고분자 |
EP0682054B1 (en) * | 1994-05-09 | 2001-08-08 | Daicel Chemical Industries, Ltd. | A biodegradable copolymer, a biodegradable polymer composition, a biodegradable article, and a preparation process thereof |
KR0141431B1 (ko) * | 1994-05-17 | 1998-07-01 | 김상웅 | 생분해성 하이드로겔 고분자 |
JP3462903B2 (ja) * | 1994-07-07 | 2003-11-05 | テルモ株式会社 | 湿潤時に表面が潤滑性を有する医療用具 |
KR0153754B1 (ko) * | 1994-08-11 | 1998-11-16 | 김상응 | 수술용 봉합사용 코팅 조성물 및 이를 적용한 봉합사 |
BE1009403A3 (fr) * | 1995-06-02 | 1997-03-04 | Solvay | Composition souple a base de polymere de chlorure de vinyle, utilisation de cette composition pour la fabrication d'un article et article comprenant cette composition. |
US6107453A (en) * | 1995-07-28 | 2000-08-22 | Sanitaria Scaligera S.P.A. | Process of surface activation of biocompatible and bioabsorbable aliphatic polyesters and polyesters thus activated |
IT1277799B1 (it) * | 1995-07-28 | 1997-11-12 | Sanitaria Scaligera Spa | Procedimento di funzionalizzazione superficiale di poliesteri- alifatici biocompatibili e bioassorbibili e poliesteri cosi' attivati |
US5908656A (en) * | 1995-08-09 | 1999-06-01 | Terumo Kabushiki Kaisha | Thermoformed medical device with lubricious modified polyethylene oxide layer |
US5720730A (en) * | 1995-09-01 | 1998-02-24 | Blake, Iii; Joseph W. | Lubricated trocar valve |
US6558686B1 (en) | 1995-11-08 | 2003-05-06 | Baylor College Of Medicine | Method of coating medical devices with a combination of antiseptics and antiseptic coating therefor |
US5756145A (en) * | 1995-11-08 | 1998-05-26 | Baylor College Of Medicine | Durable, Resilient and effective antimicrobial coating for medical devices and method of coating therefor |
EP0811710B1 (en) * | 1995-12-25 | 2002-11-13 | Teijin Limited | Heat-bondable conjugated fiber and high-modulus fiber globoid made thereof |
US5997568A (en) * | 1996-01-19 | 1999-12-07 | United States Surgical Corporation | Absorbable polymer blends and surgical articles fabricated therefrom |
US5716376A (en) * | 1996-06-28 | 1998-02-10 | United States Surgical Corporation | Absorbable mixture and coatings for surgical articles fabricated therefrom |
ZA978537B (en) | 1996-09-23 | 1998-05-12 | Focal Inc | Polymerizable biodegradable polymers including carbonate or dioxanone linkages. |
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- 1993-02-11 AT AT93102107T patent/ATE195540T1/de not_active IP Right Cessation
- 1993-02-11 DE DE69329210T patent/DE69329210T2/de not_active Expired - Lifetime
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- 1993-03-01 ZA ZA931445A patent/ZA931445B/xx unknown
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ZA931445B (en) | 1993-09-23 |
AU671976B2 (en) | 1996-09-19 |
US5442016A (en) | 1995-08-15 |
DE69329210T2 (de) | 2001-04-05 |
CA2090565C (en) | 2005-11-29 |
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JP3494382B2 (ja) | 2004-02-09 |
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AU3391793A (en) | 1993-09-09 |
EP0558965A2 (en) | 1993-09-08 |
ATE195540T1 (de) | 2000-09-15 |
EP0558965A3 (ko) | 1994-04-20 |
JPH0641310A (ja) | 1994-02-15 |
EP0558965B1 (en) | 2000-08-16 |
JP2004107670A (ja) | 2004-04-08 |
ES2149784T3 (es) | 2000-11-16 |
US5530074A (en) | 1996-06-25 |
DE69329210D1 (de) | 2000-09-21 |
MX9301047A (es) | 1993-11-01 |
PL297901A1 (en) | 1993-11-15 |
CA2090565A1 (en) | 1993-09-03 |
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